Production process of novel high-performance TPU composite material

A composite material and polymer technology, applied in the field of composite material preparation, can solve problems such as insufficient mechanical strength, inability to be widely used, poor air permeability, etc., and achieve the goal of increasing diversification, increasing physical and mechanical properties and aesthetics, and maintaining strength Effect

Inactive Publication Date: 2015-03-25
DONGGUAN XIONGLIN NEW MATERIAL TECH +1
View PDF8 Cites 13 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] CN104015444A discloses a thermoplastic polyurethane / fiber composite soft cloth and its preparation method. The disclosed composite soft cloth uses TPU and fiber fabrics of different colors as raw materials, and the TPU and fabric are bonded together in the form of heat lamination. It achieves the effects of zero pollution, simple process, and low cost. However, the composite cloth made by thermal lamination still has defects such as poor air permeability and insufficient mechanical strength.
[0006] CN103483801A discloses a thermoplastic polyurethane composite material and its preparation method, which adopts the thermoplastic polyurethane composite material, adding basalt fiber as a reinforcing material, and adopts a melt extrusion process to prepare the thermoplastic polyurethane composite material, so that the thermoplastic polyurethane composite material and Compared with polyurethane composite materials using ordinary glass fibers, mechanical properties and heat resistance have been significantly improved. However, composite materials made by co-melting and extruding fiber materials with thermoplastic polyurethane will have poor air permeability , therefore, methods such as shoe materials and clothing accessories cannot be widely used in fields that require high air permeability

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Production process of novel high-performance TPU composite material
  • Production process of novel high-performance TPU composite material
  • Production process of novel high-performance TPU composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] Carry out the preparation of TPU composite material according to the following steps:

[0055] (1) 65 parts by weight of polymer polyols are placed in a reaction kettle and heated to 80° C. The polymer polyols are polytetrahydrofuran ether glycol with a molecular weight of 1000 and polyethylene adipate glycol with a molecular weight of 3000 Butanediol ester polyol; then add 0.3 parts by weight of antioxidant, 0.2 parts by weight of two (2,2,6,6-tetramethyl-4-piperidinyl) sebacate hindered amine photostabilizer agent, 0.8 parts by weight of montan wax and / or erucamide wax lubricants and 2 parts by weight of carbodiimide hydrolysis-resistant agent, fully stirred to obtain a polymer polyol mixed solution, wherein the antioxidant β-(4-hydroxy-3,5-di-tert-butylphenyl) propanoic acid n-octadecyl ester, tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl) propanoic acid ] pentaerythritol ester or bis [(2,4-di-tert-butylphenyl) phosphite] pentaerythritol ester;

[0056] (2) adding ...

Embodiment 2

[0064] (1) 70 parts by weight of polymer polyols are placed in a reaction kettle and heated to 86° C. The polymer polyols are polytetrahydrofuran ether glycol with a molecular weight of 1000 and polyethylene adipate glycol with a molecular weight of 3000 Butanediol ester polyol; then add 0.3 parts by weight of antioxidant, 0.2 parts by weight of two (2,2,6,6-tetramethyl-4-piperidinyl) sebacate hindered amine photostabilizer agent, 0.8 parts by weight of montan wax and / or erucamide wax lubricants and 2 parts by weight of carbodiimide hydrolysis-resistant agent, fully stirred to obtain a polymer polyol mixed solution, wherein the antioxidant β-(4-hydroxy-3,5-di-tert-butylphenyl) propanoic acid n-octadecyl ester, tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl) propanoic acid ] pentaerythritol ester or bis [(2,4-di-tert-butylphenyl) phosphite] pentaerythritol ester;

[0065] (2) Add 31 parts by weight of 1,4-cyclohexane diisocyanate at a temperature of 62° C. to the polymer polyol...

Embodiment 3

[0073] Carry out the preparation of TPU composite material according to the following steps:

[0074] (1) 80 parts by weight of polymer polyols are placed in a reaction kettle, and heated to 90°C. The polymer polyols are polytetrahydrofuran ether glycol with a molecular weight of 1000 and polyethylene adipate glycol with a molecular weight of 3000 Butanediol ester polyol; Then add 0.6 weight part of antioxidant, 0.45 weight part of two (2,2,6,6-tetramethyl-4-piperidinyl) debacate hindered amine light stabilizer agent, 0.6 parts by weight of montan wax and / or erucamide wax lubricants and 4 parts by weight of carbodiimide hydrolysis-resistant agent, fully stirred to obtain a polymer polyol mixed solution, wherein the antioxidant β-(4-hydroxy-3,5-di-tert-butylphenyl) propanoic acid n-octadecyl ester, tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl) propanoic acid ] pentaerythritol ester or bis [(2,4-di-tert-butylphenyl) phosphite] pentaerythritol ester;

[0075] (2) adding 32 par...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
diameteraaaaaaaaaa
diameteraaaaaaaaaa
tear strengthaaaaaaaaaa
Login to view more

Abstract

The invention relates to a production process of a novel high-performance TPU composite material. The production process comprises the following steps: firstly, extruding a TPU material by using an extruder; and then, wrapping the TPU on a silk yarn or a cotton thread by virtue of a wrapping technology so as to obtain the TPU composite material provided by the invention. The material can be wound to form a coil or can be directly prepared into a textile. By jointly weaving a fiber layer and the TPU material, the TPU composite material which is good in air permeability and high in mechanical strength is manufactured. The composite material further has the advantages of wear resistance, flame resistance, yellowing resistance, mould proof, bacterial prevention and the like.

Description

technical field [0001] The invention belongs to the field of composite material preparation, in particular to a production process of TPU composite material. Background technique [0002] Thermoplastic polyurethane elastomer (TPU) is a kind of linear multi-block polymer formed by alternating thermodynamically incompatible hard segments and soft segments. It has a unique microphase separation structure, so its physical and mechanical properties are quite excellent. . The outstanding features of TPU are large hardness range, high strength, good elasticity, low temperature resistance, excellent wear resistance, excellent ozone resistance, and good oil resistance, chemical resistance and environmental resistance. Therefore, it is widely used in Processing methods such as injection molding, extrusion, calendering and dissolving into solution resins, its products cover the scope of industrial applications and civilian necessities. [0003] Thermoplastic polyurethane (TPU) has ou...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/08C08L75/06C08G18/75C08G18/66C08G18/48C08G18/42C08G18/32B29C47/02
Inventor 何健雄王一良
Owner DONGGUAN XIONGLIN NEW MATERIAL TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap