A conductive composite packaging material and preparation method thereof
A technology of packaging materials and conductive fillers, applied in the field of electronics, to achieve the effect of simple preparation method, strong shaping ability and good flexibility
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Embodiment 1
[0039] The conductive filler of the self-encapsulating conductive composite material is BiInSnZn alloy, and the polymer matrix is 184 silica gel. Metal Bismuth (Bi), Indium (In), Tin (Sn) and Zinc (Zn) are formulated into alloys according to the mass fraction ratio of 35%, 48.6%, 16% and 0.4%, and placed in a heating chamber at a temperature of 90°C Keep the molten state in the box for standby (the preparation method of the alloy is a prior art, see patent CN103432624 A). Next, prepare 184 silica gel, and the mass ratio of liquid A to liquid B is 10:1. After mixing and stirring liquid A and liquid B, mix the silica gel and the liquid conductive filler at a volume ratio of 1:1, put it in a heating box at 90°C and stir it with a glass rod for 10 minutes (stirring speed 60 rpm). No obvious and continuous liquid metal droplets can be seen. After the liquid metal is stirred with silica gel, the continuous phase is dispersed and wrapped by silica gel to form microspheres.
[004...
Embodiment 2
[0044] The raw materials are the same as in Example 1, the volume ratio of 184 silica gel and liquid alloy mixed is 8:2, the mixed conductive compound is injected into the mold to form a block sample with a thickness of 1 cm, and it is left standing at 25°C during the standing stage 60 hours. Other operations are the same as in Example 1. Because the curing speed is slow, the metal particles settle fully, the boundary between the two phases is clear, and no transition layer can be observed.
[0045] Since the upper surface of the self-encapsulated conductive composite material is insulated and the interior is conductive, and a module with a certain thickness has been formed, the components that need to be connected to the circuit can be directly inserted into the composite material for use. Since the obtained composite material is soft and elastic, the conductive composite material can play the role of a safe and effective connection seat, and is not limited by the shape of t...
Embodiment 3
[0047] The conductive filler of the self-encapsulating conductive composite is Bi 31.6 In 48.8 sn 19.6 The alloy (melting point is 59°C) polymer base is 184 silica gel. Mix 184 silica gel and conductive filler at a volume ratio of 3:7, place it in a heating box at 90°C and stir it magnetically for 10 minutes (stirring speed 200 rpm), at this time, no obvious and continuous liquid metal can be seen with the naked eye. Drops, after the liquid metal is stirred with silica gel, the continuous phase is broken up and wrapped by silica gel to form microspheres.
[0048] The mixed compound is drawn into a syringe, injected into a rectangular mold with a length of 5 cm, a width of 1 cm, and a height of 1 cm, and then left to stand at a temperature of 100°C for 30 minutes; Let cool and unmold. The formed composite material has good flexibility. Test the obtained solid composite material with a multimeter at room temperature, and find that the resistance between any two points on th...
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Abstract
Description
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