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Method for separating vitamin B12 and propionic acid from fermentation liquid

A technology for fermentation broth and vitamins is applied in the field of separating vitamin B12 and propionic acid, which can solve the problems of limited production efficiency and inability to obtain high-purity propionic acid, and achieve the effects of fast separation, improved production efficiency, and fast speed.

Inactive Publication Date: 2016-11-16
何颖
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The device is a batch production, the production efficiency is limited, and the device only realizes the enrichment of propionic acid, but cannot obtain high-purity propionic acid

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] With the preservation number of CCTCC No.M 207015 Propionibacterium freudenii NX-4, inoculated in the culture medium, the culture medium is: glucose 20g / L, yeast powder 5g / L, peptone 7g / L, NaCl 6g / L, pH = 6.9, cultured at 33°C for 36 hours to obtain seed liquid; the seed liquid was inserted into the fermentation medium according to the inoculum volume of 10% of the fermentation medium volume, the fermentation medium was glucose 50g / L, corn steep liquor 20g / L, K 2 HPO 4 4g / L, MgSO 4 1g / L, NaCl1g / L, pH=6.9, cultured at 35°C for 42h to obtain a fermentation broth, wherein the mass fraction of propionic acid is 10-50g / L, and the mass fraction of vitamin B12 contained in the bacterial cells in the fermentation broth is 10-50mg / L.

[0034] Passing the above-mentioned fermentation broth through an ultrafiltration membrane to obtain a filtrate A and a concentrated solution B, wherein the concentrated solution B is a bacterial enrichment solution, and the vitamin B12 is extra...

Embodiment 2

[0038] With the preservation number of CCTCC No.M 207015 Propionibacterium freudenii NX-4, inoculated in the culture medium, the culture medium is: glucose 20g / L, yeast powder 5g / L, peptone 7g / L, NaCl 6g / L, pH = 6.9, cultured at 33°C for 36 hours to obtain seed liquid; the seed liquid was inserted into the fermentation medium according to the inoculum volume of 10% of the fermentation medium volume, the fermentation medium was glucose 50g / L, corn steep liquor 20g / L, K 2 HPO 4 4g / L, MgSO 4 1g / L, NaCl1g / L, pH=6.9, cultured at 35°C for 42h to obtain a fermentation broth, wherein the mass fraction of propionic acid is 10-50g / L, and the mass fraction of vitamin B12 contained in the bacterial cells in the fermentation broth is 10-50mg / L.

[0039]The above-mentioned fermentation liquid is passed through an ultrafiltration membrane to obtain a filtrate A and a concentrated solution B, wherein the concentrated solution B is a bacterial enrichment solution, and vitamin B12 is extract...

Embodiment 3

[0043] With the preservation number of CCTCC No.M 207015 Propionibacterium freudenii NX-4, inoculated in the culture medium, the culture medium is: glucose 20g / L, yeast powder 5g / L, peptone 7g / L, NaCl 6g / L, pH = 6.9, cultured at 33°C for 36 hours to obtain seed liquid; the seed liquid was inserted into the fermentation medium according to the inoculum volume of 10% of the fermentation medium volume, the fermentation medium was glucose 50g / L, corn steep liquor 20g / L, K 2 HPO 4 4g / L, MgSO 4 1g / L, NaCl1g / L, pH=6.9, cultured at 35°C for 42h to obtain a fermentation broth, wherein the mass fraction of propionic acid is 10-50g / L, and the mass fraction of vitamin B12 contained in the bacterial cells in the fermentation broth is 10-50mg / L.

[0044] Passing the above-mentioned fermentation broth through an ultrafiltration membrane to obtain a filtrate A and a concentrated solution B, wherein the concentrated solution B is a bacterial enrichment solution, and the vitamin B12 is extra...

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Abstract

The invention relates to a method for separating vitamin B12 and propionic acid from fermentation liquid. The fermentation liquid is produced by fermentation culture of propionibacterium. The method mainly comprises the steps of ultrafiltration membrane separation, breaking of thallus cell walls by a mechanical method, extraction of vitamin B12, and nanofiltration membrane or reverse osmosis membrane concentration, extraction and back extraction. The method for separating vitamin B12 and propionic acid from fermentation liquid, provided by the invention, is suitable for the fermentation liquid produced by fermentation culture of propionibacterium; the method realizes a high speed of separating vitamin B12 and propionic acid; few extracting agents are used in the extraction process, and the extracting agent rate is high, wherein the extraction rate (mass fraction) of vitamin B12 is 95.5%, and the extraction rate (mass fraction, metered by sodium propionate) of propionic acid is 94.7%; and the method is favorable for environmental protection and can increase the production benefit.

Description

technical field [0001] The invention relates to the technical field of biological fermentation and separation, in particular to a method for separating vitamin B12 and propionic acid from fermentation broth. Background technique [0002] Vitamin B12 is an important vitamin, which can be used to treat pernicious anemia and peripheral neuritis, and can be used as food additives, animal feeding additives, etc. in daily life. In industry, the production of vitamin B12 is mainly through microbial fermentation to obtain fermentation broth. After the bacteria in the fermentation broth is broken, vitamin B12 can be extracted, and the fermentation broth after removing the bacteria is often discarded, which not only causes waste, but also pollutes the environment. [0003] During the production of vitamin B12 by Propionibacterium, a by-product propionic acid is also produced, which is present in the fermentation broth. Propionic acid is an important fine chemical product and basic ch...

Claims

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Application Information

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IPC IPC(8): C07H23/00C07H1/06C07C51/42C07C53/122
CPCC07C51/42C07H1/06C07H23/00C07C53/122
Inventor 何颖
Owner 何颖