Highly-flame-retardant transparent PET material and preparation method thereof

A high flame retardant and transparent technology, applied in the field of polymer materials, can solve the problems of low practicability, PET material melt strength, dimensional stability, barrier property, heat resistance, etc., and achieve high practicability and surface transparency Glossy, easy-to-operate effect

Active Publication Date: 2018-07-20
广东威立瑞科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the rapid development of my country's electric power field, there are various pipe materials currently used in electric power protection, and electric power protection tubes are important components in the electric power field. PET, PVC, PE, PP and other materials, among which, PET materials are widely used due to their good wear resistance, strong plasticity, good solvent resistance, good surface scratch resistance, good crack resistance, and good mechanical and physical properties. , but the melt strength, dimensional stability, barrier properties, heat resistance and other properties of PET materials are still insufficient; in addition, most of the current power protection pipes are pipe materials of various colors, and it is difficult to know the inside and outside of the pipe in real time through the pipe in practical applications. In the case of wire and cable, the practicability is low

Method used

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  • Highly-flame-retardant transparent PET material and preparation method thereof
  • Highly-flame-retardant transparent PET material and preparation method thereof
  • Highly-flame-retardant transparent PET material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A highly flame-retardant transparent PET material, the transparent PET material includes the following raw materials by weight:

[0034]

[0035]

[0036] The nucleating agent is composed of 2,2'-methylene bis(4,6-tert-butylphenol)phosphine aluminum salt, dibenzylidene sorbitol and two (p-chloro-substituted benzylidene) sorbitol in a weight ratio of 2.5 :1.2:0.8 mixture.

[0037] The compatibilizer is chlorinated polyethylene.

[0038] The flame retardant is tris(2,3-dibromopropyl) isocyanurate.

[0039] The synergist is antimony trioxide.

[0040] The coupling agent is vinyltriethoxysilane.

[0041] The transparent PET material also includes 1 part of heat-resistant agent, which is magnesium silicide.

[0042] The transparent PET material also includes 0.5 part of lubricant, and the lubricant is glycerol trihydroxystearate.

[0043] The transparent PET material also includes 2.4 parts of antioxidant, and the antioxidant is 1,3,5-tris(3,5 tert-butyl-4-hydroxy...

Embodiment 2

[0048] A highly flame-retardant transparent PET material, the transparent PET material includes the following raw materials by weight:

[0049]

[0050]

[0051] The nucleating agent is composed of 2,2'-methylene bis(4,6-tert-butylphenol)phosphine aluminum salt, dibenzylidene sorbitol and two (p-chloro-substituted benzylidene) sorbitol in a weight ratio of 2.8 :1.3:0.9 mixture.

[0052] The compatibilizer is methacrylate-acrylate copolymer.

[0053] The flame retardant is tribromophenol and / or aluminum tripolyphosphate.

[0054] The synergist is zinc stannate and / or zinc molybdate.

[0055] The coupling agent is anilinomethyltriethoxysilane.

[0056] The transparent PET material also includes 2 parts of heat-resistant agent, and the heat-resistant agent is ceramic fiber.

[0057] The transparent PET material also includes 1 part of lubricant, which is n-butyl stearate.

[0058] The transparent PET material also includes 2.6 parts of antioxidant, and the antioxidant ...

Embodiment 3

[0063] A highly flame-retardant transparent PET material, the transparent PET material includes the following raw materials by weight:

[0064]

[0065] The nucleating agent is composed of 2,2'-methylene bis(4,6-tert-butylphenol)phosphine aluminum salt, dibenzylidene sorbitol and two (p-chloro-substituted benzylidene) sorbitol in a weight ratio of 3 :1.5:1.0 mixture.

[0066] The compatibilizer is natural rubber grafted polymethyl methacrylate and / or styrene grafted maleic anhydride.

[0067] The flame retardant is tetrabromophthalic anhydride and / or octabromoether.

[0068] The synergist is magnesium silicate and / or zinc borate.

[0069] The coupling agent is γ-methacryloxypropyltrimethoxysilane and / or vinyltris(β-methoxyethoxy)silane.

[0070] The transparent PET material also includes 3 parts of heat-resistant agent, and the heat-resistant agent is lignocellulose.

[0071] The transparent PET material also includes 1.5 parts of lubricant, and the lubricant is N,N,-et...

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Abstract

The invention relates to the technical field of polymer materials, and concretely relates to a highly-flame-retardant transparent PET material and a preparation method thereof. The transparent PET material comprises, by weight, 70-118 parts of PET resin, 8-16 parts of a nucleating agent, 3-7 parts of a compatibilizer, 7-13 parts of a flame retardant, 1-3 parts of a synergist, 0.5-1.0 part of talcum powder and 2-6 parts of a coupling agent, and the nucleating agent is a mixture comprising aluminum 2,2'-methylene bis(4,6-tert-butylphenol)phosphate (NA-21), dibenzylidene sorbitol and di(p-chloro-substituted benzylidene)sorbitol according to a weight ratio of (2.5-3.5):(1.2-1.8):(0.8-1.2). The transparent PET material is transparent and visible, and has the advantages of good transparency, good flame retardancy, good heat resistance, good smoke inhibition property, good stability, good oxidation and aging resistance, high strength, good molding performance, good processing performance andhigh use values.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a highly flame-retardant transparent PET material and a preparation method thereof. Background technique [0002] With the rapid development of my country's electric power field, there are various pipe materials currently used in electric power protection, and electric power protection tubes are important components in the electric power field. PET, PVC, PE, PP and other materials, among which, PET materials are widely used due to their good wear resistance, strong plasticity, good solvent resistance, good surface scratch resistance, good crack resistance, and good mechanical and physical properties. , but the melt strength, dimensional stability, barrier properties, heat resistance and other properties of PET materials are still insufficient; in addition, most of the current power protection pipes are pipe materials of various colors, and it is difficult to know the insi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L23/28C08L33/04C08K13/02C08K5/3492C08K3/22C08K3/34C08K5/1575C08K3/32C08K5/136C08K3/24C08L51/04C08L51/00C08K5/06C08K3/38C08K5/5333C08K13/04C08K7/04
CPCC08K3/38C08K5/0083C08K5/06C08K5/1575C08K13/02C08K2003/2296C08K2003/387C08L67/02C08L2201/02C08L2201/08C08L2201/10C08L2205/24C08L23/286C08K5/3492C08K3/2279C08K3/34C08L33/04C08K13/04C08K7/04C08K5/136C08K3/32C08K3/24C08L51/04C08L51/003C08K5/5333C08K3/22
Inventor 袁伟汤咏莉贺军波麦志伟袁丽
Owner 广东威立瑞科技有限公司
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