Production method of silver coated nickel powder

A technology of silver-coated nickel powder and production method, which is applied in transportation and packaging, liquid chemical plating, coating, etc., can solve the problems of loose and non-dense coating, hinder the deposition of silver atoms, and complex process, etc., and achieve uniform and dense metal coating , slow down the deposition rate, good electrical conductivity

Active Publication Date: 2018-07-27
宁波广新纳米材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Chinese patent CN 1416986 discloses a production method of a high-temperature-resistant and anti-oxidation base silver-coated nickel powder composition. The nickel powder of the invention uses cleaning, activation, and sensitization before plating, and the process is relatively complicated and the cost is high; and silver plating During the process, it is easy to produce nickel ammonium ions to wrap on the nickel powder particles, hindering the deposition of silver atoms, and the coating is loose and not dense.

Method used

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  • Production method of silver coated nickel powder
  • Production method of silver coated nickel powder
  • Production method of silver coated nickel powder

Examples

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Embodiment 1

[0027] The invention provides a kind of production method of silver-coated nickel powder, and concrete process is as follows:

[0028] Pretreatment of S1 nickel powder: a. Weigh 300ml of water, 24g of citric acid and 2.5g of triethanolamine oleate to prepare a mixed solution for cleaning, weigh 10.5g of nickel powder (spherical nickel powder with a particle size of 1-5μm) and add to the mixture solution, then ultrasonically mechanically stirred for 30 minutes, then turned off the ultrasonic wave and continued to stir for 10 minutes. At the same time, the water temperature in the ultrasonic wave was required to be 40°C, and then washed with deionized water until the pH of the supernatant was neutral, and the nickel powder was filtered out; b Add the nickel powder to hydrogen peroxide In the alkaline solution, stir at 70° C. for 20 minutes and then wash and set aside; add the nickel powder finished in step b to an ethanol aqueous solution of 1.5% KH560 (in this example, Z6040 pro...

Embodiment 2

[0035] The invention provides a kind of production method of silver-coated nickel powder, and concrete process is as follows:

[0036] Pretreatment of S1 nickel powder: Weigh 300ml of water, 24g of malic acid and 3.5g of fatty alcohol polyoxyethylene ether to prepare a mixed solution for cleaning, weigh 10.5g of nickel powder (spherical nickel powder with a particle size of 5-10μm) and add In the mixed solution, then ultrasonic mechanically stirred for 30 minutes, then turned off the ultrasonic and continued to stir for 10 minutes. At the same time, the water temperature in the ultrasonic wave was required to be 40 ° C, and then washed with deionized water until the pH of the supernatant was neutral, and the nickel powder was filtered out; b. Add the nickel powder In 5% fructose solution, after stirring for 30 min at 75° C., wash and stand for use; add the nickel powder finished in b process into 5% KH550 (using Z6011 produced by U.S. Dow Corning in this embodiment) in an aqueo...

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Abstract

The invention discloses a production method of silver coated nickel powder. The method comprises three main steps of surface preprocessing, plating and surface post-processing to prepare the nickel powder, wherein the preprocessing include washing and surface modifying of the nickel powder; the plating is performed by a chemical plating method using a silver-ammonia solution; the nickel powder isactivated through a surfactant containing water solution and is subjected to surface modification before silver plating, so that the nickel powder is easily plated; a complexing agent is added to a reduction solution in the plating process so as to decrease the deposition speed of silver atoms, and the nickel powder can be coated with the silver atoms; after plating, the surface is further processed through a thermal processing method in order to repair few coating defects in the silver plating link by a reductive thermal treatment technology, and thus the coating density is improved; and meanwhile, the processes are environmentally friendly, and easily operated; and industrial massive production is realized. The silver coated nickel powder prepared by the method is uniform and dense in ametal plating layer, free from exposed pores, and high in electricity conductivity while being used in an electrical material.

Description

technical field [0001] The invention belongs to the field of electronic functional materials and metal powder materials, in particular to a method for preparing a metal-coated powder, more specifically, a production of silver-coated nickel powder coated and densely applied to medium-high temperature electronic paste method. Background technique [0002] With the rapid development of the modern electronics industry, the number of various commercial and household electronic products has increased dramatically. The miniaturization, integration, light weight, and digitization of electronic circuits and components have caused electronic products in daily use to be susceptible to electromagnetic interference and cause malfunctions and image disturbances. At the same time, these electronic products themselves also emit electromagnetic waves, thus forming a public hazard problem of electromagnetic waves. At present, to solve the electromagnetic wave interference and shielding prob...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F1/02C23C18/44
CPCC23C18/1692C23C18/44B22F1/17B22F1/142
Inventor 王翠霞王锴尧蒋博宋书清
Owner 宁波广新纳米材料有限公司
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