Acrylic-acid-modified water-based alkyd resin and preparation method thereof

A technology of water-based alkyd resin and acrylic acid, which is applied in coatings, polyester coatings, etc., can solve the problems of waterproof, weather resistance, acid and alkali resistance, large ethylene glycol waste base, high cost, etc., so as to facilitate the reaction The effect of progress, low cost and fast drying speed

Inactive Publication Date: 2015-09-30
ANHUI JINDUN PAINT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Ethylene glycol is an important organic chemical raw material, mainly used to produce alkyd resin, polyester, antifreeze, non-ionic surfactant, ethanolamine and explosives, etc. The demand for it in my country is very large. On the one hand, it is used to prepare ethylene glycol The disadvantages of alcohol are very obvious. It relies on petroleum resources, consumes a lot of water, and costs high. On the other hand, the amount of ethylene glycol used is very large, resulting in a large number of ethylene glycol waste. The treatment of ethylene glycol waste has always been a major problem for people. The application of ethylene glycol as a synthetic material in the production of alkyd resin has a great impact on the waterproof, weather resistance, and acid and alkali resistance of alkyd resin. How to apply ethylene glycol waste in the synthesis process of alkyd resin to Effective recycling of ethylene glycol waste can not only purify the environment and reduce pollution, but also turn waste into treasure and save a lot of petroleum resources

Method used

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  • Acrylic-acid-modified water-based alkyd resin and preparation method thereof

Examples

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Effect test

Embodiment 1

[0021] A kind of acrylic modified water-based alkyd resin, its raw material comprises by weight: 20 parts of m-xylene, 4 parts of styrene, 3 parts of ethylene glycol waste, 0.3 parts of initiator, 10 parts of isobutyl acrylate, n-methacrylic acid 4 parts of butyl ester, 0.5 parts of methacrylic acid, 60 parts of dehydrated castor oil, 10 parts of phthalic anhydride, 4 parts of isophthalic acid, 4 parts of trimethylol propane, 30 parts of dimethylol propionic acid, anti 1 part of oxygen agent, 30 parts of cosolvent, 10 parts of neutralizer, 20 parts of p-xylene, 15 parts of water;

Embodiment 2

[0023] A kind of acrylic acid modified waterborne alkyd resin, its raw material comprises by weight: m-xylene 30 parts, styrene 2 parts, ethylene glycol waste 5 parts, initiator 0.2 part, isobutyl acrylate 15 parts, methacrylic acid 3 parts of n-butyl ester, 1 part of methacrylic acid, 50 parts of dehydrated castor oil, 15 parts of phthalic anhydride, 1 part of isophthalic acid, 6 parts of trimethylol propane, 20 parts of dimethylol propionic acid, 3 parts of antioxidant, 20 parts of cosolvent, 15 parts of neutralizer, 10 parts of p-xylene, 20 parts of water;

Embodiment 3

[0025] A kind of acrylic acid modified waterborne alkyd resin, its raw material comprises by weight: 25 parts of m-xylene, 3.6 parts of styrene, 4 parts of ethylene glycol waste, 0.28 part of initiator, 12 parts of isobutyl acrylate, methacrylic acid 3.6 parts of n-butyl ester, 0.6 parts of methacrylic acid, 54 parts of dehydrated castor oil, 10 parts of phthalic anhydride, 14 parts of isophthalic acid, 5 parts of trimethylol propane, 26 parts of dimethylol propionic acid, 2 parts of antioxidant, 26 parts of cosolvent, 12 parts of neutralizer, 16 parts of p-xylene, 16 parts of water;

[0026] The cosolvent is composed of propylene glycol methyl ether acetate, isopropanol, isobutanol, n-butanol and sec-butanol. The neutralizing agent is composed of triethylamine, dimethylethanolamine, ammonia water and 2-amino-2-methyl-1-propanol. The initiator is benzoyl peroxide, azobisisobutyronitrile, 2,2-azobis(methylbutyronitrile) and 2,2-azo(2,4-dimethylvaleronitrile) One or more than ...

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Abstract

The invention discloses an acrylic-acid-modified water-based alkyd resin and a preparation method thereof. The acrylic-acid-modified water-based alkyd resin is prepared from metaxylene, styrene, ethylene glycol waste, an initiator, isobutyl acrylate, n-butyl methylacrylate, methacrylic acid, dehydrated castor oil, phthalic anhydride, m-phthalic acid, trimethylolpropane, dimethylolpropionic acid, an antioxidant, a cosolvent, a neutralizer, paraxylene and water. The ethylene glycol waste is defective waste, can be derived from tobacco industry, textile industry, cosmetics and other industries, thereby greatly lowering the production cost of the product, solving the problem of treatment of ethylene glycol waste, cleaning the environment, changing waste into valuable substances and saving abundant petroleum resources. The product has the advantages of excellent water resistance, excellent weather resistance and excellent acid / alkali resistance. The method is simple in preparation process and convenient for operation.

Description

technical field [0001] The invention relates to the technical field of alkyd resins, in particular to an acrylic-modified water-based alkyd resin and a preparation method thereof. Background technique [0002] Ethylene glycol is an important organic chemical raw material, mainly used to produce alkyd resin, polyester, antifreeze, non-ionic surfactant, ethanolamine and explosives, etc. The demand for it in my country is very large. On the one hand, it is used to prepare ethylene glycol The disadvantages of alcohol are very obvious. It relies on petroleum resources, consumes a lot of water, and costs high. On the other hand, the amount of ethylene glycol used is very large, resulting in a large number of ethylene glycol waste. The treatment of ethylene glycol waste has always been a major problem for people. The application of ethylene glycol as a synthetic material in the production of alkyd resin has a great impact on the waterproof, weather resistance, and acid and alkali res...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G63/49C08F220/18C08F212/08C08F220/06C09D167/08C09D133/08
Inventor 朱恒衡梅长林蒋伟藩
Owner ANHUI JINDUN PAINT
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