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Binder resin for inorganic particle-dispersed pastes and inorganic particle-dispersed paste

A technology of binder resin and inorganic particles, which is applied in the field of binder resin and inorganic particle dispersion paste for inorganic particle dispersion paste, can solve the problems of decreased dispersibility, peeling of electrode layer, decreased MLCC capacity, etc. Excellent printability

Active Publication Date: 2017-05-24
SHOEI CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In particular, there is a problem that the film strength of the electrode layer and the adhesion of the electrode layer to the dielectric material sheet are insufficient, so defects are generated, or the electrode layer is peeled off from the interface of the dielectric layer.
In addition, there is also a problem that the dispersibility of the conductive material in the binder resin decreases due to the micronization of the conductive material, so that the formed electrode becomes non-uniform, and the capacity of the obtained MLCC decreases and the electrical short circuit is likely to occur.

Method used

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  • Binder resin for inorganic particle-dispersed pastes and inorganic particle-dispersed paste
  • Binder resin for inorganic particle-dispersed pastes and inorganic particle-dispersed paste
  • Binder resin for inorganic particle-dispersed pastes and inorganic particle-dispersed paste

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Embodiment

[0092] Hereinafter, the present invention will be described based on detailed examples. It should be noted that the binder resin of the present invention can be produced using various production methods as described below, but among these, production by (1) (two-stage mixing process) and (3) (EC mixture) is preferably used. binder resin.

[0093] [Production of adhesive resin]

[0094] (1) Samples 1-15, 37, 38, 40, 42, 44 (2-stage mixing process)

[0095] In the mixing process of the first stage and the second stage, the "first raw material" and "second raw material" shown in Table 1-1 and Table 1-2 were used respectively, and the above-mentioned The samples were produced as follows. The kind and compounding quantity of each component used for a "1st raw material" and a "2nd raw material" are shown in Table 1-1 and Table 1-2.

[0096] Polyvinyl butyral (PVB), which is polyvinyl acetal, sufficiently dried by drying under reduced pressure was dissolved in N-methylpyrrolidone...

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Abstract

Provided are a binder resin for inorganic particle-dispersed pastes, said binder resin having both good printing properties and high adhesiveness, and an inorganic particle-dispersed paste. The binder resin for inorganic particle-dispersed pastes is a resin that contains a mixture prepared by mixing X parts by mass of polyvinyl acetal with Y parts by mass of a cellulose derivative in such a manner as to satisfy the requirement 0.2<=X / (X+Y) <=0.8, wherein, when the resin is mixed with spherical nickel particles having an average particle size of 0.3[mu]m, barium titanate particles having an average particle size of 0.05 [mu]m, a nonionic surfactant, dihydroterpineol and a mineral spirit at a preset ratio and kneaded to give a paste and a strain of 0.02 and a strain of 0.2 are applied to the paste at an angular frequency of 6.284 rad / s, the phase difference value delta caused by the strains and the resultant stresses is larger than 45 degrees, and the ratio of the viscosity at a shear rate of 4 (1 / s) of the paste to the viscosity at a shear rate of 40 (1 / s) thereof is not greater than 4.5.

Description

technical field [0001] The present invention relates to a binder resin and an inorganic particle dispersion paste for an inorganic particle dispersion paste, and particularly to a binder resin and an inorganic particle dispersion paste having predetermined rheological properties. Background technique [0002] In multilayer electronic components, such as multilayer ceramic capacitors (MLCC), the increase in capacity and size are rapidly advancing. [0003] In MLCC, ceramic green sheets containing high dielectric materials such as barium titanate and layers formed of conductive paste mainly containing conductive materials, binder resins, and solvents are alternately laminated in multiple layers. After firing, a chip with dielectric layers and electrode layers stacked alternately was obtained. With the increase in the capacity of MLCCs, multilayering and thinning of each layer are required, but various manufacturing problems arise from this. In particular, there is a problem ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/22C08K3/00C08K5/09C08K5/29C08L29/14C08L71/02
CPCC08L29/14C08L71/02H01B1/22C08L1/08C09J101/08H01G4/0085H01G4/1227H01G4/30C08K2003/0862C08K2201/005C08K3/08C08K5/29C08K5/09C08K3/013C08J3/20C08K5/05C08K5/20B01F2215/0495C08K3/00C09J9/02C09J11/04C09J101/28C09J129/14H01G4/012C08K3/11C08K2003/2206
Inventor 今井崇畅照屋正祐西村浩辅
Owner SHOEI CHEM IND CO LTD
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