Preparation method of low-temperature graphene-based nanoborate composite material

A graphene-based, composite material technology, applied in the petroleum industry, lubricating compositions, additives, etc., can solve the problems of different control conditions and complicated preparation process, and achieve low equipment investment, simple preparation process and convenient operation Effect

Active Publication Date: 2017-12-12
QUANZHOU NORMAL UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] There are many preparation methods for graphene and related nanocomposites, but the control condit

Method used

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  • Preparation method of low-temperature graphene-based nanoborate composite material
  • Preparation method of low-temperature graphene-based nanoborate composite material
  • Preparation method of low-temperature graphene-based nanoborate composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Firstly, 100 mg of graphene oxide, 2 g of organic solvent alkylphenol, 2 g of NN dimethylacetamide and 200 g of water were mixed and then ultrasonicated. The ultrasonic dispersion time was 2 hours, and a light yellow solution with a graphene oxide concentration of 0.5 mg / ml was obtained; Then, while stirring with the motor at a temperature of 80°C, add 5g of sodium borohydride and 5g of sodium citrate, and continue to stir for 1h; then add 0.5g of hexadecyl calcium borate and 0.5g of nano-cerium borate and continue to stir for 10h; continue to stir And heat up to 160 ℃ in the reflux reactor, carry out reflux reaction, keep stirring and keep warm for 6h, turn off the heat source, suction filter while it is hot, wash, dry to obtain the graphene-based nano borate composite material, such as figure 2 shown.

Embodiment 2

[0025] Firstly, 150 mg of graphene oxide, 3 g of organic solvent alkylphenol, 5 g of NN dimethylacetamide and 200 g of water were mixed and then ultrasonicated. The ultrasonic dispersion time was 2.5 h, and a light yellow solution with a graphene oxide concentration of 0.75 mg / ml was obtained. Afterwards, while stirring the motor at a temperature of 80°C, add 6g of sodium borohydride and 6g of sodium citrate, and continue to stir for 2h; then add 1g of hexadecyl calcium borate and 1g of nano-cerium borate and continue to stir for 15h; continue to stir and In the reflux reactor, the temperature is raised to 200°C, reflux reaction is carried out, continuous stirring and insulation for 8h, the heat source is turned off, suction filtration is hot, washed, and dried to obtain a graphene-based nano borate composite material, such as image 3 shown.

Embodiment 3

[0027] First, 200 mg of graphene oxide, 5 g of organic solvent alkylphenol, 6 g of NN dimethylacetamide and 200 g of water are mixed and then ultrasonicated, and the ultrasonic dispersion time is 3 h to obtain a light yellow solution with a graphene oxide concentration of 1 mg / ml; after that While stirring with the motor at a temperature of 80°C, add 8g of sodium borohydride and 8g of sodium citrate, and continue stirring for 2 hours; then add 3g of hexadecyl calcium borate and 3g of nano-cerium borate and continue stirring for 14 hours; continue stirring and reflux Heat up the temperature in the reactor to 150°C, carry out reflux reaction, keep stirring and keep warm for 20h, turn off the heat source, suction filter while it is hot, wash, and dry to obtain the graphene-based nano borate composite material, such as figure 1 shown.

[0028] In addition, when the process parameters of the above-mentioned method are changed within the scope of the content of the invention, those ...

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Abstract

The invention discloses a preparation method of a low-temperature graphene-based nanoborate composite material. The preparation method comprises the following steps: 1) firstly, mixing graphene oxide, alkyl phenol, NN-dimethyl acetamide and water by using an ultrasonic method, and then performing ultrasonic dispersion to obtain mixed liquid; 2) adding calcium hexadecyl borate and nanometer cerium borate into the mixed liquid while stirring by using a motor, keeping the constant temperature for a certain time, continuing stirring and slowly adding sodium borohydride and sodium citrate to form a mixed solution; 3) performing a refluxing reaction in an oil bath at the reaction temperature of 150-200 DEG C while stirring by using a motor-driven stirrer, performing hot suction filtration after the reaction, washing and drying to obtain the graphene-based nanoborate composite material. By the preparation method, a solution synthesis method is adopted, the graphene oxide is reduced and the nanoborate composite material is prepared; by the preparation method, the main process is simple, the reaction condition is mild, the batch production is easily achieved and the the operation is convenient.

Description

technical field [0001] The invention specifically relates to a preparation method of a low-temperature graphene-based nano borate composite material. Background technique [0002] With the development of science and technology, new materials are playing an increasingly important role in the progress of social science and technology. Especially in recent years, the research on graphene and its composite materials has become a scientific research hotspot and the focus of product commercialization. Due to the special structure of graphene determines its unique physical and chemical properties, including good mechanical properties, anti-wear and compression properties, thermal conductivity, super conductivity, high surface area ratio, etc. Dimensional structure, can form anti-wear agent with higher anti-wear performance with corresponding nano-materials, in view of the potential application value related to this, this research mainly focuses on the research of graphene-based com...

Claims

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Application Information

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IPC IPC(8): C10M125/26C10M177/00C10N20/06C10N30/06
CPCC10M125/26C10M177/00C10M2201/041C10M2201/087C10N2020/06C10N2030/06
Inventor 陈文志潘淼杨惠山姚雅迪林志锋陈艺勇
Owner QUANZHOU NORMAL UNIV
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