Dielectric medium of ceramic capacitor and preparation process thereof

A technology of ceramic capacitors and dielectrics, which is applied in the direction of fixed capacitor dielectrics and components of fixed capacitors, etc. It can solve the problems of unsatisfactory dielectric constant and voltage resistance, high sintering temperature, small dielectric constant, etc., and achieve performance stability Good, low sintering temperature, high dielectric constant effect

Inactive Publication Date: 2017-09-29
HEFEI HUAGAI BIOTECH CO LTD
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  • Abstract
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  • Application Information

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Problems solved by technology

Another example is the Chinese Invention Patent Application Publication Note CN1212443A (the name of the invention is "high dielectric high performance medium temperature sintered chip type multilayer ceramic capacitor ceramic material", the patent application number is 97117286.2), although the disclosed ceramic capacitor ceramic material has a dielectric constant High (dielectric constant ≥ 16000), but poor withstand voltage (withstand voltage 700V/mm), and its components contain a certain amount of lead
Also have, Chinese invention patent application public specification CN1212444A (invention name is " high-performance mid-temperature sintered chip type multilayer ceramic dielectric capacitor ceramic material ", and the patent application number is 97117287.0), the disclosed capacitor ceramic material dielectric constant is too small (dielectric The electric constant is 3000), the dielectric loss is less than 1.5%, and the withstand voltage is low (the withstand voltage is 860V/mm), and its components contain a certain amount of lead
[0004] Although the dielectric of some ceramic capacitors does not contain lead, it is less harmful to the human body and the environment during the production, use and disposal of ceramic capacitors, but its dielectric constant is too small and/or the withstand voltage is low
For example, Chinese journal "Electronic Components and Materials" No. 5, 1989, disclosed a high

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  • Dielectric medium of ceramic capacitor and preparation process thereof

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[0025] Example 1

[0026] A dielectric for ceramic capacitors. The dielectric includes the following raw materials: BaTiO 3 40kg, SrTiO 3 10kg, BaZrO 3 10kg, CaTiO 3 8kg, MgNb 2 O 5 8kg, CeO 2 2kg, ZnO 2kg, Co 2 O 3 2kg, BaSiO 3 1kg, Gd 2 O 3 1kg.

[0027] Wherein, the BaTiO 3 It is prepared by the following process: the conventional chemical raw material BaCO 3 And TiO 2 According to the 1:1 molar ratio, the mixture is ground and mixed evenly, and then put into an alumina crucible and kept at 1100℃ for 100 minutes. The solid phase reaction synthesizes BaTiO 3 , After cooling, grind through a 150-mesh sieve for use.

[0028] The SrTiO 3 It is prepared by the following process: the conventional chemical raw material SrCO 3 And TiO 2 According to the 1:1 molar ratio, the mixture is uniformly ground and mixed, and then put into an alumina crucible and kept at 1120℃ for 100 minutes. SrTiO is synthesized by solid-phase reaction. 3 , After cooling, grind through a 150-mesh sieve for use.

[...

Example Embodiment

[0037] Example 2

[0038] A dielectric of a ceramic capacitor. The dielectric of the ceramic capacitor includes the following raw materials: BaTiO 3 50kg, SrTiO 3 15kg, BaZrO 3 15kg, CaTiO 3 10kg, MgNb 2 O 5 10kg, CeO 2 3kg, ZnO 3kg, Co 2 O 3 3kg, BaSiO 3 2kg, Gd 2 O 3 2kg.

[0039] Wherein, the BaTiO 3 It is prepared by the following process: the conventional chemical raw material BaCO 3 And TiO 2 According to the molar ratio of 1:1, grind and mix evenly, put it in an alumina crucible, keep it at 1160℃ for 125 minutes, and synthesize BaTiO by solid phase reaction 3 , After cooling, grind through a 200-mesh sieve for use.

[0040] The SrTiO 3 It is prepared by the following process: the conventional chemical raw material SrCO 3 And TiO 2 According to 1:1 molar ratio of ingredients, grind and mix evenly, put it in an alumina crucible and keep it at 1160℃ for 120 minutes, and synthesize SrTiO by solid phase reaction. 3 , After cooling, grind through a 200-mesh sieve for use.

[0041] The...

Example Embodiment

[0049] Example 3

[0050] A dielectric of a ceramic capacitor. The dielectric of the ceramic capacitor includes the following raw materials: BaTiO 3 60kg, SrTiO 3 20kg, BaZrO 3 20kg, CaTiO 3 12kg, MgNb 2 O 5 12kg, CeO 2 4kg, ZnO 4kg, Co 2 O 3 4kg, BaSiO 3 3kg, Gd 2 O 3 3kg.

[0051] Wherein, the BaTiO 3 It is prepared by the following process: the conventional chemical raw material BaCO 3 And TiO 2 According to the 1:1 molar ratio, the mixture is ground and mixed evenly, and then put into the alumina crucible and kept at 1220℃ for 130 minutes. The solid phase reaction synthesizes BaTiO 3 , After cooling, grind through a 250-mesh sieve for use.

[0052] The SrTiO 3 It is prepared by the following process: the conventional chemical raw material SrCO 3 And TiO 2 According to the molar ratio of 1:1, grind and mix evenly, put it in an alumina crucible and keep it at 1200℃ for 140 minutes, and then synthesize SrTiO by solid phase reaction. 3 , After cooling, grind through a 250-mesh sieve f...

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Abstract

The invention discloses a dielectric medium of a ceramic capacitor and a preparation process thereof and belongs to the field of capacitor manufacturing. The dielectric medium comprises the following raw materials in parts by weight: 40-60 parts of BaTiO3, 10-20 parts of SrTiO3, 10-20 parts of BaZrO3, 8-12 parts of CaTiO3, 8-12 parts of MgNb2O5, 2-4 parts of CeO2, 2-4 parts of ZnO, 2-4 parts of Co2O3, 1-3 parts of BaSiO3 and 1-3 parts of Gd2O3. The preparation process comprises the following steps of: crushing the raw materials and uniformly mixing the raw materials; then drying the raw materials and adding an adhesive for granulation to obtain granular materials; and finally, pressing the granular materials into a raw blank sheet and sintering the same to obtain the dielectric medium. The dielectric medium of the ceramic capacitor provided by the invention is high in electric constant and high in withstand voltage, and free of environmental pollution in a using process. The invention aims to provide a preparation method of the dielectric medium of the ceramic capacitor. The preparation method is relatively low in cost and free of pollution- to the environment in the preparation process.

Description

technical field [0001] The invention belongs to the field of capacitor manufacturing, and in particular relates to a dielectric of a ceramic capacitor and a preparation process thereof. Background technique [0002] Color TV, computer, communication, aerospace, missile, navigation and other fields urgently need ceramic capacitors with high breakdown voltage, good temperature stability, high reliability, miniaturization and large capacity. In order to realize the miniaturization and large capacity of ceramic capacitors, the dielectric of ceramic capacitors is required to have a high dielectric constant; in order to achieve a high breakdown voltage of ceramic capacitors, the dielectric withstand voltage of ceramic capacitors is required to be high; at the same time, with people's health and The increasing attention to environmental protection requires that the dielectric of ceramic capacitors will not cause harm to the human body and the environment during the process of prepa...

Claims

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Application Information

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IPC IPC(8): C04B35/468C04B35/622H01G4/12
CPCC04B35/4682C04B35/622C04B2235/3206C04B2235/3224C04B2235/3229C04B2235/3236C04B2235/3248C04B2235/3251C04B2235/3275C04B2235/3284C04B2235/3436H01G4/12H01G4/1218
Inventor 张安育
Owner HEFEI HUAGAI BIOTECH CO LTD
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