Green plastic bag with double biodegradation and photodegradation and manufacturing method thereof

A double degradation, plastic bag technology, applied in the field of plastic films, can solve the problems of poor oxidation resistance, short service life and general degradation effect of photobiodegradable plastics, and achieve the goal of improving degradable performance, improving comprehensive performance and accelerating degradation speed. Effect

Inactive Publication Date: 2018-03-13
李君
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the prior art, in order to solve the problem of white pollution, photobiodegradable plastics have been produced, but the degradation effect is average and the degradation speed is slow. At the same time, photobiodegradable plastics have defects such as poor oxidation resistance, poor thermal stability, and short service life. It is easy to oxidize in an environment with high temperature, and it is easy to deteriorate when used in a high temperature environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Weigh the raw materials in the following weight ratio: 20 parts of polyethylene, 20 parts of calcium carbonate, 15 parts of microcrystalline starch, 10 parts of xyloglucan, 10 parts of chitin, 2 parts of diphenylcyclopropenone, disulfurized carbamic acid 1 part of iron, 1 part of titanate coupling agent, 1 part of nano titanium dioxide, 1 part of simethicone, 2 parts of sorbitol, 2 parts of phthalic acid, 2 parts of sodium carboxymethyl cellulose, oxidized polyethylene 2 parts wax, 2 parts mannitol stearate, 2 parts acetic acid. Prepare as follows:

[0023] (1) Grind calcium carbonate to a particle size of 700 mesh, put it in an oven at a temperature of 100°C, and dry it until the water content is 2%, add it to a high-speed stirring mixer with a titanate coupling agent, and mix for 5 minutes ;

[0024] (2) Add polyethylene, microcrystalline starch, diphenylcyclopropenone, iron disulfide carbamate, and nano-titanium dioxide to the high-speed mixer and mix for 5 minutes...

Embodiment 2

[0030] Weigh the raw materials in the following weight proportions: 25 parts of polyethylene, 25 parts of calcium carbonate, 20 parts of microcrystalline starch, 15 parts of xyloglucan, 15 parts of chitin, 4 parts of diphenylcyclopropenone, disulfurized carbamic acid 3 parts of iron, 3 parts of titanate coupling agent, 2 parts of nano-titanium dioxide, 2 parts of simethicone, 3 parts of sorbitol, 3 parts of phthalic acid, 4 parts of sodium carboxymethyl cellulose, oxidized polyethylene 5 parts of wax, 5 parts of mannitol stearate, 5 parts of acetic acid.

[0031] Prepare as follows:

[0032] (1) Grind calcium carbonate to a particle size of 1000 mesh, put it in an oven at a temperature of 100°C, and dry it until the water content is 1.5%, add it to a high-speed mixer with a titanate coupling agent, and mix for 15 minutes;

[0033] (2) Add polyethylene, microcrystalline starch, diphenylcyclopropenone, iron disulfide carbamate, and nano-titanium dioxide to the high-speed mixer ...

Embodiment 3

[0039] Weigh the raw materials in the following weight proportions: 30 parts of polyethylene, 30 parts of calcium carbonate, 30 parts of microcrystalline starch, 20 parts of xyloglucan, 20 parts of chitin, 6 parts of diphenylcyclopropenone, disulfurized carbamic acid 5 parts of iron, 5 parts of titanate coupling agent, 3 parts of nano-titanium dioxide, 3 parts of simethicone, 5 parts of sorbitol, 4 parts of phthalic acid, 6 parts of sodium carboxymethyl cellulose, oxidized polyethylene 8 parts of wax, 8 parts of mannitol stearate, 8 parts of acetic acid.

[0040] Prepare as follows:

[0041] (1) Grind calcium carbonate to a particle size of 1200 mesh, put it in an oven at a temperature of 100°C, and dry it until the water content is 1%, add it to a high-speed stirring mixer with a titanate coupling agent, and mix for 20 minutes ;

[0042] (2) Add polyethylene, microcrystalline starch, diphenylcyclopropenone, iron disulfide carbamate, and nano-titanium dioxide to the high-speed...

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PUM

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Abstract

The invention discloses a green plastic bag with double biodegradation and photodegradation and a manufacturing method thereof, which relate to the technical field of plastic thin films. The green plastic bag is prepared from the following raw materials in parts by weight: 20 to 30 parts of polyethylene, 20 to 30 parts of calcium carbonate, 15 to 25 parts of microcrystalline starch, 10 to 20 partsof xyloglucan, 10 to 20 parts of chitosan, 2 to 6 parts of diphenylcyclopropenone, 1 to 5 parts of iron dithiocarbamate, 1 to 5 parts of titanate coupling agent, 1 to 3 parts of nanometer titania, 1to 3 parts of simethicone, 2 to 5 parts of sorbitol, 2 to 4 parts of phthalic acid, 2 to 6 parts of sodium carboxymethylcellulose, 2 to 8 parts of oxidized polyethlene wax, 2 to 8 parts of mannitol stearate, and 2 to 8 parts of acetic acid. The green plastic bag provided by the invention has synergism, cooperation and coherent functions between biodegradation and photodegradation, and the photodegradation and oxide degradation can be carried out at the same time and mutually promoted; biodegradation easily occurs after photodegradation, meanwhile, the water resistance, the strength, the heat machinability and the service life are improved, and a comprehensive performance is further improved.

Description

technical field [0001] The invention relates to the technical field of plastic films, in particular to an environmentally friendly plastic bag with dual biodegradation and photodegradation and a manufacturing method thereof. Background technique [0002] With the increasing use of plastics, a large amount of plastic waste is generated. Because it is difficult to degrade (ordinary plastics can be completely degraded in 200-400 years), white pollution has become a worldwide public hazard that endangers the social environment and seriously hinders the sustainable development of social economy and the environment. In order to solve this serious social problem, more and more scholars advocate the development and application of degradable plastics, and regard it as an ideal way to solve this world problem. [0003] At present, the degradable plastics researched in the world can be divided into four categories, photodegradable plastics, biodegradable plastics, chemically degradabl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L3/02C08L5/02C08L5/08C08L83/04C08L1/28C08L23/30C08K13/02C08K3/26C08K5/07C08K5/39C08K3/22C08K5/053C08K5/092C08K5/103
Inventor 李君贺银仔
Owner 李君
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