Preparation method of nano cuprous iodide/polyvinyl alcohol composite conductive fiber
A technology of polyvinyl alcohol and cuprous iodide, applied in the direction of conductive/antistatic filament manufacturing, fiber chemical characteristics, single-component synthetic polymer rayon, etc., can solve the problem of destroying the equilibrium state, losing the unique function of nanoparticles and Effect and other issues, to achieve the effect of reducing the probability of mutual collision, good electrical conductivity and physical and mechanical properties, and easy to dye
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Embodiment 1
[0021] (1) Dissolve 15 grams of copper sulfate in 905 grams of water to form a copper sulfate solution, add 80 grams of polyvinyl alcohol (the variety of polyvinyl alcohol is 1799) to 92 ° C to dissolve the polyvinyl alcohol, form a transparent solution, and then add Glacial acetic acid, adjust the pH to 1, and prepare a solution.
[0022] (2) Dissolve 15 grams of sodium thiosulfate and 30 grams of potassium iodide in 885 grams of water to form a sodium thiosulfate solution, add 80 grams of polyvinyl alcohol (the variety of polyvinyl alcohol is 1799) to 95 ° C to make polyethylene Dissolved in alcohol to obtain solution b.
[0023] (3) Mix 500 grams of solution a and 500 grams of solution b, raise the temperature to 80° C. and react for 30 minutes to obtain the cuprous iodide / polyvinyl alcohol spinning stock solution.
[0024] (4) Use a 0.08mm spinneret to filter the spinning dope under pressure, defoam, pass through a metering pump and a filter at 50°C, and spray it out from...
Embodiment 2
[0026] (1) Dissolve 30 grams of copper sulfate in 890 grams of water to form a copper sulfate solution, add 80 grams of polyvinyl alcohol (the variety of polyvinyl alcohol is 1799) to it and raise the temperature to 92°C to dissolve the polyvinyl alcohol, form a transparent solution and add Glacial acetic acid, adjust the pH to 2, and prepare a solution.
[0027] (2) Dissolve 15 grams of sodium thiosulfate and 30 grams of potassium iodide in 885 grams of water to form a sodium thiosulfate solution, add 80 grams of polyvinyl alcohol (the variety of polyvinyl alcohol is 1799) to the phase and heat up to 95 ° C to make polyvinyl alcohol Vinyl alcohol was dissolved to obtain solution b.
[0028] (3) Mix 400 grams of solution a and 800 grams of solution b, raise the temperature to 90°C and react for 10 minutes to obtain the cuprous iodide / polyvinyl alcohol spinning stock solution.
[0029] (4) Use a 0.08mm spinneret to filter the spinning dope under pressure, defoam, pass through ...
Embodiment 3
[0031] (1) Dissolve 45 grams of copper sulfate in 790 grams of water to form a copper sulfate solution, add 160 grams of polyvinyl alcohol (the variety of polyvinyl alcohol is 1788) to it and heat up to 50°C to dissolve the polyvinyl alcohol, forming a transparent solution and then adding Glacial acetic acid, adjust the pH to 2, and prepare a solution.
[0032] (2) Dissolve 15 grams of sodium thiosulfate and 30 grams of potassium iodide in 885 grams of water to form a sodium thiosulfate solution, add 160 grams of polyvinyl alcohol (the variety of polyvinyl alcohol is 1788) to 55 ° C to make polyethylene Alcohol dissolved and dissolved to obtain b solution.
[0033] (3) Mix 300 grams of solution a and 900 grams of solution b, raise the temperature to 75°C and react for 60 minutes to obtain the cuprous iodide / polyvinyl alcohol spinning stock solution.
[0034] (4) Use a 0.1mm spinneret to filter the spinning dope under pressure, defoam, pass through a metering pump and a filter...
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