Composite film with photothermal conversion and heat energy storage/release functions and preparation method thereof

A composite film, photothermal conversion technology, applied in heat exchange materials, chemical instruments and methods, etc., can solve the problems of high packaging requirements, low photothermal conversion efficiency, easy leakage, etc., to achieve a small temperature change range, photothermal Low conversion efficiency, preventing leakage and aging effects

Active Publication Date: 2016-05-25
HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI
View PDF2 Cites 17 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the shortcomings of organic phase change materials such as low light-to-heat conversion efficiency, easy leakage, and high packaging requirements, and to provide a composite film with both light-to-heat conversion and thermal energy storage and release functions and its preparation method. The surface plasmon resonance effect of nano-gold and the heat

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Composite film with photothermal conversion and heat energy storage/release functions and preparation method thereof
  • Composite film with photothermal conversion and heat energy storage/release functions and preparation method thereof
  • Composite film with photothermal conversion and heat energy storage/release functions and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] In this embodiment, the composite film with functions of light-to-heat conversion and thermal energy storage and release uses polyvinyl alcohol as the main material of the film, gold nanoparticles as the light-to-heat conversion material, self-assembled and filled with organic phase change materials and evaporated water solvent, wherein the solid content of the organic phase change material PEG2000 is 5%.

[0035] In this example, the composite film with the functions of light-to-heat conversion and thermal energy storage and release is prepared according to the following method:

[0036] a. Preparation of gold nanoparticles

[0037] Add 1.25mL of 0.1M chloroauric acid aqueous solution into 50mL of ultrapure water, stir and heat to boiling, then add 750μL of 10% trisodium citrate aqueous solution, continue to reflux at 95°C for 0.5 hours, stop Stir and cool to room temperature to obtain a gold nanoparticle solution, which is stored in a refrigerator at 4°C for later use;...

Embodiment 2

[0047] The preparation method of the composite film of this embodiment is the same as that of Example 1, the amount of the added nano-gold particle solution is 10mL, the difference is that the added organic phase change material is 3.33mL of PEG2000 aqueous solution with a mass fraction of 20%. The solid content of PEG2000 in the obtained film was 40%.

[0048] After testing, when PEG2000 is used as the organic phase change material in Examples 1 and 2, the phase transition temperature of the obtained composite film is about 51-55°C.

[0049] Figure 4 It is an optical photo of the composite film prepared in this embodiment to prevent leakage. The upper figure is the original PEG2000 material, and the lower figure is the composite phase change energy storage material (PEG / PVA / Au) prepared in this embodiment. It can be seen from the figure , when the temperature of the hot stage gradually increased from 20°C to 80°C, the original PEG2000 material gradually melted and leaked, t...

Embodiment 3

[0053] The preparation method of this example is the same as that of Example 1, the amount of the added nano-gold particle solution is 10mL, the difference is that the organic phase change material is PEG1000, the addition amount is 2.63mL of PEG1000 aqueous solution with a mass fraction of 2%, and the mass fraction is 5.55mL of 2% PEG1000 aqueous solution, 1.25mL of 20% PEG1000 aqueous solution by mass fraction, 3.33mL of 20% PEG1000 aqueous solution by mass fraction, the solid content of PEG1000 in the obtained composite phase change material is 5%, 10%, 20% respectively and 40%. After testing, when PEG1000 is used as the organic phase change material in this embodiment, the phase transition temperature of the obtained composite film is about 35-40°C.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Phase transition temperatureaaaaaaaaaa
Melting pointaaaaaaaaaa
Freezing pointaaaaaaaaaa
Login to view more

Abstract

The invention discloses a composite film with photothermal conversion and heat energy storage/release functions and a preparation method thereof. The composite film is prepared by carrying out self-assembly on a main body material polyvinyl alcohol by using a trace amount of gold nanoparticles as a photothermal conversion material and adding an organic phase-change material. According to the composite film with photothermal conversion and heat energy storage/release functions, by utilizing the surface plasma resonance effect of the filled nano gold and the heat storage/heat release characteristics of the phase-change material, the composite phase-change film has the functions of photothermal conversion and heat energy storage/release, and effectively solves the problem of leakage in the organic phase-change material. The preparation method is simple to operate and accessible in raw materials, can be prepared in common chemical laboratories, and thus, can be easily popularized.

Description

1. Technical field [0001] The invention relates to a film material and a preparation method thereof, in particular to a composite film with functions of light-to-heat conversion and thermal energy storage and release and a preparation method thereof. 2. Background technology [0002] In the production process of today's society, energy, as an important support of the modern economy, is an important foundation for the survival and development of human society, and occupies an important position in the process of promoting economic and social development. Recently, the economic development level of the country and various regions has been restricted by the energy supply and security system. How to achieve long-term and effective energy sustainable development has always been an important part of the country's future development planning strategy. However, with the extensive use of energy resources, the total energy consumption continues to grow, and the resulting environmental...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L29/04C08L71/08C08K3/08C08J5/18C09K5/06
CPCC08J5/18C08J2329/04C08J2471/08C08L29/04C08L2203/16C09K5/063C08L71/00C08K3/08
Inventor 张忠平张淑东王振洋尚蒙娅
Owner HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap