Phase-change energy-storage dual-limit temperature adjustment mortar and preparation method thereof

A technology of phase change energy storage and phase change temperature, which is applied in the field of building materials, can solve the problems of high cost of phase change microcapsules, loss of energy storage and temperature regulation function, and difficulty in long-term performance of energy storage and temperature regulation effects of phase change mortar, etc. question

Inactive Publication Date: 2015-05-13
建筑材料工业技术监督研究中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the wall material of phase change microcapsules is an organic material, when added into the cement-based mortar matrix, defects will occur at the interface junction. When the amount is large, the strength of the hardened mortar will be significantly reduced, the possibility of cracking will be increased, and the phase change will be slightly The cost of the capsule is relatively high, and it is not suitable for a large amount of mixing, which eventually leads to the restriction of the energy storage and temperature adjustment capabilities of the mortar
It can be seen that there are certain technical and economic problems in adding inorganic porous-based shape-fixed phase-change particles or phase-change microcapsules alone, and it is difficult to obtain a substantial improvement in the energy storage and temperature regulation function.
[0007] In addition, the existing phase-change energy storage temperature-regulating mortar products generally only have a single phase-change temperature point, and the temperature-regulating function has limitations. When the indoor temperature is in different ranges in different seasons, the phase-change temperature point with a single phase It is difficult for variable mortar to exert energy storage and temperature regulation functions for a long time
For example, the phase change mortar with a phase change temperature of about 28 degrees Celsius can only play a role in summer after repeated phase changes, but it is difficult to play a role in cold seasons when the indoor temperature is low; the phase change mortar with a phase change temperature of about 18 degrees Celsius can only In autumn and winter, it has the significance of indoor energy storage and temperature regulation, but in summer, the phase change material is in a melting state for a long time, and the solid-liquid phase transition cannot occur, and loses the function of energy storage and temperature regulation
Therefore, the phase change mortar with a single phase change temperature point has fewer effective phase change reactions throughout the year, and the energy storage and temperature regulation effects are not significant enough.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0086] Step 1: Prepare phase change microcapsules with a phase change temperature of 18-20 degrees Celsius

[0087] 10 parts of polystyrene and 10 parts of butyl stearate are dissolved in 80 parts of dichloromethane, and the above-mentioned oil phase solution is slowly dripped into 600 parts of 1% aqueous sodium lauryl sulfate solution in an emulsifier with Stir at a speed of 2800r / min for 30 minutes, then reduce the speed to 500r / min, heat the emulsion until the temperature reaches 35-40 degrees Celsius, continue stirring for 2 hours, filter, wash, and dry to obtain polystyrene capsule wall—stearic acid Butyl ester capsule core phase change microcapsules have a phase change temperature of 19.5 degrees Celsius and a latent heat of phase change of 84 kJ / kg as tested by DSC, and an average particle size of 38 microns as tested by a laser particle size analyzer.

[0088] Step 2: Prepare expanded perlite shaped phase change particles with a phase change temperature of 26-28 degree...

Embodiment 2

[0093] Step 1: Prepare phase change microcapsules with a phase change temperature of 18-20 degrees Celsius

[0094] Dissolve 10 parts of polysulfone and 12 parts of n-hexadecane in 88 parts of dichloromethane, slowly drop the oil phase solution into 660 parts of 0.8% aqueous solution of sodium dodecylsulfonate, in the emulsifier at 2800r / Stir at min speed for 30 minutes, then reduce the speed to 500r / min, heat the emulsion until the temperature reaches 35-40 degrees Celsius, continue stirring for 2 hours, filter, wash, and dry to obtain the polysulfone capsule wall—n-hexadecane capsule core The phase change microcapsules have a phase change temperature of 18.6 degrees Celsius and a phase change latent heat of 98 kJ / kg as tested by DSC, and an average particle size of 45 microns tested by a laser particle size analyzer.

[0095] Step 2: Prepare expanded perlite shaped phase change particles with a phase change temperature of 26-28 degrees Celsius

[0096] Mix 10 parts of expa...

Embodiment 3

[0100] Step 1: Prepare phase change microcapsules with a phase change temperature of 18-20 degrees Celsius

[0101] Dissolve 15 parts of polymethyl methacrylate and 20 parts of n-hexadecane in 140 parts of dichloromethane, slowly drop the oil phase solution into 1050 parts of 0.9% concentration of polyvinyl alcohol aqueous solution, in the emulsifier at 2800r / Stir at min speed for 30 minutes, then reduce the speed to 500r / min, heat the emulsion until the temperature reaches 35-40 degrees Celsius, continue stirring for 2 hours, filter, wash and dry to obtain the polymethyl methacrylate capsule wall—positive ten Hexane capsule core phase change microcapsules have a phase change temperature of 18.2 degrees Celsius and a latent heat of phase change of 105 kJ / kg tested by DSC, and an average particle size of 52 microns tested by a laser particle size analyzer.

[0102] Step 2: Prepare expanded perlite shaped phase change particles with a phase change temperature of 26-28 degrees C...

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Abstract

The invention discloses phase-change energy-storage dual-limit temperature adjustment mortar and a preparation method thereof. The phase-change energy-storage dual-limit temperature adjustment mortar comprises the following raw materials in parts by weight: 25 parts of cement, 20-55 parts of medium sand, 10-30 parts of phase-change microcapsules, 10-40 parts of expanded perlite shape-stabilized phase-change particles, 0.25-1 part of fibers, 0.2-0.5 parts of cellulose ether, 1.5-3 parts of redispersible latex powder and 25-30 parts of water, wherein the phase-change temperature of the phase-change microcapsules is 18-20 DEG C and the phase-change temperature of the expanded perlite shape-stabilized phase-change particles is 26-28 DEG C. The phase-change energy-storage dual-limit temperature adjustment mortar prepared by the method has a dual-limit temperature adjustment function, not only can remarkably adjust a room temperature to be within upper and lower limit ranges of a comfortable temperature of a human body and improve thermal comfort of a human settlement environment but also improves energy-storage and temperature-adjustment capabilities of a phase-change mortar product and overcomes performance deficiencies existent during addition of a single phase-change medium through compound addition of two phase-change mediums, that is to say, the phase-change microcapsules and the expanded perlite shape-stabilized phase-change particles.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to a phase-change energy storage dual-limit temperature-regulating mortar and a preparation method thereof. Background technique [0002] In modern buildings, especially high-rise buildings, lightweight envelope structures have been used more and more widely, mainly because lightweight envelope structures can not only greatly reduce the self-load of building structures, but also have good thermal resistance. , can improve the thermal insulation effect of the building envelope. However, due to the small heat capacity and poor heat storage capacity of the lightweight enclosure structure, it cannot absorb and store a large amount of solar radiant heat during the day, causing the indoor temperature to be too high during the day and too low at night, with large diurnal fluctuations and poor thermal comfort. This results in an increase in air conditioning and heating energy ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/00C04B28/04C04B14/18
Inventor 迟碧川李应权扈士凯陈志纯朱立德王明轩段策谷冰莹曹可王笑帆陈嘉宇
Owner 建筑材料工业技术监督研究中心
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