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Modified pseudo-boehmite butadiene-acrylonitrile rubber compound cable material and preparation method thereof

A technology of boehmite nitrile and composite cable material, applied in rubber insulators, organic insulators, etc., can solve the problems of restricting the safety and service life of cables, inability to balance hardness and toughness, and intolerant of humidity, cold and heat, etc. The effect of improving aging performance, improving mechanical properties and improving electrical insulation performance

Inactive Publication Date: 2017-04-26
盛天洋
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Cable material is a general term for plastics used for wire and cable insulation and sheathing. It is made of rubber, plastic, nylon and other materials as base materials, combined with auxiliary components such as plasticizers, fillers, color masterbatches, and antioxidants. Different types of cables and The use environment has different requirements on the performance of cable materials. Most of the commercially available cable materials are not resistant to scratches and folds, are easy to corrode and oxidize the internal metal wires, have poor flame retardancy, cannot balance hardness and toughness, and are highly toxic when burned. Defects such as resistance to humidity, cold and heat restrict the safety and service life of cables

Method used

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  • Modified pseudo-boehmite butadiene-acrylonitrile rubber compound cable material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A modified pseudo-boehmite nitrile rubber composite cable material, which is prepared from the following raw materials in parts by weight (kg): nitrile rubber 50, pseudo-boehmite 30, thermoplastic polyurethane elastomer 20, brominated isobutylene - p-Methylstyrene Copolymer 30, Neopentyl Glycol Dibenzoate 10, Calcium Stearate 6, 2-Ethylhexyl Diphenyl Phosphate 30, Zinc Oxide 3, Chloropropyl Triethoxy Silane 6, terpene phenolic resin 4, pine tar 7, nanometer calcium carbonate 30, mixed caprylic monoglyceride 7, epoxyacetyl ricinoleic acid methyl ester 3, magnesium methacrylate 5, 2,4-dichloroperoxide Benzoyl Oxide 1, Active Silicon Micropowder 6, Nano Tungsten Oxide 5, Talc Powder 12, Cao Carbon Black 8.

[0017] A preparation method of modified pseudo-boehmite nitrile rubber composite cable material, comprising the following steps:

[0018] (1) Mix terpene phenolic resin, pine tar, active silicon micropowder, nano-tungsten oxide, talcum powder, and cascading carbon bla...

Embodiment 2

[0023] A modified pseudo-boehmite nitrile rubber composite cable material, characterized in that it is prepared from the following raw materials in parts by weight (kg): 55% nitrile rubber, 32.5% pseudo-boehmite, 25% thermoplastic polyurethane elastomer , Brominated isobutylene-p-methylstyrene copolymer 35, neopentyl glycol dibenzoate 11, calcium stearate 7, 2-ethylhexyl diphenyl phosphate 35, zinc oxide 4, chloropropyl Triethoxysilane 7, terpene phenolic resin 5, pine tar oil 8, nano calcium carbonate 32, mixed caprylic monoglyceride 8, epoxyacetyl ricinoleic acid methyl ester 4.5, magnesium methacrylate 6, 2, 4 -Dichlorobenzoyl peroxide 1.5, active silica powder 7.5, nano tungsten oxide 6.5, talcum powder 14, cassava carbon black 9.

[0024] The preparation method is the same as in Example 1.

Embodiment 3

[0026] A modified pseudo-boehmite nitrile rubber composite cable material, which is characterized in that it is prepared from the following raw materials in parts by weight (kg): nitrile rubber 60, pseudo-boehmite 35, thermoplastic polyurethane elastomer 30 , Brominated isobutylene-p-methylstyrene copolymer 40, neopentyl glycol dibenzoate 12, calcium stearate 8, 2-ethylhexyl diphenyl phosphate 40, zinc oxide 5, chloropropyl Triethoxysilane 8, terpene phenolic resin 6, pine tar 9, nanometer calcium carbonate 34, mixed caprylic monoglyceride 9, epoxyacetyl ricinoleic acid methyl ester 6, magnesium methacrylate 7, 2, 4 - Dichlorobenzoyl peroxide 2, activated silicon micropowder 9, nano tungsten oxide 8, talcum powder 16, cassava carbon black 10.

[0027] The preparation method is the same as in Example 1.

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PUM

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Abstract

The invention discloses a modified pseudo-boehmite butadiene-acrylonitrile rubber compound cable material and a preparation method thereof. The modified pseudo-boehmite butadiene-acrylonitrile rubber compound cable material is prepared from the following raw materials in parts by weight: 50 to 60 parts of acrylonitrile rubber, 30 to 35 parts of pseudo-boehmite, 20 to 30 parts of thermoplastic polyurethane elastomer, 30 to 40 parts of poly(isobutylene-co-p-methyl-styrene-co-p-bromomethylstyrene), 10 to 12 parts of neopentyl glycol dibenzoate, 6 to 8 parts of calcium stearate, 30 to 40 parts of 2-ethylhexyl diphenyl phosphate, 3 to 5 parts of zinc oxide, 6 to 8 parts of chloropropyl triethoxy silane, 4 to 6 parts of polyterpene phenolic resin, and the like. According to the modified pseudo-boehmite butadiene-acrylonitrile rubber compound cable material and the preparation method thereof provided by the invention, the modified pseudo-boehmite butadiene-acrylonitrile rubber is used, so that the volume resistivity of the acrylonitrile rubber is increased, and an electrical insulation property of the acrylonitrile rubber is improved; and the pseudo-boehmite treated by the chloropropyl triethoxy silane, the epoxidized methyl acetorieinoleate and the 2-ethylhexyl diphenyl phosphate is used as a filler, so that a mechanical property of the product is improved, the surface states of pseudo-boehmite particles can be well improved, the compatibility of the pseudo-boehmite particles and the acrylonitrile rubber is improved, and the ageing resistance of the acrylonitrile rubber material can be remarkably improved.

Description

technical field [0001] The invention relates to a cable material, in particular to a modified pseudo-boehmite nitrile rubber composite cable material and a preparation method thereof. Background technique [0002] With the development of my country's electric power industry and communication industry, the demand for insulating cable materials with excellent performance is also increasing. Cable material is a general term for plastics used for wire and cable insulation and sheathing. It is made of rubber, plastic, nylon and other materials as base materials, combined with auxiliary components such as plasticizers, fillers, color masterbatches, and antioxidants. Different types of cables and The use environment has different requirements on the performance of cable materials. Most of the commercially available cable materials are not resistant to scratches and folds, are easy to corrode and oxidize the internal metal wires, have poor flame retardancy, cannot balance hardness a...

Claims

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Application Information

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IPC IPC(8): C08L9/02C08L75/04C08L23/20C08L61/14C08K13/06C08K9/06C08K9/04C08K3/22C08K3/34C08K3/04B29B9/06B29C47/92H01B3/28B29C48/92
CPCC08L9/02B29B9/06B29C48/92B29C2948/9258B29C2948/92704C08K2201/011C08L2203/202C08L2205/035C08L2207/04H01B3/28C08L75/04C08L23/20C08L61/14C08K13/06C08K9/06C08K9/04C08K2003/2227C08K3/34C08K3/04
Inventor 盛天洋
Owner 盛天洋
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