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Method for producing aluminum oxide by means of granulating and sintering of low-grade bauxite

A low-grade bauxite and bauxite technology, applied in the field of smelting, can solve the problems of high production cost, complex and huge production system, complicated process flow, etc., and achieves reduction of production cost and investment in plant construction, and obvious economic benefits. , the effect of reducing the difficulty of operation

Active Publication Date: 2016-07-20
开曼铝业(三门峡)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the only way to industrially process low-grade bauxite is traditional sintering technology. However, due to its complex process and high energy consumption, the production cost remains high. At present, the sintering production line in my country is basically in a state of shutdown.
[0004] Although according to the characteristics of my country's bauxite resources, some scientific research institutes and enterprises have developed technologies such as series and mixed methods to reduce alkali consumption and improve the recovery rate of alumina, but both methods require sintering. This has caused a series of problems such as complex and huge production system, increased infrastructure investment, high energy consumption, difficulty in control, and poor product quality. The economy is not good, so it is gradually reduced or stopped.

Method used

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  • Method for producing aluminum oxide by means of granulating and sintering of low-grade bauxite
  • Method for producing aluminum oxide by means of granulating and sintering of low-grade bauxite
  • Method for producing aluminum oxide by means of granulating and sintering of low-grade bauxite

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Experimental program
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Effect test

Embodiment 1

[0037] Table 1: Bauxite Composition

[0038]

[0039] Table 2: Limestone Composition

[0040]

[0041] First, crush bauxite (composition as shown in Table 1) and limestone (composition as in Table 2) to 2-5 mm respectively, then grind them to a particle size of -0.074 mm and account for more than 85%, and crush the coke powder to 1-5 mm. 3mm. Then fully mix bauxite powder, limestone powder, coke powder, and soda ash powder according to the mass ratio of dry powder: bauxite 35: limestone 26: soda ash 6: coke powder 8, and then prepare lye, which is a circulating sodium aluminate solution , the concentration is Na 2 O510g / L, αk=14, the batching moisture that obtains is 30%, and alkali ratio is 1, and calcium ratio is 2.

[0042] Put the prepared material into the mixer for the first mixing, and the first mixed material enters the secondary mixer, and the secondary mixer machine is sprayed with lye at the same time, and the amount is 3 / 17 of the ingredient amount; The g...

Embodiment 2

[0053] Table 3: Bauxite composition

[0054]

[0055] First, crush bauxite (composition as shown in Table 3) and limestone (composition as in Table 2) to 2-5 mm respectively, then grind them to a particle size of -0.074 mm and account for more than 85%, and crush the coke powder to 1-5 mm. 3mm. Then bauxite powder, limestone powder, coke powder, and soda ash powder are fully mixed according to the ratio of bauxite 40: limestone 30: soda ash 10: coke powder 10 according to the dry powder mass ratio, and the concentration of the lye is Na 2 O550g / L, αk=20, the batching moisture that obtains is 28%, and alkali ratio is 1, and calcium ratio is 2.

[0056] Put the prepared material into the mixing machine for the first mixing, and the mixed material enters the secondary mixing machine, and the secondary mixing machine sprays the lye that accounts for 13 / 87 of the batching lye at the same time. The granulation is carried out in the mixer, and the particle distribution is 3-8mm....

Embodiment 3

[0064] Table 4: Bauxite composition

[0065]

[0066] First, crush bauxite (composition as shown in Table 4) and limestone (composition as in Table 2) to 2-5 mm respectively, then grind them to a particle size of -0.074 mm and account for more than 85%, and crush the coke powder to 1-5 mm. 3mm. Then bauxite powder, limestone powder, coke powder, and soda ash powder are fully mixed according to the dry powder mass ratio of bauxite 45: limestone 35: soda ash 15: coke powder 12%, and then prepare lye with a concentration of Na 2 O550g / L, αk=20, and the lye is divided into two parts by volume, and the distribution ratio is 90:10. The ingredient moisture is 26%, the alkali ratio is 1, the calcium ratio is 2, and the coke powder ratio is 12%.

[0067] Put the prepared material together with 90% lye into the mixer for the first mixing, and the first mixed material enters the secondary mixer, and the secondary mixer sprays the remaining 10% lye at the same time , Carry out granu...

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Abstract

The invention provides a method for producing aluminum oxide by means of granulating and sintering of low-grade bauxite.The method comprises the following steps that sodium carbonate, coke powder and alkali liquor are added to bauxite and limestone for blending, all the materials are added into a blender mixer for granulation, the finished granule products are sintered on a sintering machine, water or correction liquor is added to pulverized clinker for dissolution, obtained slag is reversely washed 5-7 times with water, and washing liquor serves as the correction liquor; a solution and sodium aluminate crystals are mixed and dissolved, desilicication is conducted, aluminum hydroxide crystal seeds are added for seed precipitation decomposition, and a seed precipitation mother solution is subjected to evaporation and salt elimination in two steps.According to the method, for the defect that low-grade bauxite is difficult to refine, the sintering technology of the smelting field is combined and utilized, the whole seed precipitation technology is provided, the technological processes of a technological process is shortened by one third or above, the seed precipitation decomposition rate is comprehensively calculated and increased to 90% or above, the total recovery rate of aluminum oxide reaches 90% or above, the operation difficulty is reduced, the equipment and personnel investment is reduced, and the energy consumption is reduced.

Description

technical field [0001] The invention belongs to the field of smelting, and in particular relates to a method for smelting bauxite by a pellet method. Background technique [0002] my country's bauxite resource grade (aluminum-silicon ratio) is low, and the production process of traditional sintering method not only makes the alumina production process complicated, but also increases the difficulty and production cost of alumina production. Therefore, at present, most enterprises in my country only use the Bayer process. For low-grade ores, if they are directly processed by the Bayer process, it will result in high alkali consumption, poor dissolution rate, and a sharp increase in cost, especially for bauxite in my country. It also contains silicon minerals such as illite, which cannot be removed by simple pre-desilication. These minerals are prone to reactions during the preheating process of the slurry, and sodium-silicon slag is precipitated on the heat exchange surface, wh...

Claims

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Application Information

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IPC IPC(8): C01F7/14C01F7/02
CPCC01F7/02C01F7/14
Inventor 张广麻树春
Owner 开曼铝业(三门峡)有限公司
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