Improved low-smoke halogen-free cable rubber jacket and preparation method thereof

A technology for cables and rubber sleeves, applied in the field of improved low-smoke halogen-free cable rubber sleeves and their preparation, can solve problems such as limited improvement effect, and achieve the effects of good oxidation resistance, stable chemical properties and good heat resistance

Inactive Publication Date: 2017-10-17
沧州会友线缆股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this kind of cable material still reduces the influence of inorganic flame retardant materials on the mechanical properties of the cable itself by improving the ratio of coupling agent and compatibilizer, and the improvement effect is limited.

Method used

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  • Improved low-smoke halogen-free cable rubber jacket and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A method for preparing an improved low-smoke halogen-free cable rubber sleeve, comprising the following steps:

[0024] The following parts are parts by weight,

[0025] A. Use the raw materials of the following components to prepare the cable inner sleeve,

[0026] 250 parts of EPDM rubber, 440 parts of methyl vinyl silicone rubber, 45 parts of 1,3-diethyl dicarboxylate, 20 parts of tetrabutyl ammonium hydrogen phosphate, 3 parts of dimethyl Urea, 3 parts of m-carborane, 27 parts of 3-methoxybenzyl alcohol, 15 parts of 3-nitro-4-aminophenol, 6 parts of calcium sulfate, 34 parts of carbon black, 12 parts of zirconium;

[0027] B. Use the raw materials of the following components to prepare the cable jacket,

[0028] 410 parts of polyethylene, 270 parts of EVA resin, 18 parts of disodium edetate, 4 parts of dicumyl peroxide, 1 part of triethanolamine, 55 parts of tert-butyl isosulfate, 13 parts of 3-nitro-4-methylacetophenone, 7 parts of potassium bisulfate, 45 parts...

Embodiment 2

[0039] A method for preparing an improved low-smoke halogen-free cable rubber sleeve, comprising the following steps:

[0040] The following parts are parts by weight,

[0041] A. Use the raw materials of the following components to prepare the cable inner sleeve,

[0042] 250 parts of EPDM rubber, 440 parts of methyl vinyl silicone rubber, 45 parts of 1,3-diethyl dicarboxylate, 20 parts of tetrabutyl ammonium hydrogen phosphate, 3 parts of dimethyl Urea, 3 parts of m-carborane, 27 parts of 3-methoxybenzyl alcohol, 15 parts of 3-nitro-4-aminophenol, 6 parts of calcium sulfate, 34 parts of carbon black, 12 parts of zirconium;

[0043] B. Use the raw materials of the following components to prepare the cable jacket,

[0044] 410 parts of polyethylene, 270 parts of EVA resin, 18 parts of disodium edetate, 4 parts of dicumyl peroxide, 1 part of triethanolamine, 55 parts of tert-butyl isosulfate, 13 parts of 3-nitro-4-methylacetophenone, 7 parts of potassium bisulfate, 45 parts...

Embodiment 3

[0055] A method for preparing an improved low-smoke halogen-free cable rubber sleeve, comprising the following steps:

[0056] The following parts are parts by weight,

[0057] A. Use the raw materials of the following components to prepare the cable inner sleeve,

[0058] 250 parts of EPDM rubber, 440 parts of methyl vinyl silicone rubber, 45 parts of 1,3-diethyl dicarboxylate, 20 parts of tetrabutyl ammonium hydrogen phosphate, 3 parts of dimethyl Urea, 3 parts of m-carborane, 27 parts of 3-methoxybenzyl alcohol, 15 parts of 3-nitro-4-aminophenol, 6 parts of calcium sulfate, 34 parts of carbon black, 12 parts of zirconium;

[0059] B. Use the raw materials of the following components to prepare the cable jacket,

[0060] 410 parts of polyethylene, 270 parts of EVA resin, 18 parts of disodium edetate, 4 parts of dicumyl peroxide, 1 part of triethanolamine, 55 parts of tert-butyl isosulfate, 13 parts of 3-nitro-4-methylacetophenone, 7 parts of potassium bisulfate, 45 parts...

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Abstract

The invention discloses a preparation method of an improved low-smoke halogen-free cable rubber jacket. The preparation method includes following steps: A, using EPDM rubber, methyl vinyl silicon rubber, 1, 3-acetone dicarboxylic acid diethyl ester, tetrabutyl ammonium hydrogen phosphate, dimethyl urea, m-caborane, 3-methoxy benzene methanol, 3-nitro-4-aminophenol, calcium sulfate, carbon black and zirconium oxide to preparing a cable inner jacket; B, using polyethylene, EVA rersin, EDTA, dicumyl peroxide, triethanolamine, tertbutyl isosulfate, 3-nitro-4-methyl acetophenone, potassium hydrogen sulfate, dibutyl fumarate and benzoyl acetonitrile to prepare a cable outer jacket; C, socketing the cable inner jacket prepared in the step A and the cable outer jacket prepared in the step B, and filling a flame retardant between the cable inner jacket and the cable outer jacket. By the preparation method, the defects of the prior art can be overcome, and mechanical performance of cables is improved further.

Description

technical field [0001] The invention relates to the technical field of cable fire prevention, in particular to an improved low-smoke halogen-free cable rubber sleeve and a preparation method thereof. Background technique [0002] With the rapid development of the global economy and the enhancement of human awareness of environmental protection, the requirements for the quality and performance of wires and cables in various fields are getting higher and higher, and there are more and more fires caused by the aging of wires and cables. How to reduce the fire Low smoke, halogen-free, flame retardant, and environmental protection have also become the development direction of the wire and cable industry. Among them, the demand for halogen-free low-smoke flame-retardant cable materials is increasing. At present, most of the production of halogen-free low-smoke flame-retardant cable materials is to add a large amount of magnesium hydroxide or magnesium hydroxide to polyolefin subst...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L23/16C08K13/02C08K5/21C08K3/30C08K3/04C08K3/22C08L23/06C08L23/08C08K5/17C08K5/41C08K5/11C08K5/14H01B13/22H01B7/295H01B7/18
CPCC08K2003/2224C08K2003/2227C08K2003/2244C08K2003/3045C08L23/06C08L83/04C08L2201/02C08L2201/08C08L2203/202C08L2205/035H01B7/1895H01B7/295H01B13/22C08L23/16C08K13/02C08K5/21C08K3/30C08K3/04C08K3/22C08L23/0853C08K5/17C08K5/41C08K5/11C08K5/14C08K5/05
Inventor 郭振杰李宝华
Owner 沧州会友线缆股份有限公司
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