A solar photovoltaic driven bioelectrochemical soil remediation system and method
A solar photovoltaic and bioelectrochemical technology, applied in the restoration of polluted soil, etc., can solve the problems of persistent organic pollutants, achieve the effect of accelerating the electron transfer rate, increasing the contact area, and solving the persistent residual
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Embodiment 1
[0032] In this embodiment, the biological filter bed is to use sand as the filter material; the anode electrode is a nickel metal organic framework material, and the cathode electrode is a graphite rod; the voltage for driving bioelectrochemical soil restoration is 0V, the soil humidity is 50%, and the pH is 6, and the soil pollutants are petroleum aromatic hydrocarbons, phenols and organophosphorus pesticides.
[0033] Among them, the spray solution contains 0mg / L of surfactant per liter of water; the concentration of carbon source is 0g / L; the concentration of nitrogen source is 0g / L; the concentration of phosphorus source is 0g / L; the metal ion is 0.1g MgSO 4 ·7H 2 O, 1 mg FeCl 3 , 0.1g KH 2 PO 4 , 0.05g anhydrous CaCl 2 ; The vitamin concentration of essential nutrients for microorganisms is 0.5ml / L.
Embodiment 2
[0035] In the present embodiment, the biological filter bed is made of crushed stone; the anode electrode is a zinc metal organic framework material, and the cathode electrode is a stainless steel mesh; and the voltage for driving bioelectrochemical soil restoration is 1V, and the soil humidity is 65%. The pH was 7, and the soil pollutants were petroleum aromatics, phenols, and organophosphorus pesticides.
[0036] Wherein the spray solution contains surfactant 50mg / L according to per liter of water, wherein the ratio of sodium dodecylbenzenesulfonate, quaternary ammonium salt and Tween 80 is: 1:2:3; carbon source concentration is 50g / L L, wherein the ratio of glucose, sodium acetate, sodium formate and sucrose is: 1:1:1; the concentration of nitrogen source is 5g / L; the concentration of phosphorus source is 2.5g / L; the metal ion is 1g MgSO 4 ·7H 2 O, 10mgFeCl 3 , 1g KH 2 PO 4 , 0.5g anhydrous CaCl 2 ; The vitamin concentration of essential nutrients for microorganisms is...
Embodiment 3
[0038] In the present embodiment, the biological filter bed is made of plastic as a filter material; the anode electrode is an iron metal organic framework material, and the cathode electrode is a graphite rod; and the voltage for driving bioelectrochemical soil restoration is 2V, the soil humidity is 80%, and the pH is 8, and the soil pollutants are petroleum aromatic hydrocarbons, phenols and organophosphorus pesticides.
[0039] Wherein the spray solution contains surfactant 100mg / L according to per liter of water, wherein the ratio of sodium dodecylbenzenesulfonate, quaternary ammonium salt and Tween 80 is: 3:2:1; carbon source concentration is 100g / L L, wherein the ratio of glucose, sodium acetate, sodium formate and sucrose is: 4:3:2:1; the concentration of nitrogen source is 10g / L; the concentration of phosphorus source is 5g / L; the metal ion is 2g MgSO 4 ·7H 2 O, 20mgFeCl 3 , 2g KH 2 PO 4 , 1g anhydrous CaCl 2 ; The vitamin concentration of essential nutrients for...
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