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Graphene composite material for photoconversion and energy storage and preparation method

A technology of composite materials and graphite materials, applied in the field of graphene composite materials and preparation, can solve problems such as uneven dispersion, high equipment requirements, and cost reduction, and achieve the effects of uniform particle size, low cost, and cost reduction.

Active Publication Date: 2016-10-26
齐河智谷产业发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method combines the two processes of mechanical exfoliation and nanomaterial compounding into one, which greatly reduces the cost and simplifies the process. It is suitable for continuous industrial production processes, compatible with the process of mechanical exfoliation of graphene, and also solves the problem of graphene and oxides. Particles are easy to agglomerate, the two are unevenly dispersed, the preparation process is complicated, and the equipment requirements are high. It is suitable for some companies with existing foundations to directly put into production.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Put 500g flake graphite into 1000g concentration and be in the aniline chlorate electrolyte solution of 20 mg / L, let stand for 1 day, allow the cation in the electrolyte solution to infiltrate between described graphite material layers, form intercalated graphite, filter and separate and take out all Describe intercalation graphite, 250g intercalation graphite and 2.5g magnesium carbonate blending are put into continuous screw reaction extruder, obtain extruding solid product, adopt sieve hole to screen out particle diameter and be the graphene of 10~20nm and magnesium carbonate powder body. Next, under the protection of nitrogen gas, the graphene and magnesium carbonate powders were added to a continuous screw reaction extruder, the temperature of the continuous screw reaction extruder was set to 300°C, the extrusion pressure was 20 MPa, and aniline chloride The acid salt and magnesium carbonate are decomposed by heat, and the decomposed carbon dioxide and ammonia gas ...

Embodiment 2

[0025] Put 500g flake graphite into 1000g concentration and be in the aniline chlorate electrolyte solution of 20 mg / L, let stand for 1 day, allow the cation in the electrolyte solution to infiltrate between described graphite material layers, form intercalated graphite, filter and separate and take out all Describe intercalation graphite, 250g intercalation graphite and 2.5g magnesium carbonate blending are put into continuous screw reaction extruder, obtain extruding solid product, adopt sieve hole to screen out particle diameter and be the graphene of 10~20nm and magnesium carbonate powder body. Next, under the protection of nitrogen gas, the graphene and magnesium carbonate powders were added to a continuous screw reaction extruder, the temperature of the continuous screw reaction extruder was set to 300°C, the extrusion pressure was 20 MPa, and aniline chloride The acid salt and magnesium carbonate are decomposed by heat, and the decomposed carbon dioxide and ammonia gas ...

Embodiment 3

[0027] Put 500g of expanded graphite into 1000g concentration of phenyl quaternary ammonium chlorate electrolyte solution of 20 mg / L, let stand for 1 day, allow the cations in the electrolyte solution to infiltrate between the graphite material layers to form intercalated graphite, filter Isolate and take out described intercalated graphite, put 250g intercalated graphite and 2.5g magnesium carbonate blend into continuous screw reaction extruder, obtain extruded solid product, adopt sieve hole to screen out particle diameter and be the graphene of 50~60nm and Magnesium carbonate powder. Next, under the protection of nitrogen gas, add graphene and magnesium carbonate powder into the continuous screw reaction extruder, set the temperature of the continuous screw reaction extruder to 300 ° C, extrusion pressure 20 MPa, phenyl quaternary ammonium The chlorate and magnesium carbonate are thermally decomposed, and the decomposed carbon dioxide and ammonia gas are released to obtain ...

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PUM

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Abstract

The invention discloses a graphene composite material for photoconversion and energy storage and a preparation method. The method comprises the steps of: employing graphite as a raw material, firstly, infiltrating phenyl ammonium salt cations between graphite layers; introducing positively charged impurities between the graphite layers through the electrophilic effect of a pi bond between the graphite layers, blending the positively charged impurities and a metal cation salt and carrying out ion exchange reaction on a benzyl ammonium salt and the metal cation salt; and decomposing the salt through warming to obtain nano metal oxide particles under the protection of an inert gas. The problems that graphene and the oxide particles are easily agglomerated and cannot be evenly dispersed, the preparation technology is complicated, the equipment requirement is high and the like in the prior art are solved. Two processes of mechanical stripping and nano material compounding are merged into one, so that the cost is greatly reduced; the technology is simplified; and the preparation method is suitable for a continuous industrial production technology, compatible with a technology for mechanically stripping the graphene and suitable for partial established companies for direct production.

Description

technical field [0001] The invention relates to the technical field of composite material preparation, in particular to a graphene composite material for light conversion and energy storage and a preparation method. Background technique [0002] Graphene is considered an ideal material for its large specific surface area, excellent electrical and thermal conductivity and low thermal expansion coefficient, especially its good electrical conductivity and large specific surface. There are also important uses. The blending of graphene and oxide powder doped polymer materials has increasingly become a research hotspot in the field of functional polymer materials, and graphene and oxide powder are important functional additives. [0003] Chinese Patent Publication No. 103804877A provides a method for preparing a polymer material with electrical conductivity and light conversion and energy storage functions. In this method, graphene and titanium dioxide doped system powder and res...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/583B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00H01M4/583Y02E60/10
Inventor 陈庆曾军堂叶任海陈兵
Owner 齐河智谷产业发展有限公司
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