Preparation technology of methyl triethoxysilane

Abstract

The invention discloses a preparation technology of methyl triethoxysilane. Methyldichlorosilane and absolute ethyl alcohol are adopted as the raw materials, and the technology comprises the four steps of alcoholysis, deacidification, separation of crude products and refinement, and comprises the following specific steps: carrying out alcoholysis reaction on methyldichlorosilane and absolute ethyl alcohol subjected to vaporization and steam stripping in an alcoholysis reaction tower; introducing the product mixture into a stripping tower for steam stripping of unreacted methyldichlorosilane and HCl, conveying the product mixture subjected to steam stripping into a neutralization kettle, and further removing HCl through the action of a neutralizer; after neutralization, filtering for salt removal to obtain a crude product of methyl triethoxysilane; carrying out rectification on the crude product for purification to obtain a colorless and transparent methyl triethoxysilane product. According to the preparation technology, the use of an organic solvent is avoided, the reaction is mild, the side reaction is less, and the product content is high; the recycling of the monomer by-product, namely, methyldichlorosilane, is effectively realized, and the additional value is increased; the devices used in the technology are conventional devices, the operation is easy to control, the pollutant emission during the whole reaction process is less, and the preparation technology is quite suitable for industrialized and enlarged production.

Description

technical field [0001] The invention relates to a preparation process of organosilane, in particular to a preparation process of methyltriethoxysilane. Background technique [0002] Methyltriethoxysilane is a common organosilicon material widely used in the rubber and pharmaceutical industries, mainly as a crosslinking agent for room temperature vulcanized silicone rubber, a glass fiber coupling It is used as an end-capping agent for siloxane polymers, and is also one of the important raw materials for the production of silicone resin, benzyl silicone oil, and waterproofing agent. [0003] At present, the conventional preparation process of methyltrialkoxysilane is to prepare methyltrichlorosilane and ethanol through esterification reaction, and generate hydrogen chloride gas at the same time. However, during the alcoholysis reaction between methyltrichlorosilane and alcohol, the substitution reaction of the third chloro group in methyltrichlorosilane is very difficult, and...

AI Technical Summary

Problems solved by technology

In the production process, usually accompanied by the formation of about 3% to 5% of the by-product methyl hydrogen dichlorosilane, these by-products currently have no effective recovery method, it is a pity to discard them in vain

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