High-load platinum and nickel ordered intermetallic compound as well as preparation method and use thereof

An intermetallic compound, platinum-nickel technology, applied in the field of preparation of high-load platinum-nickel ordered intermetallic compounds, can solve problems such as poor stability, high price, and reduced catalyst activity, achieve high dispersion, increase activity, reduce The effect of dosage

Active Publication Date: 2016-08-17
SHANGHAI ADVANCED RES INST CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, currently platinum as a cathode catalyst has the following problems: (1) Platinum resources are scarce and expensive; (2) Oxygen reduction activity needs to be improved; (3) Platinum has poor resistance to methanol poisoning; (4) Poor stability
However, during the high-temperature treatment of high-metal-loaded catalysts, the catalyst nanoparticles are easy to agglomerate and grow, which greatly reduces the catalyst activity.

Method used

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  • High-load platinum and nickel ordered intermetallic compound as well as preparation method and use thereof
  • High-load platinum and nickel ordered intermetallic compound as well as preparation method and use thereof
  • High-load platinum and nickel ordered intermetallic compound as well as preparation method and use thereof

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Experimental program
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Effect test

Embodiment 1

[0037] The invention provides a high-loaded platinum-nickel ordered intermetallic compound, the preparation process of which is as follows:

[0038](1) Measure 32 mL of 1 mg / mL graphene oxide (GO) aqueous dispersion in a 50 mL beaker, add 5 mg of sodium citrate dihydrate, and ultrasonically dissolve it completely for 10 min, then add 3 mL of acidic multi-walled carbon nanotubes ( MWCNTs) aqueous dispersion (containing 8 mg multi-walled carbon nanotubes).

[0039] (2) 80mg PtCl 4 and 70mg NiCl 2 ·6H 2 Dissolve O to a concentration of 0.5mol L in 10mL -1 In the ethylene glycol solution of sodium hydroxide, add 200mg of sodium glutamate sonication and dissolve in the above-mentioned ethylene glycol solution.

[0040] (3) Slowly stir the ethylene glycol solution prepared in step (2) into the graphene oxide (GO) dispersion prepared in step (1), and ultrasonically stir for 30 min at a temperature of 25°C. Then the above liquid was transferred to a 100mL polytetrafluoroethylene-...

Embodiment 2

[0048] The invention provides a high-loaded platinum-nickel ordered intermetallic compound, the preparation process of which is as follows:

[0049] (1) Measure 40 mL of 1 mg / mL graphene oxide (GO) aqueous dispersion into a 50 mL beaker, add 50 mg of sodium citrate dihydrate, and ultrasonically dissolve it completely for 30 min.

[0050] (2) 60mg PtCl 4 and 48mg NiCl 2 ·6H 2 O dissolved in 8mL to a concentration of 0.5mol L -1 In the ethylene glycol solution of sodium hydroxide, add 150mg of sodium glutamate sonication and dissolve in the above-mentioned ethylene glycol solution.

[0051] (3) Slowly stir the ethylene glycol solution prepared in step (2) into the graphene oxide (GO) dispersion prepared in step (1), and ultrasonically stir for 30 min at a temperature of 30°C. Then the above liquid was transferred to a 100mL polytetrafluoroethylene-lined reactor, and subjected to solvothermal reaction at 180°C for 12 hours to obtain a cylindrical black carbon hydrogel; washed...

Embodiment 3

[0059] The invention provides a high-loaded platinum-nickel ordered intermetallic compound, the preparation process of which is as follows:

[0060] (1) Measure 32 mL of 1 mg / mL graphene oxide (GO) aqueous dispersion in a 50 mL beaker, add 5 mg of sodium citrate dihydrate, and ultrasonically dissolve it completely for 10 min, then add 6 mL of acidic multi-walled carbon nanotubes ( MWCNTs) aqueous dispersion (containing 16 mg multi-walled carbon nanotubes).

[0061] In other embodiments of the present invention, if the mass of graphene oxide (GO) in the graphene oxide (GO) aqueous dispersion is less than that of multi-walled carbon nanotubes (MWCNTs) in the acidic multi-walled carbon nanotubes (MWCNTs) aqueous dispersion If the quality of sodium citrate dihydrate exceeds the quality of graphene oxide (GO) in the aqueous dispersion of graphene oxide (GO), the high-load platinum-nickel ordered intermetallic compound of the present invention cannot be prepared; 5 times the mass s...

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Abstract

The invention provides a high-load platinum and nickel ordered intermetallic compound. The high-load platinum and nickel ordered intermetallic compound takes three-dimensional porous carbon gel as a carrier, and is prepared by a method comprising the following steps: evenly mixing graphene oxide-containing carbon carrier precursor dispersion liquid, a metal precursor solution containing a Pt precursor and an Ni precursor, a reducing agent and sodium citrate dehydrate; then, carrying out a hydrothermal reaction to generate high-load platinum and nickel disordered alloy evenly loaded in carbon gel; after that, carrying out heat treatment under the reducing atmosphere to form the high-load platinum and nickel ordered intermetallic compound evenly loaded in the carbon gel. Compared with the traditional high-load Pt / C catalyst, the catalyst provided by the invention relatively reduces the consumption of precious metal Pt; the activity of the catalyst is improved by using an intermetallic synergistic effect, the stability of the catalyst is improved by using high dispersion of ordered metal nanoparticles, and the high dispersion characteristic of the catalyst is still maintained after ordered heat treatment is carried out on the catalyst. The invention also discloses the preparation method of the high-load platinum and nickel ordered intermetallic compound. The invention also discloses use of the high-load platinum and nickel ordered intermetallic compound.

Description

technical field [0001] The invention relates to a high-load platinum-nickel ordered intermetallic compound, in particular to a three-dimensional carbon gel-loaded high-load platinum-nickel ordered intermetallic compound. The invention also relates to a preparation method of a high-load platinum-nickel ordered intermetallic compound. The invention also relates to the use of a high-load platinum-nickel ordered intermetallic compound. Background technique [0002] With the continuous development of human society, the global energy crisis has gradually become prominent, and the direct use of fossil energy has caused serious pollution to the earth's environment, threatening the living quality of the earth's creatures. Therefore, it is imminent to develop a clean and efficient energy industry. Direct methanol fuel cell is a device that converts the chemical energy of fuel into electrical energy through an electrochemical reaction. Its fuel source is abundant, cheap, easy to store...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/89
CPCB01J23/892B01J35/0013B01J35/0066
Inventor 杨辉王亚蒙邹志青黄庆红邹亮亮
Owner SHANGHAI ADVANCED RES INST CHINESE ACADEMY OF SCI
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