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Gas diffusion layer for fuel cell, method for manufacturing said layer, membrane-electrode assembly, and fuel cell

A gas diffusion layer and fuel cell technology, which is used in fuel cell parts, fuel cells, battery electrodes, etc. to improve air permeability and power generation performance.

Active Publication Date: 2018-07-31
PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] In addition, Patent Documents 2, 3, and 4 disclose gas diffusion layers that do not use carbon fiber as a base material.

Method used

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  • Gas diffusion layer for fuel cell, method for manufacturing said layer, membrane-electrode assembly, and fuel cell
  • Gas diffusion layer for fuel cell, method for manufacturing said layer, membrane-electrode assembly, and fuel cell
  • Gas diffusion layer for fuel cell, method for manufacturing said layer, membrane-electrode assembly, and fuel cell

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no. 1 approach

[0060] use figure 1 , the basic configuration of the fuel cell described in the embodiment will be described. figure 1 It is a schematic perspective view of the polymer electrolyte fuel cell stack according to the embodiment. It should be noted that this embodiment is not limited to polymer electrolyte fuel cells, but can be applied to various fuel cells.

[0061] Such as figure 1 As shown, the fuel cell is formed by stacking a plurality of battery cells 10 as a basic unit, and fastening (connecting) them with a specific load from both sides with current collector plates 11 , insulating plates 12 , and end plates 13 .

[0062] The current collector plate 11 is made of an air-impermeable conductive material such as copper or brass. The current collector plate 11 is provided with a current extraction terminal portion, from which current is extracted during power generation.

[0063] For the insulating plate 12, an insulating resin such as fluorine-based resin, PPS resin, or ...

no. 2 approach

[0138] The fuel cell according to the second embodiment of the present invention will be described. The gas diffusion layer 3 is different from the first embodiment 1 . The gas diffusion layer 3 of the second embodiment differs from the gas diffusion layer 3 of the above-mentioned first embodiment in that a fluid channel 5 is formed on one surface of the gas diffusion layer 3 . The other points are the same as those of the above-mentioned first embodiment, so repeated explanations will be omitted, and the differences will be mainly described.

[0139] The basic configuration of the fuel cell described in the second embodiment is the same as that in the first embodiment, and thus description thereof will be omitted. Items not described are the same as those in Embodiment 1.

[0140] Next, the configuration of the battery unit 10 described in the second embodiment will be described in detail. Figure 8 is a cross-sectional view of the battery cell 10 .

[0141] The battery c...

Embodiment 1~6

[0168] Regarding the composition ratio of the gas diffusion layer 3 , acetylene black, Ketjen black, artificial graphite, VGCF, PTFE, and fumaric acid (pore former) were set to the composition ratios shown in Table 1. By the production method of the first embodiment, the gas diffusion layer 3 having a thickness of 200 μm and the above composition ratio was produced.

[0169] The porosity, the average pore diameter, the number of pores with a diameter of 1 μm to 200 μm, the area ratio of the pores to the total area, the air permeability (Gurley number), and the thickness direction of the gas diffusion layer 3 were measured. resistance.

[0170] The results are shown in Table 1.

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Abstract

A gas diffusion layer used in a fuel cell, wherein the gas diffusion layer comprises a porous member having electroconductive particles and a polymer resin as main components, and the interior of thegas diffusion layer has pores measuring 0.01-0.05 um and holes measuring 1-200 um. A method for manufacturing a gas diffusion layer used in a fuel cell, wherein the method comprises: a kneading step for kneading electroconductive particles, a polymer resin, a pore-forming agent, a surfactant, and a dispersion solvent; a rolling step for rolling the kneaded product obtained by the kneading, and forming the rolled product into the form of a sheet; a firing step for firing the kneaded formed into a sheet, causing the pore-forming agent to sublimate so that holes are formed, and removing the surfactant and the dispersion solvent; and a re-rolling step for re-rolling the fired kneaded product and adjusting the thickness.

Description

technical field [0001] The present invention relates to fuel cells. In particular, it relates to a membrane electrode assembly used in a fuel cell, a gas diffusion layer included in the membrane electrode assembly, and a manufacturing method thereof. Background technique [0002] In a fuel cell such as a polymer electrolyte fuel cell, one surface of the electrolyte membrane is exposed to fuel gas such as hydrogen, and the other surface is exposed to oxygen. As a result, the polymer electrolyte fuel cell synthesizes water through a chemical reaction via an electrolyte membrane. The basic principle of the polymer electrolyte fuel cell is to extract the reaction energy generated therefrom electrically. [0003] A single cell of a polymer electrolyte fuel cell has a membrane electrode assembly (hereinafter referred to as MEA) and a pair of conductive spacers arranged on both sides of the MEA. [0004] The MEA has: a hydrogen ion conductive polymer electrolyte membrane; a pair...

Claims

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Application Information

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IPC IPC(8): H01M4/96H01M4/88H01M8/02H01M8/0221H01M8/10
CPCH01M8/10H01M4/88H01M4/96H01M8/02H01M8/0234H01M8/0239H01M8/0243Y02P70/50Y02E60/50H01M4/8626H01M4/8807
Inventor 川岛勉近藤敬一庄司昌史小川孝二
Owner PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD