Method for recycling gold for gold-bearing washing mud of gold ore cyaniding system

A cyanidation system and gold recovery technology, applied in the field of metallurgy, can solve the problems of equipment cost, high energy consumption, large investment in microwave equipment, long biological oxidation time, etc., and achieve low production cost, efficient recovery, and prevention of secondary wrapping. Effect

Active Publication Date: 2018-03-20
ZIJIN MINING GROUP +1
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Problems solved by technology

[0004] The existing technology mainly includes roasting method, hot-pressed oxidation method and biological oxidation method for the pretreatment of refractory gold ore. For example, Chinese patent CN103122415A has announced "a method for improving the leaching rate of wrapped gold", which promotes the leaching rate through three-stage screening and crushing. It ensures the dissociation of wrapped gold and sulfide monomer, and oxygen-enriched roasting improves the oxidation degree of sulfide. The advantages are simple process, large processing capacity, and easy control of production conditions. The disadvantage is that the gold leaching rate is not high, only about 83%.
Another example is the Chinese patent CN 104694764A which also announces "a method for enhanced leaching of fine-grained wrapped gold". The leaching rate of gold in cyanide slag is high by this method, with an average value of 92.12%. However, due to ultra-fine grinding and hot pressing The equipment cost and energy consumption of the two leaching processes are high, resulting in high production costs
Another example is that Chinese patent CN 101285126A also discloses "a kind of process for extracting gold from refractory gold concentrate with low pollution and high recovery rate", which utilizes the combined process of biological oxidation and microwave roasting, and the gold leaching rate is relatively high, reaching about 94%. The advantage is that the biological oxidation time is long (7 days), and the investment in microwave equipment is large.
[0005] In the prior art, there is no report on the complex and difficult-to-handle gold-bearing materials such as gold-bearing mud washing in cyanidation system

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  • Method for recycling gold for gold-bearing washing mud of gold ore cyaniding system

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example 1

[0044] Example 1: The gold-containing washing mud of the gold mine cyanidation system is crushed, and the fineness after fine grinding reaches -200 mesh, accounting for 80%; The concentration is 10kg / m3, and the acid leaching time is 2h; the acid leaching pulp is subjected to solid-liquid separation, and the acid leaching residue is washed with water until the pH of the washing solution is close to neutral and dry; high temperature roasting is carried out at 500 ℃, and the roasting time is 1h; Add water to make ore pulp with a solid content of 35%, and adjust the pH of the ore pulp to 9 with sodium hydroxide; add 3kg / t of NaCN (dry slag) and 20kg / m3 of activated carbon (ore pulp) to the ore pulp to extract gold by charcoal. The leaching time is 20h; the pulp after carbon leaching gold is separated with a 20-mesh sieve, the product on the sieve is the product gold-loaded carbon, and the material under the sieve is subjected to solid-liquid separation. stockpiled.

[0045] The ...

example 2

[0046]Example 2: The gold-containing washing mud of the gold mine cyanidation system is crushed, and the fineness after fine grinding reaches -200 mesh, accounting for 85%; 50 g of gold-containing washing mud is acid leached with hydrochloric acid, and the liquid-solid ratio is 3:1, and the hydrochloric acid is 3:1. The concentration is 20kg / m3, and the acid leaching time is 3h; the acid leaching pulp is separated from the solid-liquid, and the acid leaching residue is washed with water until the pH of the washing solution is close to neutral and dry; high temperature roasting is carried out at 600 ℃, and the roasting time is 2 hours; Add water to adjust the ore pulp with a solid content of 40%, and adjust the pH of the ore pulp to 11 with sodium hydroxide; add 5kg / t of NaCN (dry slag) and 30kg / m3 of activated carbon (ore pulp) to the ore pulp to extract gold by carbon. The leaching time is 24h; the pulp after carbon leaching gold is separated with a 20-mesh sieve, the product ...

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Abstract

The invention relates to a method for recycling gold for gold-bearing washing mud of a gold ore cyaniding system. The method includes the following wet process-pyrogenic process combined technologicalsteps of crushing and grinding, acid leaching, solid-liquid separation, roasting, size mixing, alkali adjusting, gold extraction with a carbon-in-leach process and screening for solid-liquid separation b; and according to conditions, conventional sulfuric acid is replaced with hydrochloric acid for acid leaching, the weight of samples entering the roasting step can be reduced, the roasting energyconsumption is reduced, the problem of secondary gold wrapping caused by generation of calcium sulfate can be solved, the gold leaching efficiency is improved, the beneficial effects of being simplein process, low in production cost, high in gold leaching efficiency, capable turning waste into wealth, environment-friendly and the like are achieved, efficient recycling of gold-bearing washing mudvaluable resources can be achieved, and the method is suitable for recycling and application of the gold in the washing mud of the gold ore cyaniding system.

Description

technical field [0001] The invention relates to the technical field of metallurgy, in particular to a method for recovering gold from the gold-containing washing mud of a cyanidation system of a gold mine, which is suitable for the recovery and application of gold in the washing mud of a cyanidation system of a gold mine. Background technique [0002] In the process of gold production, the fine-grained part of the material obtained by washing and grading is generally used to recover precious metal gold by carbon leaching. The enterprise must recycle the cyanidation wastewater. Since the cyanidation wastewater needs to be adjusted with lime to adjust the alkali, calcium will accumulate in the leaching system, and the carbon dioxide and calcium in the air will form calcium carbonate precipitation during aeration and stirring. Calcium carbonate scaling problems exist in the tanks and pipes of the cyanide system. When cleaning the cyanidation system, the calcium carbonate scali...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B11/00C22B7/00C22B1/02C22B11/08
CPCC22B1/02C22B7/007C22B11/042C22B11/08Y02P10/20
Inventor 沈青峰甘永刚庄荣传王弘吴智
Owner ZIJIN MINING GROUP
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