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35results about How to "Has synergistic flame retardant effect" patented technology

Phosphorus/silicon-containing reactive high-molecular flame retardant, and preparation method and application thereof

The invention provides a phosphorus / silicon-containing reactive high-molecular flame retardant, and a preparation method and application thereof, relating to flame retardants. The preparation method comprises the following steps: reacting methacryloyl chloride and p-phenylenediamine in the presence of a solvent and an acid-binding agent, carrying out vacuum filtration to remove the acid-binding agent salt generated by the reaction, and purifying the crude product by water washing, rotary evaporation and drying to obtain 4-methacrylamidoaniline; reacting hydroxyethyl methacrylate and 9,10-dihydro-9-oxa-10-phosphaphenanthryl-10-oxide in the presence of carbon tetrachloride, a solvent and an acid-binding agent, carrying out vacuum filtration to remove the acid-binding agent salt generated by the reaction, and purifying the crude product by water washing, rotary evaporation and drying to obtain a phosphorus-containing monomer; and carrying out free-radical polymerization on the 4-methacrylamidoaniline, phosphorus-containing monomer and methylacryloyloxypropyl heptaisobutyl POSS (polyhedral oligomeric silsesquioxane) under the initiation conditions of a solvent and an initiator to obtain the phosphorus / silicon-containing reactive high-molecular flame retardant. The phosphorus / silicon-containing reactive high-molecular flame retardant can be used for preparing a flame-retardant epoxy resin.
Owner:XIAMEN UNIV

Phosphorus-containing fluorine-containing synergic flame-retardant compound and preparation method thereof

The invention provides a phosphorus-containing fluorine-containing synergic flame-retardant compound and a preparation method thereof, relating to flame-retardant compounds. The preparation method comprises the following steps: carrying out reaction on a diamido compound and 5-bis(trifluoromethyl)benzaldehyde in a first solvent, carrying out rotary evaporation, and drying to obtain an intermediate containing carbon-nitrogen double bond; and carrying out reaction on the intermediate containing carbon-nitrogen double bond and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide in a second solvent, precipitating the product with a precipitant, washing with the precipitant, and drying to obtain the phosphorus-containing fluorine-containing synergic flame-retardant compound. The compound simultaneously comprises the flame-retardant elements phosphorus and fluorine, and the phosphorus and fluorine have the synergic flame-retardant actions; and thus, the compound can be used as a flame retardant and has favorable flame-retardant effect. The introduced fluorine element can enhance the heat stability and chemical stability, lower the surface energy of the material and lower the dielectric constant and hydroscopic property of the material, thereby satisfying the required properties of the electronic packaging material. The compound contains two active groups, thereby being beneficial to enhancing the compatibility with the high-polymer material, improving the loss of the flame retardant and enhancing the flame retardancy.
Owner:XIAMEN UNIV

Method for preparing nitrogen phosphate sulfur-containing reactive flame retardant applied to epoxy resin

The invention relates to a method for preparing nitrogen phosphate sulfur-containing reactive flame retardant applied to epoxy resin. The preparation method comprises the following steps: sequentially adding p-hydroxy benzaldehyde, aminothiazole and a solvent into a reactor which is provided with a condensing pipe and a stirrer, and introducing inert gas to perform first reaction; adding 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide to carry out second reaction; and pumping, filtering, washing and drying the system to obtain white or light brown nitrogen phosphate sulfur-containing reactive flame retardant after the reaction is completed. The method has the advantages that 1, the synthesizing process is short, the cycle is short, post-treatment is easy, and control and industrial production are easy; 2, the prepared flame retardant contains nitrogen, phosphate and sulfur three flame-retardant elements at the same time, has a synergistic flame-retardant effect, and can be used for remarkably improving the flame retarding performance of epoxy resin; and 3, the prepared flame retardant is a reactive flame retardant, and can be used for keeping stability and mechanical performance of cured epoxy resin while improving the flame retarding effect of the cured epoxy resin.
Owner:FUJIAN NORMAL UNIV

Preparation method of regenerated fibers

The invention discloses a preparation method of regenerated fibers. The preparation method comprises the following steps: step 1, carrying out primary treatment on waste raw materials; step 2, mixing,melting and granulating; step 3, preparing graphene master batch; step 4, mixing modified polyester fiber master batch and the graphene master batch and melting; blending to obtain regenerated modified polyester fibers; step 5, loosening, carding and crossly lapping; then carrying out bundle cutting and packaging. Aiming at improving the quality of the raw materials, a raw material mixing processis carried out under a vacuum environment; the raw materials are sufficiently mixed and the quality of a finished product is improved. A phosphorus polymer, such as triphenyl phosphate or trimethyl phosphate is added by adopting a spraying manner, so that on one hand, the phosphorus polymer can be used for effectively inhibiting irreversible decomposition of the polyester fibers under a high-temperature condition and damages to ester group functional groups are avoided; on the other hand, the phosphorus polymer and graphene are subjected to oxidization reaction and have a synergistic flame-retarding effect. Furthermore, the regenerated fibers prepared by the invention have antistatic and bacterium-inhibiting effects.
Owner:JIESHOU TIANZHU TEXTILE MATERIAL

Preparation method of flame-retardant and waterproof adhesive for corrugated carton

The invention belongs to the technical field of adhesives, and particularly relates to a preparation method of a flame-retardant and waterproof adhesive for a corrugated carton. The preparation methodspecifically comprises the following steps: (1) an organic silicon modified emulsion is prepared; (2) a white prepolymer emulsion is prepared; (3) an acrylic modified flame-retardant organic siliconemulsion is prepared; and (4) 110-120 parts of the acrylic modified flame-retardant organic silicon emulsion is put into a high-speed mixer, 1.5-2.3 parts of carnallite powder, 24-27 parts of polyhalite powder and 5-7 parts of a flame retardant are added, even stirring and mixing are conducted, and then the flame-retardant and waterproof adhesive is obtained. The prepared adhesive is transparent,high in adhesion and good in stability, water-based adhesive bonding, quick drying, and acid and alkali resistance are achieved, no organic solvent is contained, the poisonless, tasteless, non-combustible, environment-friendly and pollution-free effects are achieved, and pollution-free production can be achieved. The flame-retardant and waterproof adhesive is suitable for the carton not coated andpolished, and the corrugated carton is protected very well.
Owner:马鞍山市康辉纸箱纸品有限公司

A kind of preparation method of reactive flame retardant containing phosphorus, nitrogen and sulfur in epoxy resin

The invention relates to a method for preparing nitrogen phosphate sulfur-containing reactive flame retardant applied to epoxy resin. The preparation method comprises the following steps: sequentially adding p-hydroxy benzaldehyde, aminothiazole and a solvent into a reactor which is provided with a condensing pipe and a stirrer, and introducing inert gas to perform first reaction; adding 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide to carry out second reaction; and pumping, filtering, washing and drying the system to obtain white or light brown nitrogen phosphate sulfur-containing reactive flame retardant after the reaction is completed. The method has the advantages that 1, the synthesizing process is short, the cycle is short, post-treatment is easy, and control and industrial production are easy; 2, the prepared flame retardant contains nitrogen, phosphate and sulfur three flame-retardant elements at the same time, has a synergistic flame-retardant effect, and can be used for remarkably improving the flame retarding performance of epoxy resin; and 3, the prepared flame retardant is a reactive flame retardant, and can be used for keeping stability and mechanical performance of cured epoxy resin while improving the flame retarding effect of the cured epoxy resin.
Owner:FUJIAN NORMAL UNIV

Additive for flame-retardant adhesive as well as flame-retardant adhesive and application method thereof

The invention discloses an additive for flame-retardant adhesive as well as the flame-retardant adhesive and an application method thereof. The additive for the flame-retardant adhesive is prepared from the following raw materials: molybdenum trioxide, diatomaceous earth, mineral oil, silica gel powder, ethylene bis stearamide and polyethylene glycol; the flame-retardant adhesive is prepared fromthe following raw materials: an ethylene-vinyl acetate copolymer, polyurethane resin, glyceryl tristearate, the additive for the flame-retardant adhesive, a bacteriostatic agent, a heat stabilizer anda diluent; the application method comprises the steps of adding diluent into the flame-retardant adhesive according to the required viscosity before use, evenly mixing, and detecting the viscosity ofthe flame-retardant adhesive for use. The additive for the flame-retardant adhesive is reasonable in formula and good in flame-retardant effect, does not contain phosphorus element, and does not cause pollution to the environment; the prepared flame-retardant adhesive is easy in obtaining of raw materials, has good adhesion, flame retardance, antibacterial property and stability, and is simple inpreparation method and good in mixing effect; the viscosity of the flame-retardant adhesive can be adjusted according to the needs, so that the application scope of the flame-retardant adhesive is wide.
Owner:滁州君越高分子新材料有限公司
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