Ferromagnetic nano carrier material/gene complex and preparation method and application thereof
A nanocarrier and ferromagnetic technology, which is applied in the field of carrier/gene complex preparation to achieve the effects of high reproducibility, strong popularization and low cost
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Embodiment 1
[0054] Embodiment 1: the synthesis of ferric oxide nanocube (FION)
[0055] Accurately weigh 0.706g of iron acetylacetonate, 0.4g of biphenyl-4-carboxylic acid and 1.27g of oleic acid, then add 10.4g of high boiling point solvent dibenzyl ether, and mix evenly under stirring. The mixed solution was evacuated at room temperature for 1 hour, and then the temperature was raised to about 290°C at a rate of 20°C / min using a temperature controller, and then kept heating at this temperature for 0.5h, and then rapidly cooled to room temperature, and the product was washed with ethanol Resuspended in chloroform and stored, the resulting nanocubes had a size of 22-25 nm.
Embodiment 2
[0056] Embodiment 2: the synthesis of ferric oxide nanocube (FION)
[0057] Accurately weigh 0.706g of iron acetylacetonate, 0.4g of biphenyl-4-carboxylic acid and 1.27g of oleic acid, then add 10.4g of high boiling point solvent dibenzyl ether, and mix evenly under stirring. The mixed solution was evacuated at room temperature for 1 hour, then the temperature was raised to about 300°C at a rate of 20°C / min using a temperature controller, and then kept heating at this temperature for 1 hour, and then rapidly cooled to room temperature, and the product was washed with ethanol and reassembled. Suspended in chloroform for preservation, the resulting nanocube size is 30-35nm.
Embodiment 3
[0058] Embodiment 3: the synthesis of ferromagnetic nano-carrier material
[0059] 1) The iron ferric oxide nano-cube (FION), polycaprolactone (PCL) and oleic acid (OA) synthesized in Example 1 are added successively a mixed solvent of 4mL chloroform and tetrahydrofuran in a mass ratio of 10:2:1 (vol / vol=1), stirring at 400 rpm for 2 h under mechanical stirring.
[0060] 2) Weigh the excess PEI, after it is fully dissolved in the mixed solvent of 4mL chloroform and THF (vol / vol=1), add it dropwise to the mixed solution in the above 1) under stirring, and continue to stir at 400 rpm for 2h .
[0061] 3) Add 10 mL of double-distilled water to the mixed solution in the above 2), and ultrasonicate the probe for 5 minutes at a power of 500 W to obtain a uniform brown emulsion. Evaporate under reduced pressure on a rotary evaporator to remove the organic solvent, and obtain iron that is stably dispersed in the aqueous phase system. Magnetic Nanomaterials. After centrifuging the o...
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