Flame-retardant polyolefin compound and preparation method thereof
The technology of polyolefin and compound is applied in the field of flame retardant polyolefin compound and its preparation, which can solve the problems of poor compatibility of polyolefin, volatile organic solvent, polluting the environment and human body, etc., so as to reduce the processing temperature and facilitate dispersion. , the effect of reducing the interfacial tension
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[0023] The invention provides a kind of preparation method of flame retardant polyolefin compound, it comprises the steps:
[0024] (a) Weighing 70-120 parts by weight of polyolefin and 15-100 parts by weight of intumescent flame retardant;
[0025] (b) mixing the polyolefin and the intumescent flame retardant to obtain a dry blend, then adding the dry blend to a first extruder, and melt extruding to obtain a pre-mixture;
[0026] (c) Add the pre-mixture into the second extruder, and feed supercritical carbon dioxide into 1 / 5 to 1 / 3 of the screw of the second extruder to extrude to obtain a highly efficient halogen-free flame-retardant polyolefin composites.
[0027] In step (a), the polyolefin is at least one of polyethylene, polypropylene, ethylene-propylene rubber, ethylene-vinyl acetate copolymer, and ethylene-octene copolymer. The intumescent flame retardant is formed by mixing an acid source, a carbon source and a gas source in a mass ratio of (2-4):(0-1):(0-1). Prefe...
Embodiment 1
[0037] About 80 parts by weight of polypropylene, 23 parts by weight of ammonium polyphosphate and 6 parts by weight of pentaerythritol were weighed.
[0038] The above-mentioned raw materials are mixed by a high-speed mixer, then added to the first extruder, and melted and extruded to obtain a pre-mixture.
[0039] Add the pre-mixture in the second extruder; wherein, the temperature of the first half of the screw is set to 200°C, and the temperature of the second half of the screw is set to 185°C; about 5 parts by weight of supercritical The injection pressure of carbon dioxide was set at 18 MPa; the pressure in the second extruder was maintained at 10 MPa, and the flame-retardant polypropylene compound was obtained by extrusion and granulation.
Embodiment 2
[0041] About 90 parts by weight of polypropylene, 30 parts by weight of ethylene-octene copolymer, 30 parts by weight of melamine polyphosphate and 6 parts by weight of starch were weighed.
[0042] The above-mentioned raw materials are mixed by a high-speed mixer, then added to the first extruder, and melted and extruded to obtain a pre-mixture.
[0043] The pre-mixture is added in the second extruder; wherein, the temperature of the first half of the screw is set to 195 ° C, and the temperature of the second half of the screw is set to 190 ° C; about 6 parts by weight of supercritical For carbon dioxide, the injection pressure was set to 16MPa; the pressure in the second extruder was maintained at 12MPa, and extruded and granulated to obtain a flame-retardant polypropylene / ethylene-octene copolymer compound.
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