A kind of acrylic resin for water-based 3D printing ink and preparation method thereof
An acrylic resin, 3D printing technology, applied in the field of 3D printing materials, can solve problems such as pollution and need to be improved, achieve the effect of not easy to collapse and deform, improve speed and printing efficiency, and solve the effect of insufficient response
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Embodiment 1
[0037] Embodiment 1, a kind of acrylic resin for water-based 3D printing ink
[0038] The acrylic resin for water-based 3D printing ink consists of the following components and parts by mass: 38 parts of monomer mixture, 0.2 parts of initiator, 15 parts of n-butanol, 3.6 parts of glycidyl methacrylate, particle size of 10nm 5 parts of fumed silicon dioxide, 1 part of carboxymethyl chitosan active material and 30 parts of deionized water; the monomer mixture consists of methyl methacrylate, acrylic acid and isooctyl acrylate in mass ratio 55:7: 44, the initiator is composed of benzoyl peroxide and trimethylacetic acid in a mass ratio of 12:5.
[0039] The preparation method of described carboxymethyl chitosan active substance is:
[0040] (1) get carboxymethyl chitosan, add the mixed solution that is formed by dimethyl fumarate and water by the volume ratio of 1:1, the quality of mixed solution is 16 times of above-mentioned carboxymethyl chitosan quality, Stir for 2h, add Tw...
Embodiment 2
[0047] Embodiment 2, a kind of acrylic resin for water-based 3D printing ink
[0048] The acrylic resin for water-based 3D printing ink consists of the following components and parts by mass: 45 parts of a monomer mixture, 0.5 parts of an initiator, 36 parts of n-butanol, 4.8 parts of glycidyl methacrylate, and a particle size of 30 nm 12 parts of fumed silicon dioxide, 2 parts of carboxymethyl chitosan active substances and 40 parts of deionized water; the monomer mixture consists of methyl methacrylate, acrylic acid and isooctyl acrylate in mass ratio 62:3: 36, the initiator is composed of benzoyl peroxide and trimethylacetic acid in a mass ratio of 16:3.
[0049] The preparation method of described carboxymethyl chitosan active substance is:
[0050] (1) get carboxymethyl chitosan, add the mixed solution that is formed by dimethyl fumarate and water by the volume ratio of 1:1, the quality of mixed solution is 16 times of above-mentioned carboxymethyl chitosan quality, Sti...
Embodiment 3
[0057] Embodiment 3, a kind of acrylic resin for water-based 3D printing ink
[0058] The acrylic resin for water-based 3D printing ink consists of the following components and parts by mass: 42 parts of monomer mixture, 0.4 parts of initiator, 26 parts of n-butanol, 4.2 parts of glycidyl methacrylate, and the particle size is 20nm 8 parts of fumed silicon dioxide, 1.6 parts of carboxymethyl chitosan active substances and 34 parts of deionized water; the monomer mixture consists of methyl methacrylate, acrylic acid and isooctyl acrylate in mass ratio 58:5: 42, the initiator is composed of benzoyl peroxide and trimethylacetic acid in a mass ratio of 15:4.
[0059] The preparation method of described carboxymethyl chitosan active substance is:
[0060] (1) get carboxymethyl chitosan, add the mixed solution that is formed by dimethyl fumarate and water by the volume ratio of 1:1, the quality of mixed solution is 16 times of above-mentioned carboxymethyl chitosan quality, Stir f...
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