The invention belongs to the technical field of building materials and particularly relates to interface mortar with an ardealite-based hydraulicity composite cementing material as a cementing material. The interface mortar is composed of ardealite, a slag powder, coal ash, metakaolin, a copper tailing slag powder, red mud, ordinary Portland cement, aluminate cement, quartz sand, a quartz powder,chesterite, calcium bentonite, a polycarboxylate-type water reducing agent, cellulose ether and latex powder. By adopting the interface mortar, the binding property of a base wall and a heat preservation layer in a wall heat preservation system can be effectively improved, the peeling risk of the heat preservation layer of a building wall can be reduced, and environment security problems caused bypiling of industrial ardealite can be also solved. When the interface mortar is produced, a great amount of industrial solid wastes such as non-calcined ardealite, coal ash, copper tailing slag powder and red mud are used, so that the interface mortar has the outstanding advantages of being low in energy consumption, low in cost, low in emission, and the like. The interface mortar is applied to heat preservation systems of various building walls, and the like.