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A kind of production method of plasma enhanced coal-to-acetylene

A production method and plasma technology, applied in the fields of chemical instruments and methods, organic chemistry, hydrocarbons, etc., can solve the problems of large dust entrainment in the product gas, blockage of the plasma reactor, and inability to carry out work, so as to save energy. , avoid energy consumption, avoid the effect of a large number of inclusions

Active Publication Date: 2018-12-25
SOUTHWEST RES & DESIGN INST OF CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, in the coal-to-acetylene process, there are mainly the following technical bottlenecks: one is that the existing method uses coal directly into the plasma reactor to produce acetylene, and the coal is easy to coke and agglomerate at high temperature, resulting in blockage of the plasma reactor; the other is that the product in this method The amount of dust entrained in the air is large, and it is difficult to remove, which makes it impossible to carry out follow-up work

Method used

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  • A kind of production method of plasma enhanced coal-to-acetylene

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Embodiment 1

[0025] Put pulverized coal into the moving bed at a rate of 12 kg / h, carry out medium-temperature pyrolysis at 800°C, and release hydrocarbon-rich pyrolysis gas. After the pyrolysis gas is filtered and dedusted by cyclone + ceramics, semi-coke and dust content are 0.05 mg / Nm 3 Pyrolysis raw material gas, hydrogen is introduced into a plasma generator with a power of 250kw as a flow gas to form a hydrogen plasma jet, and the reaction of plasma pyrolysis to acetylene is carried out at 1700 ° C. The reaction product is heat exchanged through a coupling exchanger, and the reaction product is cooled and released. The heat is used to preheat the pulverized coal, and then heated to 800°C for medium temperature pyrolysis. After the reaction product is cooled to 50°C, it enters the purification process and uses a silica gel adsorbent loaded with 3.8% (wt) sodium ions to remove impurities such as carbon black, sulfur, phosphorus, fluorine, chlorine, etc., and the purified gas is absorbe...

Embodiment 2

[0027] Put pulverized coal into the moving bed at a rate of 12 kg / h, carry out medium-temperature pyrolysis at 800°C, and release hydrocarbon-rich pyrolysis gas. After the pyrolysis gas is filtered and dedusted by cyclone + ceramics, semi-coke and dust content are 0.05 mg / Nm 3 Pyrolysis raw material gas, hydrogen is introduced into a plasma generator with a power of 250kw as a flow gas to form a hydrogen plasma jet, and the reaction of plasma pyrolysis to acetylene is carried out at 1700 ° C. The reaction product is heat exchanged through a coupling exchanger, and the reaction product is cooled and released. The heat is used to preheat the pulverized coal, and then heated to 800°C for medium temperature pyrolysis. After the reaction product is cooled to 50°C, it enters the purification process to remove carbon black, sulfur, phosphorus, fluorine, chlorine and other impurities with silica gel adsorbent that does not support metal ions. The purified gas absorbs propadiene and vi...

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Abstract

The invention belongs to the field of chemical engineering and specifically relates to a method for producing acetylene by intensifying coal by virtue of plasma. According to the method, coal is taken as the raw material, is heated at a intermediate temperate in a moving-bed reactor and is then pyrolyzed, pyrolysis gas is sequentially subjected to cyclone dust removal and ceramic filtration dust removal, and then the content of dust in pyrolysis gas can meet a production process of plasma acetylene. After the dust removal, the pyrolysis gas enters an acetylene generator to generate acetylene, impurities such as carbon black, sulfur, phosphorus, fluorine and chlorine in the reaction products are removed by virtue of a temperature swing adsorbent through temperature swing adsorption (TSA), and the purified gas is subjected to heavy component removal, absorption and concentration, so as to obtain a byproduct, namely hydrogen. By virtue of process characteristics that the heat is realized in a cooling process of the reaction products and is absorbed in a heating process of the raw material in the technical process, the adequate application of heat in a system is realized through the coupling of heat in the technical process; and semi-coke and the pyrolysis gas are obtained by virtue of an intermediate-temperature pyrolysis manner, so that the high energy consumption caused by high-temperature pyrolysis is avoided.

Description

technical field [0001] The invention belongs to the field of chemical industry, in particular to a production method of plasma-intensified coal-based acetylene. Background technique [0002] Acetylene is an important basic raw material in the organic synthesis industry. It can be used to produce polyvinyl chloride, neoprene rubber, polyvinyl alcohol, acetylene carbon black, trichloroethylene, methyl butynol, propyne pure, etc. It can also be used as a desulfurizer for steel , also used in metal cutting and welding gases. my country is the world's largest producer of acetylene, and acetylene products are mainly obtained through the calcium carbide method. There are more than 450 calcium carbide production enterprises in my country. In 2010, the production capacity of calcium carbide was 22 million tons, and the output was 15 million tons. Based on the output of 10 million tons of closed calcium carbide, a total of 4 billion Nm of calcium carbide furnace tail gas is produced...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C1/00C07C11/24
CPCC07C1/00C07C11/24
Inventor 许光文张华西毛震波温少桦熊国焱程继光
Owner SOUTHWEST RES & DESIGN INST OF CHEM IND
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