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Hydrogen production reaction with controllable hydrogen production speed

A reaction and speed technology, applied in the chemical industry, can solve problems such as affecting the hydrogen production rate, and achieve the effect of prolonging the service life and high purity

Inactive Publication Date: 2016-08-03
ZHEJIANG GEELY HLDG GRP CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the influence of the hydrogen production rate due to the difference in alkalinity in the traditional aluminum water hydrogen production method
When the pH is too high, the hydrogen generation rate is too fast, so that it cannot be controlled artificially. The present invention proposes a hydrogen production reaction that can control the hydrogen production rate. Alkali is added during the hydrogen production process of the aluminum hydrogen production agent and the slow release agent. Non-toxic solid catalyst, which can effectively control the rate and time of hydrogen production, so that hydrogen can be produced at a uniform speed for use

Method used

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  • Hydrogen production reaction with controllable hydrogen production speed

Examples

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Effect test

Embodiment 1

[0025] A solid catalyst in a hydrogen production reaction that can control the hydrogen production rate is mainly a mixture of sodium hydroxide and sodium bicarbonate, wherein the mass fraction of sodium hydroxide is 50% and the mass fraction of sodium bicarbonate is 50%. The mass fraction of aluminum powder in the hydrogen production agent is 79%, the rest of the sustained-release agent and other components account for 21%, and the buffer is mixed with 5% magnesium stearate and 95% sodium carboxymethyl cellulose Composition, the ratio of hydrogen generator to solid catalyst is 1:0.5.

[0026] The above mixture is processed into flakes by stirring, tableting and other processes, and packed in non-woven fabrics. When in use, mix the non-woven bag wrapped with hydrogen-generating agent and catalyst with room temperature water at a ratio of 1:10, and the hydrolysis reaction lasts for about 160 minutes.

Embodiment 2

[0028] A solid catalyst in a hydrogen production reaction capable of controlling the hydrogen production rate is mainly a mixture of sodium hydroxide, sodium bicarbonate and calcium oxide. Among them, the mass percentage of sodium hydroxide is 40%, the mass percentage of sodium bicarbonate is 30%, and the mass percentage of calcium oxide is 30%; the mass fraction of aluminum powder in the hydrogen production agent is 80%, and the rest of the slow-release agent and other components account for 20% , the buffering agent is composed of magnesium stearate with a mass fraction of 1% and sodium carboxymethyl cellulose with a mass percentage of 99%, and the ratio of hydrogen-generating agent and solid catalyst is 1:0.3.

[0029] The above mixture is processed into flakes by stirring, tableting and other processes, and packed in non-woven fabrics.

[0030] When in use, mix the non-woven bag wrapped with hydrogen-producing agent and catalyst with room temperature water at a ratio of 1:...

Embodiment 3

[0032] A solid catalyst in a hydrogen production reaction that can control the hydrogen production rate is mainly a mixture of sodium hydroxide and calcium oxide, wherein the mass fraction of sodium hydroxide is 70% and the mass fraction of sodium bicarbonate is 30%. The mass fraction of aluminum powder in the hydrogen production agent is 90%, the rest of the sustained-release agent and other components account for 10%, and the buffering agent is mixed with 10% by mass of magnesium stearate and 90% by mass of sodium carboxymethyl cellulose Composition, the ratio of hydrogen generator to solid catalyst is 1:0.2.

[0033] The above mixture is processed into flakes by stirring, tableting and other processes, and packed in non-woven fabrics. When in use, mix the non-woven bag wrapped with hydrogen-generating agent and solid catalyst with room temperature water at a ratio of 1:5, and the hydrolysis reaction lasts for about 160 minutes.

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Abstract

The invention belongs to the technical field of chemical engineering and provides a hydrogen production reaction with the controllable hydrogen production speed to solve the problem that the hydrogen production rate is affected due to different degrees of alkalinity in a traditional aluminum water hydrogen production method and the problem that manual control cannot be achieved due to the high hydrogen production speed generated when PH is too high.The hydrogen production reaction includes the process that a hydrogen production agent generates a hydrolysis reaction under the effect of a solid catalyst.The alkaline solid catalyst is added in the process of mixed hydrogen production of a hydrogen-from-aluminum agent and a sustained-release agent, the hydrogen production rate and time period can be effectively controlled, and hydrogen is generated at a uniform speed for use.

Description

technical field [0001] The invention belongs to the technical field of chemical industry, and in particular relates to a hydrogen production reaction capable of controlling the hydrogen production speed. Background technique [0002] At present, hydrogen energy (fuel cell) is considered to be the first choice to solve carbon emissions, but because infrastructure such as hydrogen supply stations seriously restricts its development, it is urgent to develop efficient, safe and rapid online hydrogen supply technology. [0003] The production of hydrogen can be achieved through different technical means, including electrolytic hydrogen production, pyrolysis hydrogen production, photochemical hydrogen production, radioactive hydrolysis hydrogen production, chemical hydrogen production and biological hydrogen production and so on. At present, most of the hydrogen is produced through natural gas steam reforming reaction or partial oxidation, but the resources are limited and a large...

Claims

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Application Information

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IPC IPC(8): C01B3/08
CPCY02E60/36C01B3/08C01B2203/1005
Inventor 戴先逢杨建国许俊
Owner ZHEJIANG GEELY HLDG GRP CO LTD
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