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Encapsulation structure and encapsulation method of organic light emitting diode device

An electroluminescent device and packaging structure technology, which is applied in the direction of electric solid-state devices, electrical components, semiconductor devices, etc., can solve the problem that the barrier performance of plastic substrates cannot meet the requirements of OLED packaging, the life of flexible organic electroluminescent devices is short, and the device film There are many defects in the layer structure to achieve excellent packaging effect, which is beneficial to the life of the device and reduces the effect of erosion

Inactive Publication Date: 2015-04-15
OCEANS KING LIGHTING SCI&TECH CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Flexible products are the development trend of organic electroluminescent devices. The difference between flexible organic electroluminescent devices and ordinary organic electroluminescent devices is that plastics are used as substrates, and the flatness of plastic substrates is poor, resulting in many structural defects in the device film layer, causing The device is damaged; moreover, the barrier properties of commonly used plastic substrates cannot meet the requirements of OLED packaging, so flexible organic electroluminescent devices generally have the problem of short life
At present, it has been reported that SiN x or SiO x Inorganic materials, such as magnetron sputtering, are placed on the surface of the metal cathode by methods such as magnetron sputtering, and are used as the packaging layer of organic electroluminescent devices. However, under the high temperature operating conditions of magnetron sputtering, the surface of the metal cathode is easily damaged.

Method used

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  • Encapsulation structure and encapsulation method of organic light emitting diode device
  • Encapsulation structure and encapsulation method of organic light emitting diode device
  • Encapsulation structure and encapsulation method of organic light emitting diode device

Examples

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Embodiment 1

[0039] figure 1 It is a schematic diagram of the packaging structure of an organic electroluminescent device provided in this embodiment. Such as figure 1 As shown, the packaging structure of the organic electroluminescent device is sequentially stacked with a conductive glass substrate 10 , an organic light-emitting functional layer 20 , a metal cathode 30 and a packaging layer 40 . Wherein, the organic light-emitting functional layer 20 includes a hole injection layer 21 , a hole transport layer 22 , a light-emitting layer 23 , an electron transport layer 24 and an electron injection layer 25 stacked sequentially from bottom to top. figure 2 yes figure 1 Schematic diagram of the structure of the encapsulation layer, such as figure 2 As shown, the encapsulation layer 40 includes a germanium carbonitride layer 41 , a first barrier layer 42 and a second barrier layer 43 sequentially stacked on the metal cathode 30 . More specifically, the encapsulation layer 40 includes d...

Embodiment 2

[0055] A packaging structure of an organic electroluminescence device, which sequentially includes a conductive glass substrate, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injection layer, a metal cathode and a packaging layer from bottom to top. The encapsulation layer is composed of 4 layers of germanium carbonitride / Al 2 o 3 :Cl layer / ZrO 2 : Multilayer composite film structure composed of Cl layer. Its preparation method is as follows:

[0056] (1) Pre-treatment of ITO glass substrates: ITO glass substrates are cleaned with acetone, ethanol, deionized water, and ethanol, all of which are cleaned with an ultrasonic cleaner. The single washing is cleaned for 5 minutes, then blown dry with nitrogen, and dried in an oven Standby; the cleaned ITO glass also needs surface activation treatment to increase the oxygen content of the conductive surface layer and improve the work function of the conductive layer...

Embodiment 3

[0070] A packaging structure of an organic electroluminescence device, which sequentially includes a conductive glass substrate, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injection layer, a metal cathode and a packaging layer from bottom to top. The encapsulation layer is composed of 3 layers of germanium carbonitride / Ga 2 o 3 :Cl layer / HfO 2 : Multilayer composite film structure composed of Cl layer. Its preparation method is as follows:

[0071] (1) Pre-treatment of ITO glass substrates: ITO glass substrates are cleaned with acetone, ethanol, deionized water, and ethanol, all of which are cleaned with an ultrasonic cleaner. The single washing is cleaned for 5 minutes, then blown dry with nitrogen, and dried in an oven Standby; the cleaned ITO glass also needs surface activation treatment to increase the oxygen content of the conductive surface layer and improve the work function of the conductive layer...

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Abstract

The invention discloses an encapsulation structure of an organic light emitting diode device. The encapsulation structure includes an anode electric conduction substrate as well as an organic light-emitting functional layer, a metal cathode and an encapsulation layer which are sequentially stacked on the anode electric conduction substrate, wherein the encapsulation layer includes germanium carbonitride layers, first barrier layers and second barrier layers which are sequentially stacked on the metal cathode, wherein the first barrier layers are made of chlorine-doped R2O3, wherein R is a IIIA-family element, and the second barrier layers are made of one kind material selected from chlorine-doped titanium oxide, chlorine-doped zirconium oxide and chlorine-doped hafnium oxide. The encapsulation structure has excellent obstruction performance for oxygen and water vapor, and therefore, stress on a film layer can be effectively slowed down and released, and the service life of the organic light emitting diode device can be significantly prolonged. The invention also provides an encapsulation method of an organic light emitting diode device. The method is applicable to the encapsulation of organic light emitting diode devices prepared through adopting electric conduction glass substrates, and in particularly applicable to the encapsulation of flexible organic light emitting diode devices prepared through adopting plastic or metal substrates.

Description

technical field [0001] The invention belongs to the packaging field of organic electroluminescent devices, and in particular relates to a packaging structure and a packaging method of organic electroluminescent devices. Background technique [0002] Organic electroluminescent device (OLED) is a current-mode semiconductor light-emitting device based on organic materials. Its typical structure is to prepare a layer of tens of nanometers thick organic light-emitting material on the ITO glass as the light-emitting layer, and the top of the light-emitting layer is a metal electrode. When a voltage is applied to the electrodes, the light-emitting layer produces light radiation. [0003] Organic electroluminescent materials are particularly sensitive to the intrusion of oxygen and water vapor. On the one hand, because oxygen is a quencher, the quantum efficiency of light emission will be significantly reduced, and the oxidation of oxygen to the hole transport layer will also reduc...

Claims

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Application Information

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IPC IPC(8): H01L51/52H01L51/56
CPCH10K50/84H10K71/00
Inventor 周明杰钟铁涛王平张振华
Owner OCEANS KING LIGHTING SCI&TECH CO LTD