Scale-inhibiting corrosion inhibitor composition, scale-inhibiting corrosion inhibitor, and applications of scale-inhibiting corrosion inhibitor

A technology of scale and corrosion inhibitor and composition, which is applied in descaling and water softening, chemical instruments and methods, water/sludge/sewage treatment, etc. and corrosion inhibition function, microorganisms and slime hazards, etc., to achieve the effect of reducing processing costs and daily maintenance workload, reducing bacterial corrosion and bacterial algae growth problems, and reducing secondary pollution problems.

Active Publication Date: 2016-06-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] CN1754840A discloses a corrosion and scale inhibitor for industrial cooling water systems, comprising acrylic acid-acrylate-sulfonate copolymer, mercaptobenzothiazole, sodium humate, lignin and water, but sodium humate and lignin The source of the element is miscellaneous, the quality is unstable, and the treatment effect is poor; CN1609020A discloses a method for treating corrosion and scale inhibition water containing polyepoxysuccinic acid, which is to use polyepoxysuccinic acid or polyepoxysuccinic acid and glucose Acid or gluconate and zinc salt (Zn 2+ ) used in conjunction with the corrosion and scale inhibition method, but polyepoxy succinic acid basically has no dispersion function and corrosion inhibition function, and it is easy to cause the deposition of zinc salts, resulting in low corrosion inhibition performance; CN101591073A discloses a non-phosphorus corrosion and scale

Method used

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  • Scale-inhibiting corrosion inhibitor composition, scale-inhibiting corrosion inhibitor, and applications of scale-inhibiting corrosion inhibitor
  • Scale-inhibiting corrosion inhibitor composition, scale-inhibiting corrosion inhibitor, and applications of scale-inhibiting corrosion inhibitor
  • Scale-inhibiting corrosion inhibitor composition, scale-inhibiting corrosion inhibitor, and applications of scale-inhibiting corrosion inhibitor

Examples

Experimental program
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Effect test

preparation Embodiment 1

[0045] This preparation example was used to synthesize the Mannich base used in the example.

[0046] In a 250ml four-neck flask equipped with a thermometer, a stirrer, a reflux condenser and a dropping funnel, add 0.1mol (11.9g) benzotriazole (AR), 0.1mol (14.15g) diethanolamine hydrochloride ( AR), 100ml of distilled water, heated to reflux, dripped 0.1mol (8.1g of 37% aqueous solution) formaldehyde solution (AR) under reflux conditions, refluxed for 5 hours after dripping, and then cooled to obtain a light yellow solution, concentrated and cooled to obtain a light yellow Crystallized and dried to obtain 1-[N,N'-bis(2-hydroxyethyl)aminomethyl]benzotriazole (R is hydrogen, referred to as product-1).

[0047] According to the above steps, benzotriazole was replaced with methylbenzotriazole to obtain 1-[N,N'-bis(2-hydroxyethyl)aminomethyl]methylbenzotriazole (R is Methyl, referred to as product-2).

[0048] According to the above procedure, replace benzotriazole with n-butylb...

Embodiment 1

[0050] Weigh 1.0g of product-1, then add 7.78g of AA / AMPS, 7.0g of PAA, 2.0g of anhydrous zinc chloride, and finally dilute with water to form a 30% by weight pharmaceutical solution, and stir evenly.

Embodiment 2

[0052] Weigh 2.0g of product-2, then add 8.88g of AA / SMAM, 8.0g of PMA, 1.0g of anhydrous zinc chloride, and finally dilute with water to form a 30% by weight pharmaceutical solution, and stir evenly.

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Abstract

The present invention discloses a scale-inhibiting corrosion inhibitor composition, a scale-inhibiting corrosion inhibitor, and applications of the scale-inhibiting corrosion inhibitor. The scale-inhibiting corrosion inhibitor composition contains 1-[N,N'-bis(2-hydroxyethyl)aminomethyl]benzotriazole or a derivative thereof, a carboxylic acid group-containing homopolymer, a sulfonic acid group-containing copolymer and a water-soluble zinc salt according to a weight ratio of 1:0.5-10:0.5-10:0.3-7.5, preferably 1:2-5:2-5:0.5-3.5. According to the present invention, the environmentally friendly scale-inhibiting corrosion inhibitor does not use phosphorus-containing compounds, non-renewable molybdates or tungstates, and the like, has characteristics of no phosphorus and no nitrogen, provides high tolerance for calcium and alkali, has characteristics of high-concentration-chlorine-ion-corrosion resistance, high-concentration-sulfate-ion-corrosion resistance and wide water quality adaptation range, and provides technical conditions for circulation water operating under high concentration multiple and sewage discharge reducing; and the scale-inhibiting corrosion inhibitor has advantages of excellent scale-inhibiting corrosion inhibition, less addition amount, simple treatment process, significant effect, and easy promotion application when the scale-inhibiting corrosion inhibitor is applied in the circulation water system.

Description

technical field [0001] The invention relates to a scale and corrosion inhibitor composition, a scale and corrosion inhibitor and applications thereof. Background technique [0002] Water is the basic condition for human survival, but water resources in the world are limited. my country's per capita water volume is only a quarter of the world's per capita water volume, and water resources are even poorer. With the rapid development of industry, the ecological balance of water has been seriously damaged day by day. In order to solve the water resource crisis and adapt to sustainable development, it is necessary to save water reasonably. The amount of cooling water in industrial water accounts for 60-80% by weight of the total water consumption. Therefore, the main goal of saving industrial water is to recycle cooling water, improve the reuse rate as much as possible, and reduce sewage discharge. However, during the use of cooling water, with the continuous circulation and c...

Claims

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Application Information

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IPC IPC(8): C02F5/12C02F5/10
Inventor 张建枚潘亚男卜少华
Owner CHINA PETROLEUM & CHEM CORP
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