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Polyvinyl alcohol water-soluble 3D (Three-dimensional) printing support consumable item and preparation method thereof

A polyvinyl alcohol, 3D printing technology, applied in the field of 3D printing consumables, can solve the problems of high price, low quality, less variety, etc., to improve the supportability, improve the printability, and solve the effect of poor bonding

Inactive Publication Date: 2018-01-09
ZHEJIANG FLASHFORGE 3D TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at present, foreign soluble support materials have few varieties and high prices, while domestic related products are of low quality, so the development and research of FDM soluble support materials is of great significance to expand the application range of FDM technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0034] A method for preparing a polyvinyl alcohol water-soluble 3D printing support consumable as described above, comprising the following steps:

[0035] 1) According to the formula, add polyvinyl alcohol and plasticizer into the mixer, and mix for 5-8 minutes at the speed of the mixer at 500-2000r / min to obtain the mixed material; then put the material in an oven at 60°C until the The plasticizer is completely absorbed;

[0036] 2) According to the formula, add the mixture obtained in step (1), antioxidant, heat stabilizer, fluidity modifier, and melt bonding enhancer into the mixer, under the condition that the mixer speed is 500-3000r / min Mix for 5-10 minutes to obtain the mixed material;

[0037] 3) Dry the mixture obtained in step (2) and add it to a twin-screw extruder for blending and extrusion. The temperature of the extruder is controlled at 160-200°C and the screw speed is 60-100r / min. Air cooling and pelletizing to obtain polyvinyl alcohol modified pellets;

[...

Embodiment 1

[0041] A polyvinyl alcohol water-soluble 3D printing support consumable, the raw material formula is: Taiwan Changchun Chemical Industry 0588 polyvinyl alcohol 500g, polyethylene glycol / glycerol blend (1:1) 90g, tetrakis [β-(3, 5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester / tris(2,4-di-tert-butylphenyl) phosphite blend (1:1) 2g, magnesium hydroxide 15g, Ethylene bis stearic acid amide 5g, terpene resin 2.5g.

[0042]The preparation process of polyvinyl alcohol water-soluble 3D printing support material: add the blend of polyvinyl alcohol and polyethylene glycol / glycerol (1:1) into a high-speed mixer, the speed is 1000r / min, and the mixing time is 5min. Place the mixed material in an oven at 60°C and dry for 4-6 hours until the plasticizer is completely absorbed; put the mixed material obtained above and other raw materials in the formula into a high-speed mixer at a speed of 2000r / min, and the mixing time is 5 minutes; mix the mixed material The premix is ...

Embodiment 2

[0045] A polyvinyl alcohol water-soluble 3D printing support material, the raw material formula is: Taiwan Changchun Chemical Industry 0588 polyvinyl alcohol 500g, glycerin 50g, tetrakis [β-(3,5-di-tert-butyl-4-hydroxyphenyl) Propionic acid] pentaerythritol ester / tris(2,4-di-tert-butylphenyl) phosphite blend (1:1) 2.5g, magnesium hydroxide 20g, polyethylene wax 5g, petroleum resin 2.5g.

[0046] Preparation process of polyvinyl alcohol water-soluble 3D printing support material: Add the blend of polyvinyl alcohol and glycerin into a high-speed mixer, the speed is 1000r / min, the mixing time is 5min, and the obtained mixture is dried in an oven at 60°C 4 to 6 hours until the plasticizer is completely absorbed; put the above-mentioned mixed material and other raw materials in the formula into a high-speed mixer, the speed is 2000r / min, and the mixing time is 5min; put the mixed premixed material into a twin-screw extruder After melt extrusion and granulation, the twin-screw extru...

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PUM

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Abstract

The invention discloses a polyvinyl alcohol water-soluble 3D (Three-dimensional) printing support consumable item and a preparation method thereof. The polyvinyl alcohol water-soluble 3D printing support consumable item is prepared from the following components:60 to 90 parts of polyvinyl alcohol, 10 to 40 parts of plasticizer, 0.1 to 1 part of antioxidant, 0.1 to 5 parts of heat stabilizer, 0.5 to 2 parts of fluidity modifier, and 0.1 to 1 part of melt bonding enhancer. The preparation process comprises the steps of (1) adding the polyvinyl alcohol and the plasticizer into a mixer, and aftermixing and stirring, putting into a drying box; (2) adding the mixture, the antioxidant, the heat stabilizer, the fluidity modifier and the melt bonding enhancer into the mixture, and uniformly stirring; (3) after drying the mixture, adding to a pelletizer for extruding and pelletizing, and obtaining polyvinyl alcohol modified particles through co-mixing, pulling, air-cooling and dicing; (4) extruding the particles through the 3D printing consumable item so as to form threads, and rolling. The polyvinyl alcohol water-soluble 3D printing support consumable item and the preparation method thereof provided by the invention effectively solve the problem of poor bonding, the supportability is improved, the water solution speed is improved, and meanwhile, the requirement on water solution temperature is reduced.

Description

technical field [0001] The invention relates to the technical field of 3D printing consumables, in particular to a polyvinyl alcohol water-soluble 3D printing support consumable and a preparation method thereof. Background technique [0002] 3D printing technology, also known as additive manufacturing technology, is a type of rapid prototyping technology. It is based on digital model files and uses bondable materials such as powdered metal or plastic to construct objects by layer-by-layer printing. technology. At the end of the 20th century, the rapid development of computer technology and material technology promoted the sudden emergence of 3D printing technology in the manufacturing industry. With the rapid development of material science, rapid prototyping technology is constantly developing in all walks of life. At present, 3D printing has been widely used in aerospace, automobile industry, medical supplies, electronic appliances, art design, daily necessities and other...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L29/04C08L71/02C08L45/00C08L23/06C08L57/02C08L93/04C08K3/22B29C47/92B33Y70/00B29C48/92
Inventor 裴文剑钱欣金泽枫
Owner ZHEJIANG FLASHFORGE 3D TECH CO LTD
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