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Graphene oxide melamine resin and preparation method thereof

A melamine and resin technology, applied in the field of graphene oxide melamine resin and its preparation, can solve the problems of limited performance improvement, short storage period, poor easy cracking, etc., and achieves improved mechanical properties, improved bonding strength, and improved toughness. and the effect of bending resistance

Inactive Publication Date: 2015-07-29
WUHU BAOYI AMUSEMENT EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, a single graphene oxide has limited performance improvement of the resin, and further improvement of the performance of the resin is needed. The performance of the resin can be improved by improving the process and composition; for example, it is necessary to improve the strength, water resistance, thermal stability, wear resistance, Hardness, resistance to chemicals, poor toughness, easy to break, short storage period and other properties make the resin more widely used in furniture, vehicles, construction, etc.

Method used

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Examples

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Embodiment Construction

[0014] A graphene oxide melamine resin, made of the following raw materials in parts by weight (kg): carbon nanotube 0.6, aluminum phosphate 0.2, melamine 23, 37% formaldehyde aqueous solution 43, graphene oxide 2, trifluoroethylene methacrylate Esters 0.7-0.9, polyacrylonitrile 0.8, dimethylformamide amount, polyethylene oxide 0.2, dimethylformamide / methylene chloride volume ratio 1:1, compound solvent amount, tert-butyl hydroperoxide 0.4, lemon Appropriate amount of acid, appropriate amount of alkaline pH regulator AMP-95, and appropriate amount of ethanol.

[0015] The production method of described graphene oxide melamine resin is characterized in that:

[0016] (1) Dissolve polyacrylonitrile in dimethylformamide to prepare a 4wt% solution; dissolve polyethylene oxide in a composite solvent with a volume ratio of dimethylformamide / dichloromethane of 1:1 to prepare a 4wt% solution % solution, then mix the above two solutions evenly, add carbon nanotubes, aluminum phosphate...

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Abstract

The invention discloses graphene oxide melamine resin. The graphene oxide melamine resin is prepared from the following raw materials in parts by weight: 0.5-0.8 part of carbon nanotubes, 0.2-0.3 parts of aluminum phosphate, 20-25 parts of melamine, 40-45 parts of a 37% formalin, 1.8-2.1 parts of graphene oxide, 0.7-0.9 part of trifluoroethyl methacrylate, 0.7-0.9 part of polyacrylonitrile, an appropriate amount of dimethylformamide, 0.2-0.3 parts of polyoxyethylene, an appropriate amount of a composite solvent which comprises dimethylformamide and dichloromethane according to the volume ratio of 1:1, 0.3-0.5 part of tert-butyl hydroperoxide, an appropriate amount of citric acid, an appropriate amount of an alkaline pH value modifier AMP-95, and an appropriate amount of ethanol. According to the graphene oxide melamine resin disclosed by the invention, graphene oxide, the carbon nanotubes and aluminum phosphate are added, so that the mechanical properties of the material are improved, and the conductivity and the bending strength are improved.

Description

technical field [0001] The invention relates to the field of melamine resin materials, in particular to a graphene oxide melamine resin and a preparation method thereof. Background technique [0002] Graphene is a carbonaceous material with a two-dimensional planar honeycomb lattice structure formed by a single layer of carbon atoms tightly packed. Its unique nanostructure determines that it has a series of excellent properties. The theoretical specific surface area is as high as 2600㎡ / g; thermal conductivity The coefficient is as high as 5000W / (m.K), which is 5 times that of diamond, and the strength is the highest among known materials, reaching 130GPa, which is more than 100 times that of steel. At present, graphene is considered to be used in functional composite materials, nano devices, and energy storage. Materials and catalyst supports have a wide range of application space. [0003] Using the excellent properties of graphene to prepare graphene / polymer composites, t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G12/32C08K13/06C08K9/04C08K3/04C08K7/24C08K3/32
Inventor 张庆
Owner WUHU BAOYI AMUSEMENT EQUIP
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