Multifiber reinforced magnesia-alumina-carbon refractory material and preparation process thereof

A refractory material and preparation technology, applied in the field of refractory materials, can solve problems such as easy oxidation, pollution, high heat loss molten steel, etc., and achieve the effect of enhancing oxidation resistance, broad application prospects, and improving mechanical properties

Active Publication Date: 2017-12-26
营口宏远耐火材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to solve the problems of easy oxidation, high heat loss and easy pollution to molten steel during the use of magnesia-carbon refractory materials in the field of metallurgical steelmaking, and provides a multi-stage dead-burned magnesia fine powder, liquid Multi-fiber reinforced magnesium with high oxidation resistance, strong thermal conductivity and strong corrosion re...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] A preparation process for a multi-fiber reinforced magnesium-aluminum-carbon refractory material, the preparation process comprising the following preparation steps:

[0038] 1) Preparation of nano-nickel modified resin: a) Dissolve nickel chloride hexahydrate into ethanol solution to make solution A, the concentration of nickel ions in solution A is 0.11mol / L;

[0039] b) Add sodium hydroxide and hydrazine hydrate to the solution A obtained in a) and stir, stir and react at room temperature at 900r / min for 170min, and rinse the black particles obtained by filtering with filter paper with deionized water and ethanol to obtain nano-nickel powder ;

[0040] c) Add the nano-nickel obtained in b) into ethanol, disperse it evenly by 80kW ultrasonic vibration, then add it to the phenolic resin solution and mix for 55min, and vacuum dry to remove the excess ethanol in the nano-nickel modified resin to obtain nano-nickel modified resin.

[0041] 2) Mix A-grade dead-burned mag...

Embodiment 2

[0047] A preparation process for a multi-fiber reinforced magnesium-aluminum-carbon refractory material, the preparation process comprising the following preparation steps:

[0048] 1) Preparation of nano-nickel modified resin: a) Dissolve nickel chloride hexahydrate into ethanol solution to make solution A, the concentration of nickel ions in solution A is 0.12mol / L;

[0049] b) Add sodium hydroxide and hydrazine hydrate to the solution A obtained in a) and stir, stir and react at room temperature at 1000r / min for 190min, and rinse the black particles obtained by filtering with filter paper with deionized water and ethanol to obtain nano-nickel powder ;

[0050] c) Add the nano-nickel obtained in b) into ethanol, disperse it evenly by 80kW ultrasonic vibration, then add it to the phenolic resin solution and mix for 70min, and vacuum dry to remove excess ethanol in the nano-nickel modified resin to obtain nano-nickel modified resin.

[0051] 2) Mix A-grade dead-burned magnes...

Embodiment 3

[0057] A preparation process for a multi-fiber reinforced magnesium-aluminum-carbon refractory material, the preparation process comprising the following preparation steps:

[0058] 1) Preparation of nano-nickel modified resin: a) Dissolve nickel chloride hexahydrate into ethanol solution to make solution A, the concentration of nickel ions in solution A is 0.115mol / L;

[0059] b) Add sodium hydroxide and hydrazine hydrate to the solution A obtained in a) and stir, stir and react at room temperature at 1000r / min for 180min, and rinse the black particles obtained by filtering with filter paper with deionized water and ethanol to obtain nano-nickel powder ;

[0060] c) Add the nano-nickel obtained in b) into ethanol, disperse it uniformly by 85kW ultrasonic vibration, then add it to the phenolic resin solution and mix for 60min, and vacuum dry to remove excess ethanol in the nano-nickel modified resin to obtain nano-nickel modified resin.

[0061] 2) Mix A-grade dead-burned ma...

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PUM

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Abstract

The invention relates to a multifiber reinforced magnesia-alumina-carbon refractory material and a preparation process thereof. A refractory brick is prepared from the following raw materials in percentages by weight: 8 to 10% of A-grade dead-burnt magnesia fine powder, 5 to 7% of B-grade dead-burnt magnesia fine powder, 19 to 22% of C-grade dead-burnt magnesia fine powder, 11 to 13% of D-grade dead-burnt magnesia fine powder, 8 to 10% of E-grade dead-burnt magnesia fine powder, 15 to 18% of F-grade dead-burnt magnesia fine powder, 7 to 8% of a binder A, 5.5 to 7.5% of a binder B, 1.3 to 1.7% of a binder C, 6 to 8% of metal aluminum powder and 0.3 to 0.5% of an additive. According to the invention, products and raw materials are safe and non-toxic, and may not cause harmful effects to users and the environment; good physical properties and wide application prospects in the fields of metallurgy and steelmaking are realized; the refractory material is improved in mechanical properties of the substrate thereof by mixed application of dead-burnt magnesia fine powder with different particles sizes, and is superior to a substrate material prepared from the dead-burnt magnesia fine powder with single particle size; the fiber structure greatly improves the mechanical properties of the material; meanwhile, carbon is difficult to be diffused into molten steel after carbon nanotube fiber is formed, so the pollution of the refractory materials to the molten steel is greatly reduced.

Description

technical field [0001] The invention relates to a refractory material, in particular to a multi-fiber reinforced magnesium-aluminum-carbon refractory material with physical properties such as high density, high compressive strength, high volume stability and erosion resistance and a preparation process thereof. Background technique [0002] Magnesia-carbonaceous materials are very suitable for oxygen top-blown converters, electric arc furnaces and ladles in the iron and steel industry. Magnesium oxide-carbonaceous materials currently on the market have good thermal shock resistance and corrosion resistance due to their high flake graphite content, high thermal conductivity, low expansion coefficient, and poor wettability by molten steel. However, high carbon content will cause poor oxidation resistance, high heat loss, drop in molten steel temperature, and increased carbon content in molten steel, which will seriously affect the production of high-quality steel. [0003] On...

Claims

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Application Information

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IPC IPC(8): C04B35/043C04B35/80
CPCC04B35/043C04B35/803C04B2235/402C04B2235/444C04B2235/48C04B2235/5224C04B2235/77C04B2235/96C04B2235/9607
Inventor 胡宏平
Owner 营口宏远耐火材料有限公司
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