Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

High-performance starch-based carbon fiber and preparation method thereof

A starch-based, carbon fiber technology, applied in the direction of fiber chemical characteristics, conjugated rayon, conjugated synthetic polymer rayon, etc., can solve the problem of increasing the force between carbon atoms, low tensile strength and modulus, etc. problem, to achieve the effect of simple preparation method, good tensile strength and tensile modulus, excellent tensile strength and tensile modulus

Inactive Publication Date: 2017-12-22
DEYANG LIJIU YUNZHI KNOWLEDGE PROPERTY OPERATIONS CO LTD
View PDF0 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the defects of low tensile strength and modulus in starch-based carbon fibers, and provide a starch-based carbon fiber and a preparation method thereof; the present invention forms a small amount of carbon-silicon bonds by introducing silicon atoms into starch-based carbon fibers, thereby The adjacent carbon atoms in the starch-based carbon fibers are bonded by silicon atoms, which increases the force between the carbon atoms and significantly increases the tensile strength and tensile modulus of the starch-based carbon fibers, which is conducive to the replacement of the starch-based carbon fibers by the polycarbonate. The popularization and application of acrylonitrile (PAN)-based carbon fiber, pitch-based carbon fiber and viscose-based carbon fiber in more fields

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] (1) Degrade and isomerize 65 parts of starch with 0.02 part of glucose isomerase and 0.01 part of amylase at 25°C for 4 hours to obtain product A;

[0030] (2) Add 1 part of ferric chloride and 1 part of copper chloride to product A, dehydrate at 105°C for 3 hours, separate and dry to obtain product B;

[0031] (3) After mixing the product B with 8 parts of paraffin, 4 parts of phthalic acid, 4 parts of oxalic acid, 15 parts of polyacrylonitrile, and 8 parts of vinyl silicone oil, use a twin-screw extruder to Carry out cross-linking polymerization reaction; obtain product C; the maximum temperature of the working area in the twin-screw extruder is set to 330°C, and the minimum temperature is set to 280°C; the residence time of the material in the extruder is controlled at 90s;

[0032] (4) Melt spinning the product C at a temperature of 330°C to obtain starch-based carbon fiber precursors;

[0033] (5) The starch-based carbon fiber precursors were subjected to the firs...

Embodiment 2

[0035] (1) Degrade and isomerize 50 parts of starch with 0.01 part of glucose isomerase and 0.01 part of amylase at 35°C for 5 hours to obtain product A;

[0036] (2) Add 1 part of ferrous chloride to product A, dehydrate at 85°C for 5 hours, separate and dry to obtain product B;

[0037] (3) Mix the product B with 5 parts of paraffin, 5 parts of hydroquinone, 5 parts of ethylene glycol, 20 parts of polyacrylonitrile, and 5 parts of vinyl silicone oil, and then use a twin-screw extruder to carry out extruding Copolymerization reaction; product C is obtained; the maximum temperature of the working area in the twin-screw extruder is set to 320°C, and the minimum temperature is set to 260°C; the residence time of the material in the extruder is controlled at 120s;

[0038] (4) Melt spinning the product C at a temperature of 350°C to obtain starch-based carbon fiber precursors;

[0039] (5) The starch-based carbon fiber precursors are subjected to the first pre-oxidation at 240°C...

Embodiment 3

[0041] (1) Degrade and isomerize 80 parts of starch with 0.03 parts of glucose isomerase and 0.02 parts of amylase at 35°C for 2 hours to obtain product A;

[0042] (2) Add 1 part of ferric chloride, 1 part of ferrous chloride and 1 part of hydrochloric acid to product A, dehydrate at 120°C for 1 hour, separate and dry to obtain product B;

[0043] (3) Mix product B with 10 parts of paraffin, 2 parts of ethylene glycol, 3 parts of glycerol, 10 parts of polyacrylonitrile, and 10 parts of vinyl silicone oil, and then use a twin-screw extruder to process Cross-linking polymerization reaction; product C is obtained; the maximum temperature of the working area in the twin-screw extruder is set to 340°C, and the minimum temperature is set to 290°C; the residence time of the material in the extruder is controlled at 60s;

[0044] (4) Melt spinning the product C at a temperature of 310°C to obtain starch-based carbon fiber precursors;

[0045] (5) The starch-based carbon fiber precurso...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a high-performance starch-based carbon fiber and a preparation method thereof. The starch-based carbon fiber is prepared from the following raw materials in parts by weight: 50-80 parts of starch, 5-10 parts of paraffin, 1-3 parts of dehydration catalyst, cross-linking 3-8 parts of agent, 0.01-0.03 parts of biological enzyme, 10-20 parts of polyacrylonitrile, 5-10 parts of vinyl silicone oil; by introducing silicon atoms into starch-based carbon fibers, a small amount of carbon-silicon bonds are formed, so that starch-based Adjacent carbon atoms in carbon fibers are bonded by silicon atoms, which increases the force between carbon atoms, significantly improves the tensile strength and tensile modulus of starch-based carbon fibers, and is conducive to starch-based carbon fibers replacing polyacrylonitrile ( PAN)-based carbon fiber, pitch-based carbon fiber and viscose-based carbon fiber are popularized and applied in more fields.

Description

technical field [0001] The invention relates to the field of carbon fiber materials, in particular to a high-performance starch-based carbon fiber and a preparation method thereof. Background technique [0002] Carbon fiber (CF for short) is a new fiber material with high strength and high modulus with a carbon content of more than 95%. It is a microcrystalline graphite material obtained by stacking organic fibers such as flake graphite microcrystals along the axial direction of the fiber, and undergoing carbonization and graphitization. Carbon fiber has many excellent properties, such as high axial strength and modulus, low density, high specific performance, no creep, ultra-high temperature resistance in non-oxidizing environment, good fatigue resistance, specific heat and electrical conductivity between non-metal and Between metals, the coefficient of thermal expansion is small and has anisotropy, good corrosion resistance, good X-ray permeability, good electrical and th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): D01F9/22D01F9/16D01F9/24D01F8/18D01F8/08D01F8/16C08J3/24C12P19/24C12P19/14C12P19/12C12P7/58C07D307/46C08L33/20C08L91/06C08L83/07
CPCD01F9/22C07D307/46C08J3/246C08J2333/20C08J2383/07C08J2391/06C08J2433/20C08J2483/07C08J2491/06C12P7/58C12P19/12C12P19/14C12P19/24D01F8/08D01F8/16D01F8/18D01F9/16D01F9/24
Inventor 李红梅
Owner DEYANG LIJIU YUNZHI KNOWLEDGE PROPERTY OPERATIONS CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products