The invention discloses a phase change cold-accumulation material and a preparation method thereof. The phase change cold-accumulation material is prepared from, by mass, 50-60% of sodium sulfafe decahydrate, 10-15% of sodium bromide, 2-5% of ammonium chloride, 3% of aluminum oxide, 1-3% of sodium borate, 1-2% of boric acid, 4% of nanometer silicon dioxide, 2% of nanometer magnesium silicate and the balance deionized water. The preparation method comprises the steps of sequentially adding the sodium sulfafe decahydrate, the sodium bromide, the ammonium chloride, the sodium borate and the boric acid into a heating tank provided with a blender, conducting mixing and uniform stirring, controlling the mixture temperature within the range from 60 DEG C to 70 DEG C, conducting stirring till the mixture is molten completely, adding the aluminum oxide, the nanometer silicon dioxide and the nanometer magnesium silicate in the high-speed stirring process, replenishing the balance deionized water, stirring the mixture uniform, preserving the temperature for one hour at the temperature of 40 DEG C, cooling the mixture to be room temperature, and obtaining the uniform plasty fluid form phase change cold-accumulate material. Compared with the prior art, the phase change cold-accumulate material has the advantages of being high in potential heat value, stable in system, few in phase-change temperature hysteresis phenomenon, low in repeated cycling degradation and the like, raw materials are easy to obtain, the production is easy to conduct, the safety and nontoxicity are achieved, and the material has practical value in the field of heating, ventilation and air conditioning (HVAC).