Silk-novolac-epoxy-mixed full-degradation food bag and preparing method thereof

A technology of phenolic epoxy resin and phenolic resin, applied in the field of plastic films, can solve problems such as hindering the wide application of silk plastics, declining mechanical properties of films, and difficult processing, and achieve the effects of realizing large-scale industrial production, being easy to popularize and easy to master.

Inactive Publication Date: 2017-01-04
安徽浩峯塑业有限公司
View PDF3 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, while silk improves the degradability of plastics, on the one hand, it will cause a decrease in its physical and mechanical properties, making it difficult to process. On the other hand, it is too hydrophilic and has poor compatibility with most general-purpose resins. Poor, resulting in a significant decline in the mechanical properties of the film, poor water resistance, thus hindering the wide application of silk plastics in the process of industrialization
Phenolic resin is a widely used high molecular polymer, its performance is between plastic and rubber, it contains a large number of polar group hydroxyl groups, its toxicity is very low, its molecular chain structure is symmetrical and regular, and it has unique strong adhesion, film Flexibility, smoothness, oil resistance, solvent resistance, protective colloid, gas barrier and water resistance after special treatment, and also has certain biodegradability, 6 under the condition of bacteria in wet environment It can be completely decomposed into water and carbon dioxide within a month. It is a completely biodegradable material, but the degradation process has high requirements on the degradation environment, so the degradation rate is still relatively slow.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A silk-phenolic epoxy resin blended fully degradable food bag, the following weight components are weighed: 50 kg of phenolic resin, 8 kg of calcium carbonate, 1 kg of nano-titanium dioxide, 10 kg of benzoin ether, 7 kg of nano-montmorillonite, Tetrabutyl titanate 1.2kg, ramie bone 12kg, silk 60kg, gelatin 2kg, magnesium stearate 1kg, acetyl tributyl citrate 13kg, 2,6-di-tert-butyl-4-, 1 kg of methyl phenol, 4 kg of 3-hydroxybenzoic acid, 1 kg of lauryl sulfate, 4 kg of plant saponin.

[0018] Made by the following specific steps:

[0019] (1) Mix the silk and nano-montmorillonite evenly, put it in an oven, dry it at 130°C for 120 minutes, take it out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath at 30°C). ℃, the ultrasonic power is 100W), then transfer the mixed powder to the stirring tank, add tetrabutyl titanate, control the temperature at 75 ℃, stir at 1500 rpm for 15 minutes, then continue to add tetrab...

Embodiment 2

[0024] A silk-phenolic epoxy resin blended fully degradable food bag, weighing the following components: phenolic resin 60kg, calcium carbonate 15kg, nano-titanium dioxide 4kg, benzoin ethyl ether 20kg, nano-montmorillonite 9kg , tetrabutyl titanate 1.4kg, ramie bone 14kg, silk 65kg, gelatin 3kg, magnesium stearate 2kg, acetyl tributyl citrate 15kg, 2,6-di-tert-butyl-4- , Methylphenol 1.5kg, 3-hydroxybenzoic acid 6kg, lauryl sulfate 2kg, plant saponin 6kg.

[0025] Made by the following specific steps:

[0026] (1) Mix the silk and nano-montmorillonite evenly, put it in an oven, dry it at 130°C for 120 minutes, take it out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath at 30°C). ℃, the ultrasonic power is 100W), then transfer the mixed powder to the stirring tank, add tetrabutyl titanate, control the temperature at 75 ℃, stir at 1500 rpm for 15 minutes, then continue to add tetrabutyl titanate , stirred for 15 minu...

Embodiment 3

[0031] A silk-phenolic epoxy resin blended fully degradable food bag, the following components are weighed: 55 kg of phenolic resin, 10 kg of calcium carbonate, 3 kg of nano-titanium dioxide, 15 kg of benzoin ether, and 8 kg of nano-montmorillonite , tetrabutyl titanate 1.3kg, ramie bone 13kg, silk 63kg, gelatin 2kg, magnesium stearate 2kg, acetyl tributyl citrate 13kg, 2,6-di-tert-butyl-4- ,Methyl phenol 1kg, 3-hydroxybenzoic acid 5kg, lauryl sulfate 1kg, plant saponin 5kg.

[0032] Made by the following specific steps:

[0033](1) Mix the silk and nano-montmorillonite evenly, put it in an oven, dry it at 130°C for 120 minutes, take it out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath at 30°C). ℃, the ultrasonic power is 100W), then transfer the mixed powder to a stirring tank, add tetrabutyl titanate, control the temperature at 75 ℃, stir at 1500 rpm for 15 minutes, then continue to add tetrabutyl titanate , sti...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
diameteraaaaaaaaaa
Login to view more

Abstract

The invention discloses a silk-novolac-epoxy-mixed full-degradation food bag and a preparing method thereof. The silk-novolac-epoxy-mixed full-degradation food bag is prepared from, by weight, 50-60 parts of phenolic resin, 8-15 parts of calcium carbonate, 1-4 parts of nanometer titanium dioxide, 10-20 parts of benzoin ethyl ether, 7-9 parts of nanometer montmorillonite, 1.2-1.4 parts of tetrabutyl titanate, 12-14 parts of ramie bones, 60-65 parts of silk, 2-3 parts of gelatin, 1-2 parts of magnesium stearate, 13-15 parts of acetyl citric acid three butyl ester, 1-1.5 parts of 2,6-di-tert-butyl-4-methylphenol, 4-6 parts of 3-hydroxybenzoic acid, 1-2 parts of lauryl sulfate and 4-6 parts of plant saponin. The product is produced with a safe formula, and can be used for making a food packaging bag and the like, and the product is large in strength, resistant to water and oil and durable; meanwhile, large-scale industrial production can be achieved, and the food bag and the preparing method are easy to grasp and convenient to popularize; a wasted product can be automatically decomposed under the effects of oxygen enrichment and microorganisms, carbon dioxide and water are automatically generated, and ecological environmental protection is achieved.

Description

technical field [0001] The invention relates to the technical field of plastic films, in particular to a silk-phenolic epoxy resin blended fully degradable food bag and a preparation method thereof. Background technique [0002] In recent years, due to the increasingly serious "white pollution" caused by waste plastics that are difficult to degrade, it has attracted widespread attention from all over the world. Countries around the world have successively issued relevant laws and regulations restricting or prohibiting the use of non-degradable plastic packaging. On the other hand, because petroleum, the raw material for making traditional plastics, is a non-renewable resource, it will be exhausted with the massive use of human beings. Therefore, it is imminent to develop environmentally friendly plastics that use renewable resources as raw materials and are degradable. [0003] The use of biodegradable silk materials to prepare degradable packaging films has become a researc...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L89/00C08L61/06C08L97/02C08K13/06C08K9/04C08K3/34C08K5/13C08K3/26B29C55/28B29B9/06
CPCC08L89/00B29B9/06B29C55/28C08K2201/011C08L2201/06C08L2205/025C08L2205/035C08L2205/16C08L61/06C08L97/02C08K13/06C08K9/04C08K3/346C08K5/13C08K2003/265
Inventor 汪漭
Owner 安徽浩峯塑业有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products