Rare earth-itaconic acid monocrystalline silicon solar cell surface texture liquid and preparation method thereof

A technology of silicon solar cells and itaconic acid single crystals, applied in the field of solar cells, can solve problems such as poor reaction uniformity, high price of isopropanol, and fast volatilization speed, and achieve fast reaction speed, small particles, and high recycling rate Effect

Inactive Publication Date: 2016-09-28
CHINALAND SOLAR ENERGY
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Problems solved by technology

[0003] At present, chemical etching is the most commonly used method for surface texture of single crystal silicon, and the commonly used texturing liquid is NaOH / isopropanol system, but isopropanol is expensive, volatilizes quickly, costs high and is not conducive to environmental protection
Patent 201010161287.8 discloses a monocrystalline silicon additive texturing solution, which is composed of alkaline corrosion solution, surfactant and organic acid or salt, does not contain isopropanol and is fast and efficient, but it has the problem of poor uniformity of reaction, which is easy to cause After texture, the pyramids on the silicon surface are too large and local over-corrosion, etc., the quality of the silicon wafers needs to be further improved

Method used

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Embodiment Construction

[0014] A rare earth-itaconic acid monocrystalline silicon solar cell surface texturing liquid is prepared from the following components by weight (kg):

[0015] Itaconic acid 0.1, cerium nitrate 0.05, styrene 1.5, 5% ammonium persulfate solution 1, emulsifier OP-10 0.1, sodium lauryl sulfate 0.1, dodecafluoroheptylpropyltrimethoxysilane 0.1, hydrogen Sodium oxide 3, citric acid 0.3, hydroxypropyl methylcellulose 0.05, water 100.

[0016] A preparation method of rare earth-itaconic acid monocrystalline silicon solar cell surface texture liquid, comprising the following steps:

[0017] (1) Weigh raw materials by weight, first add sodium lauryl sulfate to 1 / 3 weight of water and stir evenly, then slowly add the mixture of styrene and dodecafluoroheptylpropyltrimethoxysilane and stir for 0.5h , and finally slowly add ammonium persulfate solution dropwise and stir at 70°C for 2 hours, keep warm for 3 hours and then cool to obtain a composite emulsion;

[0018] (2) Add itaconic ac...

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Abstract

The invention discloses a rare earth-itaconic acid monocrystalline silicon solar cell surface texture liquid. The texture liquid is prepared from the following raw materials in parts by weight: 0.1-0.2 of itaconic acid, 0.05-0.1 of cerium nitrate, 1.5-2.5 of styrene, 1-2 of 5-10% ammonium persulfate solution, 10 0.1-0.15 of emulsifier OP, 0.1-0.2 of sodium dodecyl sulfate, 0.1-0.15 of dodecafluoroheptyl-propyl-trimethoxysilane, 3-5 of sodium hydroxide, 0.3-0.5 of citric acid, 0.05-0.1 of hydroxyl propyl methylcellulose, and 100-120 of water. According to the invention, the silicon chip texture liquid has moderate corrosion, small thinning amount, stable properties, high repetition utilization rate, has even sized suede pyramids, small granular, rapid reaction speed, excellent quality stability, and excellent product uniformity.

Description

technical field [0001] The invention relates to the technical field of solar cells, in particular to a rare earth-itaconic acid monocrystalline silicon solar cell surface texture liquid and a preparation method thereof. Background technique [0002] As the world's energy crisis becomes more serious, solar energy has become the most potential alternative energy source, and a solar cell is an electronic component that directly converts solar energy into electrical energy. The main problem hindering the development of solar cell technology is its high manufacturing cost. At present, in order to reduce the cost of monocrystalline silicon solar cells and improve the photoelectric conversion efficiency, silicon surface texturing is the easiest and most efficient method. Texture, also known as velvet, uses the principle of light trapping to make the incident light reflect multiple times to prolong its propagation path on the surface of the battery, thereby improving the light abso...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/18C30B33/10
CPCC30B33/10H01L31/18Y02P70/50
Inventor 程晓民李尚荣王可胜孟祥法郭万东袁艺琴
Owner CHINALAND SOLAR ENERGY
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