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A kind of preparation method of airgel fiber composite material

A fiber composite material and aerogel technology, which is applied in the field of preparation of aerogel fiber composite materials, can solve the problems of complex process, high safety and high risk, expensive construction and operation costs, etc., and achieves improved mechanical strength and good mechanical properties. Effect

Active Publication Date: 2020-03-10
LUYANG ENERGY SAVING MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high-pressure technology involved in supercritical drying is very complex in process and has high safety risks. In addition, its construction and operation costs are also extremely expensive. Therefore, the most widely used green body drying method in industrial production is atmospheric pressure. drying, but the mechanical properties of airgel fiber composites obtained by normal pressure drying are poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0022] The invention provides a kind of preparation method of airgel fiber composite material, comprises the following steps:

[0023] a) forming after mixing the raw materials to obtain an airgel cellulose blank; the raw materials include airgel or its precursor, and fibers;

[0024] b) Calcining the airgel cellulose blank to obtain an airgel fiber composite material; the temperature of the calcination is 300-1000°C.

[0025] In the present invention, the raw materials are mixed first. Wherein, the raw material includes airgel or its precursor, and fiber. The airgel includes, but is not limited to, one or more of silica aerogel, alumina aerogel, titania aerogel, zirconia aerogel and boron nitride aerogel. The airgel is preferably airgel particles, and the particle diameter of the airgel particles is preferably ≤5mm. In the present invention, the airgel precursor is a stock solution or sol for preparing airgel. Taking silica airgel as an example, its precursor can be an et...

Embodiment 1

[0050] Preparation of airgel fiberboard

[0051] 1) Preparation of biscuit: add 3kg RCF fiber, 2kg E fiber, 82kg silica airgel granules (particle size ≤ 5mm), 13kg zircon powder into a dry mixer for mixing, and mix the air The gel fiber is put into the forming mold in a fluffy state, and after compression, degassing and pressure keeping, the high aerogel fiber board green body is made.

[0052] 2) Calcination: Apply a layer of 1-2mm thick 1260°C high-temperature paint on the surface of the green body, and after natural drying, perform calcination. The calcination system is as follows:

[0053] Room temperature to 300°C: heating rate 20°C / min;

[0054] 300°C: keep warm for 5 minutes;

[0055] 300°C to 600°C: heating rate 30°C / min;

[0056] 600°C: keep warm for 10 minutes;

[0057] 600°C to 900°C: heating rate 40°C / min;

[0058] 900°C: keep warm for 5 minutes;

[0059] After the calcination is completed, an airgel fiber board is obtained.

[0060] 3) Testing: Perform perf...

Embodiment 2

[0062] Preparation of airgel fiber blanket

[0063] 1), prepare green body: according to silica airgel and RCF fiber mass ratio is 15:85, the precursor of silica airgel (orthosilicic acid containing trimethylsilane) is evenly sprayed in the cotton collector Ethanol hydrolysis solution of tetraethyl ester), co-sedimentation with RCF fibers in the cotton collector to make fluffy fiber mats containing airgel precursors, interweaving fibers with each other by double-sided needle punching machine to make airgel-containing Fiber blanket green body of glue precursor.

[0064] 2), calcining the fiber blanket green body, the calcination system is as follows:

[0065] Room temperature to 300°C: heating rate 30°C / min;

[0066] 300°C: keep warm for 10 minutes;

[0067] 300°C to 500°C: Heating rate 40°C / min;

[0068] 500°C: keep warm for 15 minutes;

[0069] After calcination, the airgel fiber blanket is obtained.

[0070] 3), testing: performance testing of the prepared airgel fiber...

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PUM

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Abstract

The invention belongs to the field of aerogel composite materials, and particularly relates to a method for preparing an aerogel fiber composite material. The method provided by the invention comprises the following steps: a) mixing raw materials and performing molding to obtain a plain aerogel fiber blank, wherein the raw materials comprise aerogel or a precursor of the aerogel, and fiber; b) calcining the plain aerogel fiber blank, thereby obtaining an aerogel fiber composite material, wherein the calcining temperature is 300-1000 DEG C. As the plain blank containing the aerogel and the fiber is calcined at specific temperature, the mechanical strength of the aerogel fiber composite material is remarkably improved. Experimental results show that the aerogel fiber composite material prepared with the method provided by the invention is good in mechanical property.

Description

technical field [0001] The invention belongs to the field of airgel composite materials, in particular to a preparation method of airgel fiber composite materials. Background technique [0002] Airgel is a lightweight nanoporous material with a spatial network structure composed of colloidal particles or polymer molecules cross-linked with each other. It has the characteristics of low density, high porosity, and large specific surface area. Its fine nanoporous network The structure enables it to effectively limit solid-state heat conduction and gaseous heat convection, so it has extremely low thermal conductivity and excellent thermal insulation performance, and has broad application prospects in aerospace, chemical, metallurgy and other fields. [0003] Pure airgel has low strength and poor toughness. Therefore, in order to improve its strength and toughness, the prior art usually combines airgel with fibers to make composite materials. The traditional production process o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/80C04B35/82C04B35/14C04B35/64C04B41/87
CPCC04B35/14C04B35/64C04B35/82C04B41/5031C04B41/5035C04B41/87C04B2235/5228C04B2235/656C04B2235/77C04B2235/9615C04B2235/96C04B2235/9607C04B41/0072
Inventor 刘超任大贵张成贺宋传涛
Owner LUYANG ENERGY SAVING MATERIALS CO LTD