Ag-based composite brazing foil and preparing method thereof

A silver-based composite and foil technology, used in welding equipment, manufacturing tools, metal processing equipment, etc., can solve the problems of difficult to use processing welding sheets or welding wires, alloys do not have processability, and alloy plasticity is reduced. good wettability, good toughness and plasticity

Active Publication Date: 2018-02-16
SINO PLATINUM METALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The melting point of Sn is only 231.89°C. Adding 12-20wt.% Sn to the Ag-Cu alloy can make the melting temperature of the alloy at 400-600°C. The microstructure of the alloy is mainly composed of Ag-rich α phase and Cu-rich phase. , Sn β phase composition, with the increase of Sn content, various electronic compounds such as β', γ', ε1, ε', δ, etc. will appear in the alloy. The existence of these electronic compounds will reduce the plasticity of the alloy and increase the brittleness. , it is difficult to use traditional rolling, drawing and other processes to process into welding sheet or welding wire
Existing studies have shown that only when the Sn content in the solder is ≤12wt.%, the Ag-Cu-Sn alloy has good processability, and when the Sn content is ≥15wt.%, the alloy basically has no processability

Method used

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  • Ag-based composite brazing foil and preparing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Using 6 silver layers, 5 copper layers, and 10 tin layers with thicknesses of 0.2, 0.1, and 0.05 mm respectively, a silver-based composite solder foil with a thickness of 0.1 mm was prepared by adopting the steps of the present invention. According to the chemical composition analysis, the weight percentage of the composition of the composite solder foil is: tin content is 20.1%, copper content is 22.2%, and the balance is silver. According to DSC thermal analysis and comparison, the melting temperature range of the silver-based composite solder foil is 28°C narrower than that of the alloy solder prepared by casting method, and the melting point is lowered by 6.8°C. According to GB / T11364-2008 "Experimental Method for Wettability of Solder", the solder wettability test was carried out between the solder prepared by the present invention and the solder prepared by the casting method, that is, 0.05g of each of the two solders was placed in the size The center of the coppe...

Embodiment 2

[0023] Prepare the silver-based composite brazing filler metal foil material by the method of embodiment 1, according to GB / T 11364-2008 " brazing filler metal wettability test method ", the brazing filler metal prepared by the present invention and the brazing filler metal that adopt melting casting method to prepare brazing filler metal Wettability test, that is, place 0.05g of each of the two solders in the center of a nickel substrate of 15×15×2mm, put it into a high vacuum brazing furnace and heat it to 595°C at a heating rate of 20°C / min and keep it for 5min. Then cool down to room temperature with the furnace, after measuring, it is found that the wetted area of ​​the silver-based composite solder foil prepared by the method of the present invention is 1.1 times that of the solder wetted area prepared by the melting and casting method to the nickel base material. The wettability of the solder to the nickel substrate is better. Under the same brazing conditions, nickel s...

Embodiment 3

[0025] Silver-based composite solder foil was prepared according to the method of Example 1. Under the same brazing conditions, the lap joint test of copper and nickel substrates was carried out on the two solders. The length of the lap joint was 2 mm, and the gap between the welds was 0.1 mm. According to GB / T 228.1-2010 "Metal Material Tensile Test", the mechanical properties of the welded joints are tested and compared, and it is found that the silver-based composite solder foil prepared by the method of the present invention is used to braze copper and nickel substrates. The tensile strength of the brazed joint is 10.6MPa higher than that of the solder prepared by the melting and casting method, and the silver-based composite solder foil prepared by the method of the present invention can be used to braze copper and nickel substrates with better mechanical properties. Brazed joints.

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Abstract

The invention discloses Ag-based composite brazing foil and a preparing method thereof, which is used for brazing electric vacuum components. The thickness of the Ag-based composite brazing foil is 0.05-1mm, the Sn content is 19-21%, the Cu content is 21-23%, and the rest is Ag. The preparing method of the Ag-based composite brazing foil comprises the following steps: orderly stacking Ag layers, Cu layers and Sn layers which are the same in size and 0.05-0.5mm in thickness according to the structure mode of Ag/Sn/Cu/Sn/Ag/.../Ag/Sn/Cu/Sn/Ag; making an Ag-Cu-Sn multi-layer composite blank of which the total layer number is 5-30 through pre-compression; then carrying out rolling to make Ag-Cu-Sn foil of which the thickness is 0.05-1mm; and after the following heat treatment, obtaining the Ag-based composite brazing foil. The prepared foil product has great tenacity and ductility, can be made into various sizes of premolding soldering lugs through cold blanking, and has great wetting property and welding property on base materials, such as copper, nickel, high-temperature alloy and kovar alloy.

Description

technical field [0001] The invention relates to a solder, in particular to a silver-based composite solder foil and a preparation method thereof. Background technique [0002] Brazing is one of the important methods for connecting metal materials and is a key connection technology in many fields. Brazing filler metal is a filler added to the gap between brazing joints to achieve the combination of two materials. It can be divided into hard solder and soft solder according to its melting temperature range. Precious metal brazing filler metal is an important class of non-ferrous metal brazing filler metal. It has moderate melting temperature, wide range of wettable substrates, and excellent mechanical properties of brazed joints. Its research and development and application have been widely concerned. [0003] Precious metal brazing filler metals refer to alloy brazing filler metals made of gold, silver, palladium, platinum and other precious metals and their alloys. Gold-bas...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/30
Inventor 许昆王春琴赵晓燕刘毅武海军罗锡明李伟张健康张文林
Owner SINO PLATINUM METALS CO LTD
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