Method of recovering fluorine resource in process of processing low-grade bauxite by chemical floatation method
A chemical flotation and bauxite technology, applied in the directions of alumina/aluminum hydroxide, ammonium halide, silicon oxide, etc., can solve the problems of resource and energy consumption, improve the recovery rate, reduce the cost, and the treatment process is simple and easy row effect
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[0030] Example 1
[0031] see figure 1 , the first embodiment of the present invention provides a method for recovering fluorine resources from a chemical flotation process for treating low-quality bauxite, comprising the following steps:
[0032]Chemical flotation desiliconization: provide the low-grade bauxite raw ore shown in Table 1, place it in a crusher for crushing, and then place the crushed low-grade bauxite in a grinder for grinding to obtain The particle size is 100 mesh low-grade bauxite particles; 10.00 g of the 100-mesh low-grade bauxite particles are placed in a fluidized bed reactor, and hydrogen fluoride gas is passed into the fluidized bed reactor at 110 ° C, The reaction was carried out for 30 min to obtain a desiliconized solid residue and a gas product containing silicon fluoride; the desiliconized solid residue was washed with clean water and filtered to obtain 6.969g of high-quality bauxite product. X-ray fluorescence analysis was used to analyze: SiO ...
Example Embodiment
[0037] Example 2
[0038] The second embodiment of the present invention provides a process for removing silicon from low-grade bauxite by chemical flotation, which is different from the first embodiment in that:
[0039] In the step of removing silicon by chemical flotation, the reaction temperature of the low-grade bauxite particles and hydrogen fluoride gas was 70° C., and the reaction was performed for 15 minutes to obtain 5.400 g of high-grade bauxite products. X-ray fluorescence analysis was used to analyze: SiO in high-quality bauxite products 2 The content is 1.41%, the removal rate of silicon is 97.65%, the content of fluorine is 23.41%, and the Al 2 O 3 The content is 68.53%.
[0040] In the step of gas absorption and ammonolysis, the gas product is passed into the absorption tower at -4kPa, and the gas product is hydrolyzed at 80°C, and the content of the material in the ammonolysis kettle is neutralized after ammonolysis. The pH was 8 and aged at 80°C for 1.5 h...
Example Embodiment
[0042] Example 3
[0043] The third embodiment of the present invention provides a process for removing silicon from low-grade bauxite by chemical flotation, which is different from the first embodiment in that:
[0044] In the chemical flotation desilicon step, the reaction temperature of the low-grade bauxite particles and the hydrogen fluoride gas was 20° C., and the reaction was performed for 20 min to obtain 5.410 g of high-grade bauxite products. X-ray fluorescence analysis was used to analyze: SiO in high-quality bauxite products 2 The content is 5.19%, the removal rate of silicon is 91.33%, the content of fluorine is 19.80%, and the Al 2 O 3 The content is 65.20%.
[0045] In the step of gas absorption and ammonolysis, the gas product is passed into the absorption tower at -5kPa, and the gas product is hydrolyzed at 78°C. pH was 8 and aged at 78°C for 2 hours.
[0046] In the step of recovering fluorine resources, the fluorine-containing filtrate is concentrated u...
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