Halogen-free flame-retardant TPVC material and preparation method thereof
A technology of PVC resin and flame retardant, which is applied in the field of polymer composite materials and its preparation, can solve the problems of increased flammability of TPVC materials, decreased mechanical properties of TPVC materials, and harmfulness to human body, and achieves good synergistic flame retardancy and good Eco-friendly, effect of improving cold resistance
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Embodiment 1)
[0026] The halogen-free flame-retardant TPVC material of the present embodiment is made of the following components by weight:
[0027] 100kg of SG-3 type PVC resin.
[0028] As a plasticizer, 30kg of dioctyl terephthalate (DOTP), 4.5kg of epoxy fatty acid methyl ester, 22.5kg of diphenyl-isooctyl phosphate (DPOP) and 3kg of chlorinated paraffin.
[0029] 6kg of calcium-zinc composite stabilizer.
[0030] 1 kg calcium stearate, 1.1 kg stearic acid and 1 kg polyethylene wax as lubricants.
[0031] 50kg active magnesium hydroxide, 6kg microcapsule red phosphorus, 4kg antimony trioxide and 5kg zinc borate as a halogen-free flame retardant.
[0032] The preparation method of the above-mentioned halogen-free flame-retardant TPVC material has the following steps:
[0033] ① Weigh SG-3 PVC resin, dioctyl terephthalate, epoxy fatty acid methyl ester, diphenyl-isooctyl phosphate, chlorinated paraffin, calcium zinc composite stabilizer, calcium stearate according to the above weight ...
Embodiment 2~ Embodiment 6)
[0039] The preparation method of each example is the same as that of Example 1, except for the formulation of the halogen-free flame-retardant TPVC material, see Table 1 for details.
[0040] Table 1
[0041] Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 PVC resin SG-3 type 100kg SG-3 type 100kg SG-3 type 100kg S-2500 type 100kg S-2500 type 100kg S-2500 type 100 kg DOTP 30kg 30kg 30kg 30kg 30kg 30kg epoxy fatty acid methyl ester 4.5kg 5kg 4kg 4.5kg 6kg 3kg DPOP 22.5kg 20kg 25kg 22.5kg 15kg 15kg Chlorinated paraffin 3kg 4kg 2kg 3kg 4.5kg 1.5kg Calcium Zinc Composite Stabilizer 6kg 6kg 6kg 6kg 6kg 6kg Calcium stearate 1kg 1kg 1kg 1kg 1kg 1kg stearic acid 1.1kg 1.1kg 1.1kg 1.1kg 1.1kg 1.1kg polyethylene wax 1kg 1kg 1kg 1kg 1kg 1kg Active Magnesium Hydroxide 50kg 50kg 60kg 60kg 60kg ...
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