High-strength anti-corrosion coating as well as preparation method and application thereof
A technology for anti-corrosion coatings and anti-corrosion coatings, applied in anti-corrosion coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of anti-corrosion coatings such as poor knock resistance, shortened anti-corrosion time, and poor durability, and achieve low production costs , excellent anti-corrosion, and the effect of improving scratch resistance
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[0048] In some embodiments, the preparation method includes: adding the enhancer, synergist, and solvent into the reactor at a mass ratio of 1:0.025-2.5:20-50 and reacting at 20-100°C for 1-10 hours , after the reaction product is cooled, filter the product under reduced pressure and dry it at room temperature for 10-30 hours, then grind and sieve to finally obtain the enhancer with active groups on the surface.
[0049] In some embodiments, the synergist includes a silane coupling agent and / or a polymer compound. Since the reinforcing agent has undergone surface modification treatment, it has -OH, -NH 3 Such active functional groups enhance the binding force between the coating and the substrate, thereby greatly improving the strength of the coating and the scratch resistance of the coating compared with the prior art.
[0050] Preferably, the silane coupling agent includes 3-aminopropyltrimethoxysilane, γ-(2,3-glycidoxy)propyltriethoxysilane, γ-methacryloxypropyl Any one o...
Embodiment 1
[0069] (1) Add 7.5g nano-tungsten carbide, 18.75g 3-aminopropyltrimethoxysilane and 375g ethanol into the reaction kettle and react at 100°C for 10h. After the reaction product is cooled, filter the product under reduced pressure and store it at room temperature Dry for 30 hours, then grind and sieve, and finally obtain a surface with a large amount of -NH 3 nano tungsten carbide.
[0070] (2) Weigh 10 g of polyurethane resin, 5 g of nano zinc powder and 100 g of xylene in a 250 mL beaker, and stir for 40 min with a 1600 rpm magnetic stirrer.
[0071] (3) Add 7.5g surface with a large amount of -NH to the dispersion liquid that step (2) makes 3 Nano tungsten carbide, 6g isophorone, 9g sodium lauryl sulfate, 4.5g lauryl alcohol ester, and then stirred with a magnetic stirrer at 2000rpm for 20min to obtain a stable dispersion, that is, to obtain the high-strength anti-corrosion coating.
[0072] (4) Take the cleaned workpiece, and use brushing, spraying or dipping to make the ...
Embodiment 2
[0075] (1) Add 2g of black gemstone, 0.5g of polyacrylic acid and 90g of deionized water into the reactor and react at 60°C for 2h. After the reaction product is cooled, filter the product under reduced pressure and dry it at room temperature for 14h, then grind and sieve Points, and finally obtain a black gemstone with a large amount of -COOH on the surface;
[0076] (2) Weigh 10g polyacrylic resin, 10g nano-zinc powder, 50g n-butanol and 50g xylene in a 250mL beaker respectively, and stir for 45min with a magnetic stirrer at 1500rpm;
[0077] (3) Add 2g of black gemstone with a large amount of -COOH on the surface, 0.3g of octyltriethoxysilane, 0.20g of polyacrylamide, 0.15g of ethylene glycol monopropylene to the dispersion liquid prepared in step (2). ether, and then stirred with a 2000rpm magnetic stirrer for 20 minutes to obtain a stable dispersion, that is, to obtain the high-strength anti-corrosion coating.
[0078] (4) Take the cleaned workpiece and use brushing, spr...
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