Starch-polyurethane blend garment bag and production method thereof

A polyurethane and garment bag technology, applied in the field of plastic films, can solve the problems such as hindering the wide application of starch plastics, difficult processing, and declining film mechanical properties, and achieve the effects of realizing large-scale industrial production, easy to master, and easy to popularize.

Inactive Publication Date: 2016-12-21
ANHUI MEIXIANG PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, while starch improves the degradability of plastics, on the one hand, it will cause a decrease in its physical and mechanical properties, making it difficult to process. On the other hand, it is also too hydrophilic, which is not compatible with most general-purpose resins. Poor, resulting in a significant decline in the mechanical properties of the film, poor water resistance, thus hindering the wide application of starch plastics in the process of industrialization
Polyurethane is a widely used high molecular polymer, its performance is between plastic and rubber, it contains a large number of polar hydroxyl groups, its toxicity is very low, its molecular chain structure is symmetrical and regular, it has unique strong adhesiveness and flexible film Sex, smoothness, oil resistance, solvent resistance, protective colloid, gas barrier and water resistance after special treatment, and also has a certain degree of biodegradability, under the condition of bacteria in a wet environment for 6 months It can be completely decomposed into water and carbon dioxide, which is a completely biodegradable material, but the degradation process has high requirements on the degradation environment, so the degradation rate is still relatively slow

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A starch-polyurethane blended garment bag, which weighs the following components by weight: 50 kg of polyurethane, 8 kg of calcium carbonate, 1 kg of nano-titanium dioxide, 10 kg of benzoin ethyl ether, 7 kg of nano-montmorillonite, and 1.2 kg of tetrabutyl titanate ㎏, 12 kg of ramie bone, 60 kg of corn starch, 2 kg of gelatin, 1 kg of magnesium stearate, 13 kg of acetyl tributyl citrate, 1 kg of 2,6-di-tert-butyl-4-methylphenol , 3-hydroxybenzoic acid 4kg, lauryl sulfate 1kg, plant saponin 4kg.

[0018] Made with the following specific steps:

[0019] (1) Mix cornstarch and nano-montmorillonite evenly and put them in an oven, dry them at 130°C for 120 minutes, take them out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath to 30°C, ultrasonic power is 100W), then transfer the mixed powder to a stirring tank, add tetrabutyl titanate, control the temperature at 75°C, stir at 1500 rpm for 15 minutes, then continue...

Embodiment 2

[0024] A starch-polyurethane blended garment bag, which weighs the following components: 60 kg of polyurethane, 15 kg of calcium carbonate, 4 kg of nano-titanium dioxide, 20 kg of benzoin ethyl ether, 9 kg of nano-montmorillonite, and tetrabutyl titanate 1.4kg, ramie bone 14kg, corn starch 65kg, gelatin 3kg, magnesium stearate 2kg, acetyl tributyl citrate 15kg, 2,6-di-tert-butyl-4-, methylphenol 1.5 ㎏, 6 kg of 3-hydroxybenzoic acid, 2 kg of lauryl sulfate, 6 kg of plant saponins.

[0025] Made with the following specific steps:

[0026] (1) Mix cornstarch and nano-montmorillonite evenly and put them in an oven, dry them at 130°C for 120 minutes, take them out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath to 30°C, ultrasonic power is 100W), then transfer the mixed powder to a stirring tank, add tetrabutyl titanate, control the temperature at 75°C, stir at 1500 rpm for 15 minutes, then continue to add tetrabutyl tita...

Embodiment 3

[0031] A starch-polyurethane blended garment bag, which weighs the following components: 55 kg of polyurethane, 10 kg of calcium carbonate, 3 kg of nano-titanium dioxide, 15 kg of benzoin ethyl ether, 8 kg of nano-montmorillonite, and tetrabutyl titanate 1.3kg, ramie bone 13kg, corn starch 63kg, gelatin 2kg, magnesium stearate 2kg, acetyl tributyl citrate 13kg, 2,6-di-tert-butyl-4-, methylphenol 1 ㎏, 3-hydroxybenzoic acid 5kg, lauryl sulfate 1kg, plant saponin 5kg.

[0032] Made with the following specific steps:

[0033](1) Mix cornstarch and nano-montmorillonite evenly and put them in an oven, dry them at 130°C for 120 minutes, take them out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath to 30°C, ultrasonic power is 100W), then transfer the mixed powder to a stirring tank, add tetrabutyl titanate, control the temperature at 75°C, stir at 1500 rpm for 15 minutes, then continue to add tetrabutyl titanate Esters, st...

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Abstract

The invention discloses a starch-polyurethane blend garment bag and a production method thereof. The garment bag comprises, by weight, 50-60 parts of polyurethane, 8-15 parts of calcium carbonate, 1-4 parts of nanometer titanium dioxide, 10-20 parts of benzoin ethyl ether, 7-9 parts of nanometer montmorillonite, 1.2-1.4 parts of tetrabutyl titanate, 12-14 parts of ramie bones, 60-65 parts of corn starch, 2-3 parts of gelatin, 1-2 parts of magnesium stearate, 13-15 parts of acetyl tributyl citrate, 1-1.5 parts of 2,6-di-tert-butyl-4-methylphenol, 4-6 parts of 3-hydroxybenzoic acid, 1-2 parts of lauryl sulfate and 4-6 parts of plant saponin. The garment bag is produced according to a safe formula, can be used for manufacturing food packaging bags, and has the advantages of realization of large strength, good water resistance, good oil resistance and good durability in use, facilitation of realization of large-scale industrial production, easiness in knowing, and convenience in promotion; and the garment bag automatically decomposes under the action of rich oxygen and microbes after being wasted in order to finally generate carbon dioxide and water, so the garment bag is ecologic and environmentally-friendly.

Description

technical field [0001] The invention relates to the technical field of plastic films, in particular to a starch-polyurethane blended garment bag and a preparation method thereof. Background technique [0002] In recent years, due to the increasingly serious "white pollution" caused by waste plastics that are difficult to degrade, it has attracted widespread attention from all over the world. Countries around the world have successively issued relevant laws and regulations restricting or prohibiting the use of non-degradable plastic packaging. On the other hand, because petroleum, the raw material for making traditional plastics, is a non-renewable resource, it will be exhausted with the massive use of human beings. Therefore, it is imminent to develop environmentally friendly plastics that use renewable resources as raw materials and are degradable. [0003] The use of biodegradable starch materials to prepare degradable packaging films has become a research hotspot around t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L1/02C08L3/02C08L89/00C08K13/02C08K3/26C08K3/22C08K3/34C08K5/10C08K5/098C08K5/134
CPCC08L75/04C08K2201/011C08K2201/014C08L2201/06C08L2203/16C08L2205/035
Inventor 杨雪梅王维佳
Owner ANHUI MEIXIANG PLASTIC
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