All-solid-state inorganic electrochromic device and its preparation method

An electrochromic device and electrochromic layer technology, which can be used in instruments, nonlinear optics, optics, etc., can solve the problems of poor thermal stability of polymer electrolytes, poor corrosion resistance of liquid electrolytes, and unfavorable large-scale production. Achieve large-scale production, the production method is simple and easy, and the effect of good application prospects

Active Publication Date: 2017-10-10
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Based on the above problems, the present invention provides an all-solid-state inorganic electrochromic device and its preparation method, which solves the problems of poor corrosion resistance, poor chemical stability, difficult packaging of liquid electrolytes, and poor thermal stability of polymer electrolytes, which are not conducive to large-scale production. question

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  • All-solid-state inorganic electrochromic device and its preparation method
  • All-solid-state inorganic electrochromic device and its preparation method
  • All-solid-state inorganic electrochromic device and its preparation method

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Embodiment 1

[0026] Such as figure 1 As shown, the present embodiment provides a single-layer all-solid-state inorganic electrochromic device. The transparent substrate 1 is an ordinary glass sheet; the first transparent conductive layer 2 is an indium zinc oxide (IZO) film, which communicates with an external power source as a cathode electrode; the first electrochromic layer 3 is tungsten oxide (WO x ) film, as the cathodic color change layer; electrolyte layer 4 is silicon dioxide (SiO 2 ) a transparent nanoparticle film as an electrolyte layer; the second transparent conductive layer 5 is an indium zinc oxide film, which is connected to an external power source and serves as an anode electrode.

[0027] The manufacturing method of the above-mentioned all-solid-state inorganic electrochromic device includes the following steps:

[0028] Step 1: The area cleaned by ultrasonic cleaning with acetone and absolute ethanol solution is 2.5×2.5cm 2 Ordinary glass is used as the transparent s...

Embodiment 2

[0035] Such as figure 2 As shown, the present embodiment provides a double-layer all-solid-state inorganic electrochromic device, the transparent substrate 1 is an ordinary glass sheet; the first transparent conductive layer 2 is an indium tin oxide (ITO) film, as a cathode electrode; The chromic layer 3 is tungsten oxide (WO x ) film, as a cathodic color change layer; electrolyte layer 4 is phosphorus-doped silicon dioxide (SiO 2 : P) film, as an electrolyte layer; the second transparent conductive layer 5 is an indium tin oxide (ITO) film, as an anode electrode; the second electrochromic layer 6 is a nickel oxide (NiO) film, as an anode color-changing layer.

[0036] The manufacturing method of the above-mentioned inorganic electrochromic device comprises the following steps:

[0037] Step 1: The area cleaned by ultrasonic cleaning with acetone and absolute ethanol solution is 2.5×2.5cm 2 Ordinary glass as a transparent substrate 1;

[0038] Step 2: Deposit a layer of i...

Embodiment 3

[0045] This embodiment provides a single-layer all-solid-state inorganic electrochromic device, the transparent substrate is an ordinary glass sheet; the first transparent conductive layer is an indium zinc oxide (IZO) film, which is connected with an external power source and serves as a cathode electrode; The chromic layer is tungsten oxide (WO x ) film as the cathodic color change layer; the electrolyte layer is perchloric acid (HClO 4 ) solution soaked silicon dioxide (SiO 2 ) film as an electrolyte layer; the second transparent conductive layer is an indium zinc oxide film, which communicates with an external power source and serves as an anode electrode.

[0046] The manufacturing method of the above-mentioned inorganic electrochromic device comprises the following steps:

[0047] Step 1: The area cleaned by ultrasonic cleaning with acetone and absolute ethanol solution is 2.5×2.5cm 2 ordinary glass as a transparent substrate;

[0048] Step 2: Deposit a layer of indi...

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Abstract

The invention provides an all-solid-state inorganic electrochromic device and a fabrication method thereof. The all-solid-state inorganic electrochromic device comprises a transparent conductive layer, an electrochromic layer and an electrolyte layer, wherein the electrolyte layer is a silicon dioxide or phosphor-doped silicon dioxide transparent nano-particulate film. The all-solid-state inorganic electrochromic device provided by the invention comprises multiple layers of solid inorganic composite membranes, has the most typical and simplest structure of an electrochromic device, can achieve the targets of large-scale industrialization, full solid state and stable device performance, and can be directly applied to the fields of smart windows, display technologies and the like, thereby having a good application prospect. The electrochromic device with low cost, large-scale industrialization and stable performance can be obtained by utilizing the method provided by the invention, and comprises the all-solid-state inorganic solid inorganic composite membranes; the method can be directly applied to the manufacturing line of an existing industrialized electrochromic device, and has an important application value.

Description

technical field [0001] The invention relates to the technical field of electrochromism, in particular to an all-solid-state inorganic electrochromic device and a preparation method thereof. Background technique [0002] Electrochromic materials refer to materials whose optical properties (emission rate, transmission rate, absorption rate, etc.) will undergo stable and reversible changes after voltage is applied. Electrochromic materials include a wide range and can be roughly divided into two types: electrodeless electrochromic materials and organic electrochromic materials. Devices made of electrochromic materials are called electrochromic devices. Electrochromic devices have the advantages of high efficiency, low consumption, no pollution, and intelligence. All have broad application prospects. [0003] Electrochromic devices generally include a transparent conductive layer, an electrochromic layer and an electrolyte layer, and are supported by a transparent substrate, o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G02F1/153
CPCG02F1/1508
Inventor 张洪亮万青竺立强曹鸿涛
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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