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Composite electrode material and application thereof

A composite positive electrode material and composite electrode technology, applied in the field of energy materials, can solve the problems of inability to carry out large-scale industrial production, low active material loading capacity, high preparation cost, etc., and achieve suitable for large-scale industrial production and output energy density High, promote the conduction effect

Active Publication Date: 2017-08-11
TSINGHUA UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, all-solid-state lithium-ion batteries include thin-film all-solid-state lithium-ion batteries and bulk-type all-solid-state lithium-ion batteries. The large-scale industrialization process of thin-film all-solid-state lithium-ion batteries is hindered by their low energy density, low active material loading capacity, and The preparation cost is very expensive and other disadvantages
However, the large-scale all-solid-state lithium-ion battery cannot be mass-produced due to its huge interface resistance.

Method used

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  • Composite electrode material and application thereof
  • Composite electrode material and application thereof
  • Composite electrode material and application thereof

Examples

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Embodiment 1

[0062] Using the method of the embodiment of the present invention, lithium cobaltate coated with barium titanate is used as the positive electrode active material, the coating amount is 5wt.%, tantalum-doped lithium lanthanum zirconate is used as the solid electrolyte, and metal lithium is used as the negative electrode material. Solid lithium-ion battery, the specific steps are as follows:

[0063] (1) surface-treating tantalum-doped lithium lanthanum zirconate to obtain a solid electrolyte with a clean surface;

[0064] (2) Lithium cobaltate, lithium borate, and indium tin oxide conductive additive (mass ratio 6:3:1) coated with barium titanate were respectively dissolved in a solvent to prepare a positive electrode layer slurry, in which ethyl cellulose was used as a binder agent, the solvent is butyl carbitol, and the solid phase content ratio is 48wt.%.

[0065] (3) Coating and printing the positive electrode layer slurry on the surface of the solid electrolyte, and the...

Embodiment 2

[0070] Using the method of the embodiment of the present invention, pure lithium cobaltate is used as the positive electrode active material, tantalum-doped lithium lanthanum zirconate is used as the solid electrolyte, and metal lithium is used as the negative electrode material to assemble a solid lithium ion battery. The specific steps are as follows:

[0071] (1) surface-treating tantalum-doped lithium lanthanum zirconate to obtain a solid electrolyte with a clean surface;

[0072] (2) Lithium cobaltate positive electrode active material, lithium borate, indium tin oxide conductive additive, and lithium fluoride (mass ratio 5:3:1:1) were respectively dissolved in a solvent to prepare positive electrode layer slurry, wherein ethyl cellulose As a binder, the solvent is butyl carbitol, and the solid phase content ratio is 48wt.%.

[0073] (3) Coating and printing the positive electrode layer slurry on the surface of the solid electrolyte, and then heat-treating at 700 degrees;...

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Abstract

The invention discloses a composite electrode material and an application thereof. The composite electrode material comprises an electrode active material, oxide nanoparticles, a coating layer, an inorganic nano filler and a conductive agent, wherein the electrode active material comprises an electrode active raw material; the electrode active raw material is an anode active raw material or a cathode active raw material; the oxide nanoparticles are distributed on the surface of the electrode active raw material; the coating layer coats the electrode active material, and comprises an electrolyte material; the inorganic nano filler is dispersed in the electrolyte material; and the conductive agent is dispersed in the electrolyte material. An all-solid lithium ion battery prepared by the composite electrode material has the characteristics of low interfacial resistance, high safety performance, good chemical stability, high output energy density and the like.

Description

technical field [0001] The present invention relates to the field of energy materials, in particular, composite electrode materials and applications thereof, and more specifically, composite electrode materials, all-solid lithium-ion batteries and methods for preparing all-solid-state lithium-ion batteries. Background technique [0002] All-solid-state lithium-ion batteries have attracted more and more attention because of their high safety performance, high energy density, and excellent electrochemical stability. All-solid-state lithium-ion batteries are mainly composed of three parts: solid positive electrode, solid electrolyte, and solid negative electrode. Compared with commercial lithium batteries, the solid electrolyte material simultaneously plays the role of lithium salt, organic solvent and separator, thus simplifying the structure of the battery. , hinder the growth of lithium dendrites and improve the safety of the battery. In addition, all-solid-state lithium ba...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/525H01M4/62H01M10/0525H01M10/0562H01M10/058B82Y30/00
CPCB82Y30/00H01M4/366H01M4/525H01M4/624H01M4/628H01M10/0525H01M10/0562H01M10/058H01M2300/0068Y02E60/10Y02P70/50
Inventor 南策文刘亭张益博陈儒君沈洋林元华崔跃
Owner TSINGHUA UNIV
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