Unlock instant, AI-driven research and patent intelligence for your innovation.

Flame-retardant polyolefin compound and preparation method thereof

The technology of polyolefin and compound is applied in the field of flame retardant polyolefin compound and its preparation, which can solve the problems of poor compatibility of polyolefin, volatile organic solvent, polluting the environment and human body, etc., so as to reduce the processing temperature and facilitate dispersion. , the effect of reducing the interfacial tension

Active Publication Date: 2017-10-31
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
View PDF2 Cites 9 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, hydrotalcite and montmorillonite also have poor compatibility with polyolefins and are difficult to disperse uniformly, so surface modification is usually required
However, since the modification of hydrotalcite and montmorillonite usually needs to be carried out in organic solvents such as toluene, it has the disadvantages of low grafting rate and complicated operation, and organic solvents are volatile, pollute the environment and harm the human body during use. Harmful and other issues

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Flame-retardant polyolefin compound and preparation method thereof
  • Flame-retardant polyolefin compound and preparation method thereof
  • Flame-retardant polyolefin compound and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0023] The invention provides a kind of preparation method of flame retardant polyolefin compound, it comprises the steps:

[0024] (a) Weighing 70-120 parts by weight of polyolefin and 15-100 parts by weight of intumescent flame retardant;

[0025] (b) mixing the polyolefin and the intumescent flame retardant to obtain a dry blend, then adding the dry blend to a first extruder, and melt extruding to obtain a pre-mixture;

[0026] (c) Add the pre-mixture into the second extruder, and feed supercritical carbon dioxide into 1 / 5 to 1 / 3 of the screw of the second extruder to extrude to obtain a highly efficient halogen-free flame-retardant polyolefin composites.

[0027] In step (a), the polyolefin is at least one of polyethylene, polypropylene, ethylene-propylene rubber, ethylene-vinyl acetate copolymer, and ethylene-octene copolymer. The intumescent flame retardant is formed by mixing an acid source, a carbon source and a gas source in a mass ratio of (2-4):(0-1):(0-1). Prefe...

Embodiment 1

[0037] About 80 parts by weight of polypropylene, 23 parts by weight of ammonium polyphosphate and 6 parts by weight of pentaerythritol were weighed.

[0038] The above-mentioned raw materials are mixed by a high-speed mixer, then added to the first extruder, and melted and extruded to obtain a pre-mixture.

[0039] Add the pre-mixture in the second extruder; wherein, the temperature of the first half of the screw is set to 200°C, and the temperature of the second half of the screw is set to 185°C; about 5 parts by weight of supercritical The injection pressure of carbon dioxide was set at 18 MPa; the pressure in the second extruder was maintained at 10 MPa, and the flame-retardant polypropylene compound was obtained by extrusion and granulation.

Embodiment 2

[0041] About 90 parts by weight of polypropylene, 30 parts by weight of ethylene-octene copolymer, 30 parts by weight of melamine polyphosphate and 6 parts by weight of starch were weighed.

[0042] The above-mentioned raw materials are mixed by a high-speed mixer, then added to the first extruder, and melted and extruded to obtain a pre-mixture.

[0043] The pre-mixture is added in the second extruder; wherein, the temperature of the first half of the screw is set to 195 ° C, and the temperature of the second half of the screw is set to 190 ° C; about 6 parts by weight of supercritical For carbon dioxide, the injection pressure was set to 16MPa; the pressure in the second extruder was maintained at 12MPa, and extruded and granulated to obtain a flame-retardant polypropylene / ethylene-octene copolymer compound.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention provides a preparation method of a flame-retardant polyolefin compound. The method comprises the following steps of (a) weighing 70-120 parts of polyolefin and 15-100 parts of an intumescent flame-retardant; (b) carrying out dry mixing on the polyolefin and the intumescent flame-retardant to obtain a dry mixture, adding the dry mixture to a first extruder and carrying out melting extrusion to obtain a pre-mixture; and (c) adding the pre-mixture to a second extruder, introducing supercritical carbon dioxide to 1 / 5-1 / 3 position of a screw rod of the second extruder and carrying out melting extrusion to obtain the flame-retardant polyolefin compound. The supercritical carbon dioxide is capable of promoting uniform dispersion of the intumescent flame-retardant in polyolefin, thereby obtaining the flame-retardant polyolefin compound with excellent flame-retardant property. The invention further provides the flame-retardant polyolefin compound.

Description

technical field [0001] The invention relates to the technical field of flame-retardant polymer materials, in particular to a flame-retardant polyolefin compound and a preparation method thereof. Background technique [0002] Polyolefin materials have the advantages of abundant raw materials, low price, easy processing and molding, and superior comprehensive performance. They are widely used in agriculture, machinery, electronics, packaging, automobiles, building materials and other fields, but they are flammable and have poor flame retardancy. Therefore, flame retardant treatment is required in many applications. At present, the flame retardancy of polyolefin is mainly achieved by adding various flame retardants. Although traditional halogen-containing flame retardants have good flame retardancy, they are prone to produce a large amount of smoke and toxic gases during production and use, resulting in secondary pollution. , so it is particularly important to develop halogen-...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L23/12C08L23/08C08L3/02C08L23/06C08L23/16C08K5/523C08K3/32C08K5/053C08K5/3492C08K5/06B29C47/38B29C47/08B29C48/395
CPCB29C48/25B29C48/395C08K3/32C08K5/053C08K5/3492C08K5/34928C08K2003/323C08L23/12C08L2201/02C08L2205/02C08L2205/03C08L23/06C08L23/0853C08L23/0815C08L3/02C08L23/16C08K5/523C08K5/06Y02P20/54
Inventor 庞永艳郑文革黄朋科张利华吴飞
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More