A method for recovering valuable elements in waste lithium-ion battery electrode materials
A lithium-ion battery and electrode material technology, which is applied in the field of recycling waste lithium battery electrode materials, can solve the problems of increased cost, low nickel-cobalt-manganese leaching rate, low recovery rate, etc., to achieve recycling, reduce battery sorting and Recovery cost and the effect of reducing recovery cost
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Embodiment 1
[0012] After crushing and sorting waste lithium-ion batteries containing nickel-cobalt-manganese positive electrode materials, a mixture of positive electrode materials, negative electrode graphite powder and part of the electrolyte is obtained, containing 15%wt of nickel, 8%wt of cobalt, 10%wt of manganese, and 5% of lithium. %wt, carbon 35%wt, fluorine 1.2%wt, calcining under nitrogen atmosphere, the calcining temperature is 500 ℃, and keep it warm for 30 minutes. The roasted slag in [H + ] The sulfuric acid solution with a concentration of 0.5mol / L is mixed according to the mass ratio of 1:10, and leached at a leaching temperature of 90°C and a leaching time of 1h. After the leaching is completed, filter and separate to obtain the leaching solution and leaching residue; the leaching solution is used for further recovery of nickel and cobalt , manganese, lithium, and the leaching residue are used to prepare negative electrode materials. The analysis results show that the le...
Embodiment 2
[0014] After crushing and sorting waste lithium-ion batteries containing nickel-cobalt-aluminum cathode materials, a mixture of cathode materials, negative electrode graphite powder, and part of the electrolyte is obtained, containing 30%wt of nickel, 6%wt of cobalt, 5%wt of aluminum, and 4% of lithium. %wt, carbon 20%wt, fluorine 0.5%wt, calcined in an argon atmosphere, the calcined temperature is 600 ℃, and kept for 60 minutes. The roasted slag in [H + ] The hydrochloric acid solution with a concentration of 1mol / L is mixed according to the mass ratio of 1:8, and leached at a leaching temperature of 70°C and a leaching time of 3h. Manganese, lithium, and leached slag are used to prepare negative electrode materials. The analysis results show that the leaching rates in terms of slag are 90.97% for lithium, 92.75% for nickel, 91.78% for cobalt, and 90.77% for aluminum.
Embodiment 3
[0016] After crushing and sorting waste lithium-ion batteries containing different proportions of nickel-cobalt-manganese cathode materials, a mixture of cathode materials, negative electrode graphite powder, and part of the electrolyte is obtained, which contains 22%wt of nickel, 12%wt of cobalt, and 6% of manganese wt, aluminum 0.01%wt, lithium 2%wt, carbon 30%wt, fluorine 1.0%wt, were calcined in a carbon dioxide atmosphere at 400°C and kept for 120 minutes. The roasted slag in [H + ] Sulfuric acid solution and hydrochloric acid solution with a concentration of 2mol / L are mixed at a mass ratio of 1:6, and leached at a leaching temperature of 50°C and a leaching time of 5h. After the leaching is completed, filter and separate to obtain the leaching solution and leaching residue; the leaching solution is used to further recover nickel , cobalt, manganese, lithium, and the leaching residue are used to prepare negative electrode materials. The analysis results show that the le...
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