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Carbon fiber reinforced halogen-free flame retardant polypropylene composite material and preparation method thereof

A flame-retardant polypropylene and composite material technology, applied in the field of polymer materials, can solve the problems of fast flame propagation rate, health hazards, and large release rate, and achieve improved compatibility and adhesion, high heat resistance And the effect of corrosion resistance, good halogen-free flame retardancy

Inactive Publication Date: 2016-05-04
HEILONGJIANG XINDA ENTERPRISE GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, most polymers are flammable and combustible materials, which have a large release rate, high calorific value, fast flame propagation rate, and are not easy to extinguish when burned. Sometimes they also produce dense smoke and toxic gases, causing harm to the environment and human health. Life safety poses a huge threat; currently flame retardant materials mainly include organic and inorganic, halogen and non-halogen; organic highly flame retardant materials are some flame retardants represented by bromine, nitrogen and red phosphorus and compounds, and inorganic Antimony trioxide, magnesium hydroxide, aluminum hydroxide, silicon series and other flame retardant systems
Most of the existing flame-retardant technologies are based on halogen-based additives. Although the prepared materials have obvious flame-retardant effects, certain halogen-based elements will volatilize when the halogen-based flame-retardant materials are heated, causing environmental pollution and affecting people's health. health hazard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The preparation method of a carbon fiber reinforced halogen-free flame-retardant polypropylene composite material is as follows:

[0026] 1) Carbon fiber surface oxidation treatment:

[0027] Mix 60kg of nitric acid, 30kg of sodium nitrate and 10kg of hydrogen peroxide, add distilled water to make a 50% solution, then heat to 60°C, soak the carbon fiber in its 40°C solution for 60min, take it out and rinse with distilled water at a temperature of 80°C After drying, the carbon fiber with surface oxidation treatment is obtained;

[0028] 2) Preparation of red phosphorus flame retardant masterbatch

[0029] Mix 15kg of polypropylene resin, 70kg of red phosphorus, 12kg of zinc borate and 3kg of light stabilizer in a high-speed mixer. After mixing, the components are added to a twin screw extruder for melt blending, extrusion granulation, and drying Prepare red phosphorus flame retardant masterbatch;

[0030] 3) Mixing of raw materials

[0031] Weigh 60kg of polypropylene, 10kg of re...

Embodiment 2

[0035] The preparation method of a carbon fiber reinforced halogen-free flame-retardant polypropylene composite material is as follows:

[0036] 1) Carbon fiber surface oxidation treatment:

[0037] Mix 60kg of nitric acid, 30kg of sodium nitrate and 10kg of hydrogen peroxide, add distilled water to make a 55% solution, then heat to 70℃, soak the carbon fiber in its 60℃ solution for 120min, take it out and rinse with distilled water at a temperature of 100℃ After drying, the carbon fiber with surface oxidation treatment is obtained;

[0038] 2) Preparation of red phosphorus flame retardant masterbatch

[0039] Mix 15kg of polypropylene resin, 70kg of red phosphorus, 12kg of zinc borate and 3kg of compatibilizer in a high-speed mixer. After mixing, the components are added to a twin screw extruder for melt blending, extrusion granulation, and drying. Prepare red phosphorus flame retardant masterbatch;

[0040] 3) Mixing of raw materials

[0041] Weigh 70kg of polypropylene, 15kg of red ...

Embodiment 3

[0045] The preparation method of a carbon fiber reinforced halogen-free flame-retardant polypropylene composite material is as follows:

[0046] 1) Carbon fiber surface oxidation treatment:

[0047] Mix 60kg of nitric acid, 30kg of sodium nitrate and 10kg of hydrogen peroxide, add distilled water to make a 55% solution, then heat to 80°C, soak the carbon fiber in its 80°C solution for 180min, take it out and rinse with distilled water, at a temperature of 120°C After drying, the carbon fiber with surface oxidation treatment is obtained;

[0048] 2) Preparation of red phosphorus flame retardant masterbatch

[0049] 15kg of polypropylene resin, 70kg of red phosphorus, 12kg of zinc borate and 3kg of lubricant are fully mixed in a high-speed mixer. After mixing, the components are added to a twin screw extruder for melt blending, extrusion granulation, and drying. Obtain red phosphorus flame retardant masterbatch;

[0050] 3) Mixing of raw materials

[0051] Weigh 70kg of polypropylene, 10...

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Abstract

The invention relates to a carbon fiber reinforced halogen-free flame retardant polypropylene composite material and a preparation method thereof, belonging to the technical field of high polymer materials. The carbon fiber reinforced halogen-free flame retardant polypropylene composite material consists of the following components: polypropylene, carbon fiber, red phosphorus flame-retardant masterbatch, a dispersing agent, an antioxidant and a pigment. The preparation method of the carbon fiber reinforced halogen-free flame retardant polypropylene composite material comprises the following specific steps: 1) surface oxidation treatment on carbon fiber; 2) preparation of the red phosphorus flame-retardant masterbatch; 3) mixing of raw materials; and 4) preparation of the product. The carbon fiber reinforced halogen-free flame retardant polypropylene composite material provided by the invention not only has good halogen-free flame retardance (the oxygen index is 25 or over which reaches the UL94-0 flame retardant grade standard, but also promises low smoke generation, and thus is an environment-friendly product and meets the export requirements of environmental regulations.

Description

Technical field [0001] The invention relates to a carbon fiber reinforced halogen-free flame-retardant polypropylene composite material and a preparation method thereof, belonging to the technical field of polymer materials. Background technique [0002] In recent decades, high polymer materials such as plastics, rubber, synthetic fibers and their products have developed vigorously. They are rapidly replacing traditional steel, metal, cement and natural materials such as wood and cotton, and are widely used in industry, agriculture, and military And other sectors of the national economy. [0003] However, most polymers are flammable and combustible materials. They have a large release rate during combustion, a high heat value, a fast flame propagation rate, and are not easy to extinguish. Sometimes they also produce dense smoke and toxic gases, causing harm to the environment and humans. Life safety poses a huge threat; currently flame retardant materials mainly include organic an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L23/08C08L91/06C08K13/06C08K9/02C08K7/06C08K3/02C08K3/38C08K5/13C08K5/524
CPCC08L23/12C08L2201/02C08L2201/08C08L2201/22C08L2205/02C08L2205/025C08L2205/035C08L23/06C08L23/0853C08L91/06C08K13/06C08K9/02C08K7/06C08K2003/026C08K2003/387C08K5/13C08K5/524
Inventor 马海清刘刚林航
Owner HEILONGJIANG XINDA ENTERPRISE GRP
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