Red coloring agent for low-temperature colored glass, and preparation method and use method thereof

A colorant and color technology, applied in the field of colored glass, can solve the problems of unstable color development, low diffusion rate, heavy metal element pollution, etc.

Inactive Publication Date: 2018-02-02
JIANGSU BAIFU TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above methods all have problems such as unstable color development, low diffusion rate, and heavy metal element pollution. It is of great significance to develop new low-temperature red glass colorants.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1) Raw materials: Quartz powder (2000 mesh) 40kg, borax 26kg, sodium carbonate 25kg, titanium dioxide 1kg, zircon powder (200 mesh) 0.2kg, selenium powder 3.8kg.

[0022] (2) Mixing: Put all the raw materials in a mixing machine and mix them at room temperature for 60 minutes to obtain a composite powder.

[0023] (3) High-temperature melting and water quenching: the composite powder obtained in step (2) is directly put into a high-temperature frit furnace for melting. The temperature of the frit furnace is 1400°C, and the melting time is 6 hours. After melting, the molten glass material is directly put into water at room temperature for water quenching to obtain a water quenched material with a size of 2-10 mm.

[0024] (4) Drying: Dry the water-quenched material obtained in step (3) in an oven or other drying equipment at a temperature of 180°C for 10 hours, so that the water-quenched material has a moisture content of less than 1% to obtain a water-quenched material...

Embodiment 2

[0027] (1) Raw materials: Quartz powder (1000 mesh) 30kg, borax 25kg, sodium carbonate 20kg, potassium carbonate 2kg, calcium carbonate 5kg, titanium dioxide 10kg, zircon powder (200 mesh) 0.5kg, selenium powder 3kg, iron oxide 0.5kg .

[0028] (2) Mixing: Put all the raw materials in a mixing machine and mix them at room temperature for 2 hours to obtain a composite powder.

[0029] (3) High-temperature melting and water quenching: the composite powder obtained in step (2) is directly put into a high-temperature frit furnace for melting. The temperature of the frit furnace is 1480°C, and the melting time is 6 hours. After melting, the molten glass material is directly put into water at room temperature for water quenching to obtain a water quenched material with a size of 2-10 mm.

[0030] (4) Drying: Dry the water-quenched material obtained in step (3) in an oven or other drying equipment at a temperature of 250°C for 6 hours, so that the water-quenched material has a moist...

Embodiment 3

[0033] (1) Raw materials: Quartz powder (1000 mesh) 45kg, borax 20kg, sodium carbonate 15kg, potassium carbonate 5kg, calcium carbonate 5kg, dolomite powder 3kg, titanium dioxide 5kg, zinc oxide 2.5kg, zircon powder (200 mesh) 0.2kg , selenium powder 2kg, iron oxide 0.5kg, copper oxide 0.3kg.

[0034] (2) Mixing: Put all the raw materials in a mixing machine and mix them at room temperature for 5 hours to obtain a composite powder.

[0035] (3) High-temperature melting and water quenching: the composite powder obtained in step (2) is directly put into a high-temperature frit furnace for melting. The temperature of the frit furnace is 1350°C, and the melting time is 8 hours. After melting, the molten glass material is directly put into water at room temperature for water quenching to obtain a water quenched material with a size of 2-10 mm.

[0036] (4) Drying: Dry the water-quenched material obtained in step (3) in an oven or other drying equipment at a temperature of 150°C fo...

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PUM

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Abstract

The invention belongs to the field of colored glass, and particularly relates to a red coloring agent for low-temperature colored glass, and a preparation method and a use method thereof. The red coloring agent is prepared from the following raw materials in parts by mass: 30 to 50 parts of a quartz powder, 10 to 30 parts of borax, 10 to 25 parts of sodium carbonate and 2 to 30 parts of a coloringadditive, by the steps of mixing the materials, founding at high temperature, performing water quenching and pulverizing, wherein the coloring additive is one of or a mixture of more than one of selenium powder, cuprous oxide and ferric oxide. A large amount of low-melting-point silicon oxide, borax and sodium carbonate are adopted in the coloring agent base material, so that the dispersing speedof the coloring agent in 1200-DEG C glass liquid is greatly enhanced and uniformly colored glass original liquid is formed. In the preparation process of the coloring agent, the composite powder is directly added into a high-temperature frit furnace to perform founding and the reaction temperature is increased from a room temperature to 1350 to 1500 DEG C instantaneously, so that decomposition, volatilization and composition segregation of the materials in the slow heating process are avoided, and a coloring agent product with high stoichiometric ratio and high high-temperature dispersion speed is obtained.

Description

technical field [0001] The invention belongs to the field of colored glass, and in particular relates to a red colorant for low-temperature colored glass and a preparation method and application method thereof. Background technique [0002] Colored glass refers to glass that can absorb, reflect, and pass through light of different wavelengths to present different colors. Color glass has blue, brown, gray, green, gold and other colors, and has many functions, such as effectively absorbing the sun's radiant heat, producing "cold room effect", achieving the effect of heat shielding and energy saving; Become soft and avoid glare; can effectively absorb the sun's ultraviolet rays, prevent indoor items from fading, deterioration, etc. [0003] At present, the color glass preparation process is to directly add the glass colorant to the glass melting furnace at about 1600 ℃. The temperature of the furnace is high, so that the colorant components can be completely melted, fully and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C1/04
CPCC03C1/04
Inventor 徐和良张慧娟崔栋
Owner JIANGSU BAIFU TECH CO LTD
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