Bioelectrochemistry soil remediation system and method driven by solar photovoltaic
A solar photovoltaic and bioelectrochemical technology, applied in the restoration of polluted soil, etc., can solve problems such as the persistent residual of organic pollutants, and achieve the effect of accelerating the electron transfer rate, solving the persistent residual, and increasing the contact area.
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Embodiment 1
[0032] In this embodiment, the biological filter bed uses sand as the filter material; the anode electrode is a nickel metal organic framework material, and the cathode electrode is a graphite rod; the voltage used to drive the bioelectrochemical soil remediation is 0V, the soil humidity is 50%, and the pH is 6, and soil pollutants are petroleum aromatic hydrocarbons, phenols and organophosphorus pesticides.
[0033] The spray solution is 0mg / L of surfactant per liter of water; the carbon source concentration is 0g / L; the nitrogen source concentration is 0g / L; the phosphorus source concentration is 0g / L; the metal ion is 0.1g MgSO 4 ·7H 2 O, 1mg FeCl 3 , 0.1g KH 2 PO 4 , 0.05g anhydrous CaCl 2 ; The concentration of microbial essential nutrients and vitamins is 0.5ml / L.
Embodiment 2
[0035] In this embodiment, the biological filter bed uses crushed stone as the filter material; the anode electrode is a zinc metal organic framework material, and the cathode electrode is a stainless steel mesh; and the voltage used to drive the bioelectrochemical soil remediation is 1V, and the soil humidity is 65%. The pH was 7, and the soil contaminants were petroleum aromatic hydrocarbons, phenols, and organophosphorus pesticides.
[0036] The spray solution contains 50mg / L of surfactant per liter of water, wherein the ratio of sodium dodecylbenzenesulfonate, quaternary ammonium salt and Tween 80 is: 1:2:3; the carbon source concentration is 50g / L L, in which the ratio of glucose, sodium acetate, sodium formate and sucrose is: 1:1:1; nitrogen source concentration is 5g / L; phosphorus source concentration is 2.5g / L; metal ion is 1g MgSO 4 ·7H 2 O, 10mg FeCl 3 , 1g KH 2 PO 4 , 0.5g anhydrous CaCl 2 ; The concentration of microbial essential nutrients and vitamins is 2ml...
Embodiment 3
[0038] In this embodiment, the biological filter bed uses plastic as the filter material; the anode electrode is an iron metal organic framework material, and the cathode electrode is a graphite rod; and the voltage used to drive the bioelectrochemical soil remediation is 2V, the soil humidity is 80%, and the pH is 80%. was 8, and the soil pollutants were petroleum aromatic hydrocarbons, phenols and organophosphorus pesticides.
[0039] The spray solution contains 100mg / L of surfactant per liter of water, wherein the ratio of sodium dodecylbenzene sulfonate, quaternary ammonium salt and Tween 80 is: 3:2:1; the carbon source concentration is 100g / L L, in which the ratio of glucose, sodium acetate, sodium formate and sucrose is: 4:3:2:1; nitrogen source concentration is 10g / L; phosphorus source concentration is 5g / L; metal ion is 2g MgSO 4 ·7H 2 O, 20mg FeCl 3 , 2g KH 2 PO 4 , 1g anhydrous CaCl 2 ; The concentration of microbial essential nutrients and vitamins is 5ml / L.
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